ALBERT

Note: CONTENTS: Preface to the Second Edition. - Preface to the First Edition. - 1 The Atmosphere. - 1.1 History and Evolution of the Earth's Atmosphere. - 1.2 Climate. - 1.3 The Layers of the Atmosphere. - 1.4 Pressure in the Atmosphere. - 1.4.1 Units of Pressure. - 1.4.2 Variation of Pressure with Height in the Atmosphere. - 1.5 Temperature in the Atmosphere. - 1.6 Expressing the Amount of a Substance in the Atmosphere. - 1.7 Spatial and Temporal Scales of Atmospheric Processes. - Problems. - References. - 2 Atmospheric Trace Constituents. - 2.1 Atmospheric Lifetime. - 2.2 Sulfur-Containing Compounds. - 2.2.1 Dimethyl Sulfide (CH3SCH3). - 2.2.2 Carbonyl Sulfide (OCS). - 2.2.3 Sulfur Dioxide (SO2). - 2.3 Nitrogen-Containing Compounds. - 2.3.1 Nitrous Oxide (N2O). - 2.3.2 Nitrogen Oxides (NO* = NO + NO2). - 2.3.3 Reactive Odd Nitrogen (NOy). - 2.3.4 Ammonia (NH3). - 2.4 Carbon-Containing Compounds. - 2.4.1 Classification of Hydrocarbons. - 2.4.2 Methane. - 2.4.3 Volatile Organic Compounds. - 2.4.4 Biogenic Hydrocarbons. - 2.4.5 Carbon Monoxide. - 2.4.6 Carbon Dioxide. - 2.5 Halogen-Containing Compounds. - 2.5.1 Methyl Chloride (CH3C1). - 2.5.2 Methyl Bromide (CH3Br). - 2.6 Atmospheric Ozone. - 2.7 Particulate Matter (Aerosols). - 2.7.1 Stratospheric Aerosol. - 2.7.2 Chemical Components of Tropospheric Aerosol. - 2.7.3 Cloud Condensation Nuclei (CCN). - 2.7.4 Sizes of Atmospheric Particles. - 2.7.5 Sources of Atmospheric Paniculate. - 2.7.6 Carbonaceous Particles. - 2.7.7 Mineral Dust. - 2.8 Emission Inventories. - 2.9 Biomass Burning. - Appendix 2.1 Air Pollution Legislation. - Appendix 2.2 Hazardous Air Pollutants (Air Toxics). - Problems. - References. - 3 Chemical Kinetics. - 3.1 Order of Reaction. - 3.2 Theories of Chemical Kinetics. - 3.2.1 Collision Theory. - 3.2.2 Transition State Theory. - 3.2.3 Potential Energy Surface for a Bimolecular Reaction. - 3.3 The Pseudo-Steady-State Approximation. - 3.4 Reactions of Excited Species. - 3.5 Termolecular Reactions. - 3.6 Chemical Families. - 3.7 Gas-Surface Reactions. - Appendix 3 Free Radicals. - Problems. - References. - 4 Atmospheric Radiation and Photochemistry. - 4.1 Radiation. - 4.1.1 Solar and Terrestrial Radiation. - 4.1.2 Energy Balance for Earth and Atmosphere. - 4.1.3 Solar Variability. - 4.2 Radiative Flux in the Atmosphere. - 4.3 Beer-Lambert Law and Optical Depth. - 4.4 Actinic Flux. - 4.5 Atmospheric Photochemistry. - 4.6 Absorption of Radiation by Atmospheric Gases. - 4.7 Absorption by O2 and O3 122. - 4.8 Photolysis Rate as a Function of Altitude. - 4.9 Photodissociation of O3 to Produce O and O(1D). - 4.10 Photodissociation of NO2. - Problems. - References. - 5 Chemistry of the Stratosphere. - 5.1 Overview of Stratospheric Chemistry. - 5.2 Chapman Mechanism. - 5.3 Nitrogen Oxide Cycles. - 5.3.1 Stratospheric Source of NO* from N2O. - 5.3.2 NO* Cycles. - 5.4 HO* Cycles. - 5.5 Halogen Cycles. - 5.5.1 Chlorine Cycles. - 5.5.2 Bromine Cycles. - 5.6 Reservoir Species and Coupling of the Cycles. - 5.7 Ozone Hole. - 5.7.1 Polar Stratospheric Clouds. - 5.7.2 PSCs and the Ozone Hole. - 5.7.3 Arctic Ozone Hole. - 5.8 Heterogeneous (Nonpolar) Stratospheric Chemistry. - 5.8.1 The Stratospheric Aerosol Layer. - 5.8.2 Heterogeneous Hydrolysis of N2O5. - 5.8.3 Effect of Volcanoes on Stratospheric Ozone. - 5.9 Summary of Stratospheric Ozone Depletion. - 5.10 Transport and Mixing in the Stratosphere. - 5.11 Ozone Depletion Potential. - Problems. - References. - 6 Chemistry of the Troposphere. - 6.1 Production of Hydroxyl Radicals in the Troposphere. - 6.2 Basic Photochemical Cycle of NO2, NO, and O3. - 6.3 Atmospheric Chemistry of Carbon Monoxide. - 6.3.1 Low NO* Limit. - 6.3.2 High NO* Limit. - 6.3.3 Ozone Production Efficiency. - 6.3.4 Theoretical Maximum Yield of Ozone from CO Oxidation. - 6.4 Atmospheric Chemistry of Methane. - 6.5 The NO* and NOy, Families. - 6.5.1 Daytime Behavior. - 6.5.2 Nighttime Behavior. - 6.6 Ozone Budget of the Troposphere and Role of NO*. - 6.6.1 Ozone Budget of the Troposphere. - 6.6.2 Role of NO*. - 6.7 Tropospheric Reservoir Molecules. - 6.7.1 H2O2, CH3OOH, and HONO. - 6.7.2 Peroxyacyl Nitrates (PANs). - 6.8 Relative Roles of VOC and NOx in Ozone Formation. - 6.8.1 Importance of the VOC/NOx Ratio. - 6.8.2 Ozone Isopleth Plot. - 6.9 Simplified Organic/NOx Chemistry. - 6.10 Chemistry of Nonmethane Organic Compounds in the Troposphere. - 6.10.1 Alkanes. - 6.10.2 Alkenes. - 6.10.3 Aromatics. - 6.10.4 Aldehydes. - 6.10.5 Ketones. - 6.10.6 α, β-Unsaturated Carbonyls. - 6.10.7 Ethers. - 6.10.8 Alcohols. - 6.11 Atmospheric Chemistry of Biogenic Hydrocarbons. - 6.12 Atmospheric Chemistry of Reduced Nitrogen Compounds. - 6.12.1 Amines. - 6.12.2 Nitriles. - 6.12.3 Nitrites. - 6.13 Atmospheric Chemistry (Gas Phase) of Sulfur Compounds. - 6.13.1 Sulfur Oxides. - 6.13.2 Reduced Sulfur Compounds (Dimethyl Sulfide). - 6.14 Tropospheric Chemistry of Halogen Compounds. - 6.14.1 Chemical Cycles of Halogen Species. - 6.14.2 Tropospheric Chemistry of CFC Replacements: Hydrofluorocarbons (HFCs) and Hydrochlorofluorocarbons (HCFCs). - Problems. - References. - 7 Chemistry of the Atmospheric Aqueous Phase. - 7.1 Liquid Water in the Atmosphere. - 7.2 Absorption Equilibria and Henry's Law. - 7.3 Aqueous-Phase Chemical Equilibria. - 7.3.1 Water. - 7.3.2 Carbon Dioxide-Water Equilibrium. - 7.3.3 Sulfur Dioxide-Water Equilibrium. - 7.3.4 Ammonia-Water Equilibrium. - 7.3.5 Nitric Acid-Water Equilibrium. - 7.3.6 Equilibria of Other Important Atmospheric Gases. - 7.4 Aqueous-Phase Reaction Rates. - 7.5 S(IV)-S(VI) Transformation and Sulfur Chemistry. - 7.5.1 Oxidation of S(IV) by Dissolved O3. - 7.5.2 Oxidation of S(IV) by Hydrogen Peroxide. - 7.5.3 Oxidation of S(IV) by Organic Peroxides. - 7.5.4 Uncatalyzed Oxidation of S(IV) by O2. - 7.5.5 Oxidation of S(IV) by O2 Catalyzed by Iron and Manganese. - 7.5.6 Comparison of Aqueous-Phase S(IV) Oxidation Paths. - 7.6 Dynamic Behavior of Solutions with Aqueous-Phase Chemical Reactions. - 7.6.1 Closed System. - 7.6.2 Calculation of Concentration Changes in a Droplet with Aqueous-Phase Reactions. - Appendix 7.1 Thermodynamic and Kinetic Data. - Appendix 7.2 Additional Aqueous-Phase Sulfur Chemistry. - 7.A.1 S(IV) Oxidation by the OH Radical. - 7.A.2 Oxidation of S(IV) by Oxides of Nitrogen. - 7.A.3 Reaction