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  • ddc:600  (37)
  • 551.9  (18)
  • English  (55)
  • Danish
  • 2020-2022  (55)
  • 1
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    Evolution of Magmatism in the New Hebrides Island Arc and in Initial Back-Arc Rifting, SW Pacific (2021)
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    Publication Date: 2021-07-26
    Description: We present new geochemical and isotopic data for rock samples from two island arc volcanoes, Erromango and Vulcan Seamount, and from a 500 m thick stratigraphic profile of lava flows exposed on the SW flank of Vate Trough back-arc rift of the New Hebrides Island Arc (NHIA). The basalts from the SW rift flank of Vate Trough have ages of ~0.5 Ma but are geochemically similar to those erupting along the active back-arc rift. The weak subduction component in the back-arc basalts implies formation by decompression melting during early rifting and rifting initiation by tectonic processes rather than by lithosphere weakening by arc magma. Melting beneath Vate Trough is probably caused by chemically heterogeneous and hot mantle that flows in from the North Fiji Basin in the east. The melting zone beneath Vate Trough back-arc is separate from that of the arc front, but a weak slab component suggests fluid transport from the slab. Immobile incompatible element ratios in South NHIA lavas overlap with those of the Vate Trough depleted back-arc basalts, suggesting that enriched mantle components are depleted by back-arc melting during mantle flow. The slab component varies from hydrous melts of subducted sediments in the Central NHIA to fluids from altered basalts in the South NHIA. The volcanism of Erromango shows constant compositions for 5 million years, that is, there is no sign for variable depletion of the mantle or for a change of slab components due to collision of the D'Entrecasteaux Ridge as in lava successions further north.
    Keywords: 551.9 ; subduction zone ; back-arc basalt ; sediment subduction
    Language: English
    Type: article
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  • 2
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    Sampling soil water along the pF curve for δ2H and δ18O analysis (2021)
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    Publication Date: 2021-07-23
    Description: Soil water stable isotopes are widely used across disciplines (e.g., hydrology, ecology, soil science, and biogeochemistry). However, the full potential of stables isotopes as a tool for characterizing the origin, flow path, transport processes and residence times of water in different eco-, hydro-, and geological compartments has not yet been exploited. This is mainly due to the large variety of different methods for pore water extraction. While recent work has shown that matric potential affects the equilibrium fractionation, little work has examined how different water retention characteristics might affect the sampled water isotopic composition. Here, we present a simple laboratory experiment with two well-studied standard soils differing in their physico-chemical properties (e.g., clayey loam and silty sand). Samples were sieved, oven-dried and spiked with water of known isotopic composition to full saturation. For investigating the effect of water retention characteristics on the extracted water isotopic composition, we used pressure extractors to sample isotopically labelled soil water along the pF curve. After pressure extraction, we further extracted the soil samples via cryogenic vacuum extraction. The null hypothesis guiding our work was that water held at different tensions shows the same isotopic composition. Our results showed that the sampled soil water differed isotopically from the introduced isotopic label over time and sequentially along the pF curve. Our and previous studies suggest caution in interpreting isotope results of extracted soil water and a need to better characterize processes that govern isotope fractionation with respect to soil water retention characteristics. In the future, knowledge about soil water retention characteristics with respect to soil water isotopic composition could be applied to predict soil water fractionation effects under natural and non-stationary conditions. In this regard, isotope retention characteristics as an analog to water retention characteristics have been proposed as a way forward since matric potential affects the equilibrium fractionation between the bound water and the water vapour.
    Keywords: 551.9 ; pF value ; soil water isotopes ; soil water pool ; δ2H and δ18O analysis
    Language: English
    Type: article
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  • 3
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    Cryptic metasomatic agent measured in situ in Variscan mantle rocks: Melt inclusions in garnet of eclogite, Granulitgebirge, Germany (2021)
    Details
    Publication Date: 2021-07-26
    Description: Garnet of eclogite (formerly termed garnet clinopyroxenite) hosted in lenses of orogenic garnet peridotite from the Granulitgebirge, NW Bohemian Massif, contains unique inclusions of granitic melt, now either glassy or crystallized. Analysed glasses and re-homogenized inclusions are hydrous, peraluminous, and enriched in highly incompatible elements characteristic of the continental crust such as Cs, Li, B, Pb, Rb, Th, and U. The original melt thus represents a pristine, chemically evolved metasomatic agent, which infiltrated the mantle via deep continental subduction during the Variscan orogeny. The bulk chemical composition of the studied eclogites is similar to that of Fe-rich basalt and the enrichment in LILE and U suggest a subduction-related component. All these geochemical features confirm metasomatism. In comparison with many other garnet+clinopyroxene-bearing lenses in peridotites of the Bohemian Massif, the studied samples from Rubinberg and Klatschmühle are more akin to eclogite than pyroxenites, as reflected in high jadeite content in clinopyroxene, relatively low Mg, Cr, and Ni but relatively high Ti. However, trace elements of both bulk