of Dissolved SO2 with HCHO. - Appendix 7.3 Aqueous-Phase Nitrite and Nitrate Chemistry. - 7.A.4 NOx Oxidation. - 7.A.5 Nitrogen Radicals. - Appendix 7.4 Aqueous-Phase Organic Chemistry. - Appendix 7.5 Oxygen and Hydrogen Chemistry. - Problems. - References. - 8 Properties of the Atmospheric Aerosol. - 8.1 The Size Distribution Function. - 8.1.1 The Number Distribution nN(Dp). - 8.1.2 The Surface Area, Volume, and Mass Distributions. - 8.1.3 Distributions Based on In Dp and log Dp. - 8.1.4 Relating Size Distributions Based on Different Independent Variables. - 8.1.5 Properties of Size Distributions. - 8.1.6 The Lognormal Distribution. - 8.1.7 Plotting the Lognormal Distribution. - 8.1.8 Properties of the Lognormal Distribution. - 8.2 Ambient Aerosol Size Distributions. - 8.2.1 Urban Aerosols. - 8.2.2 Marine Aerosols. - 8.2.3 Rural Continental Aerosols. - 8.2.4 Remote Continental Aerosols. - 8.2.5 Free Tropospheric Aerosols. - 8.2.6 Polar Aerosols. - 8.2.7 Desert Aerosols. - 8.3 Aerosol Chemical Composition. - 8.4 Spatial and Temporal Variation. - 8.5 Vertical Variation. - Problems. - References. - 9 Dynamics of Single Aerosol Particles. - 9.1 Continuum and Noncontinuum Dynamics: The Mean Free Path. - 9.2 The Drag on a Single Particle: Stokes' Law. - 9.2.1 Corrections to Stokes' Law: The Drag Coefficient. - 9.2.2 Stokes' Law and Noncontinuum Effects: Slip Correction Factor. - 9.3 Gravitational Settling of an Aerosol Particle. - 9.4 Motion of an Aerosol Particle in an External Force Field. - 9.5 Brownian Motion of Aerosol Particles. - 9.5.1 Particle Diffusion. - 9.5.2 Aerosol Mobility and Drift Velocity. - 9.5.3 Mean Free Path of an Aerosol Particle. - 9.6 Aer

Note: Contents: Introduction. - List of abbreviations. - 1. Balance of energy as a contemporary challenge. - 1.1. Energy resources and needs. - 1.2. Natural gas balance at the beginning of 21st century. - 1.3. Economic and political conditions at the European gas market. - 1.4. European Union facing the problem of energy supplies. - 2. Energy security - Norden - Basic issues. - 2.1. Subject and scope of national energy security. - 2.2. Nordic countries in international life. - 2.3. Norden and the energy issues of the Baltic states. - 2.4. Nordic countries - European Union in the context of energy security. - 3. Basic elements of the energy balance in Norden states. - 3.1. The Republic of Iceland. - 3.2. The Kingdom of Denmark. - 3.3. The Kingdom of Sweden. - 3.4. The Republic of Finland. - 4. Position of the Kingdom of Norway. - 4.1. Norway as an oil and gas producer. - 4.2. Norway in the energy balance of the region. - 4.3. High North - strategy vision and plan of Norway. - 4.4. High North - relations with the Russian Federation in the field of energy. - 5. Energy and climate - directions of activities of countries from Nordic region. - 5.1. Activities concerning energy and environmental protection and climate changes. - 5.2. Research and development - overcoming negative relations between progress and environment degradation. - 5.3. Nordic states versus contemporary energy security challenges. - Conclusion. - Literature. - List of figures and tables.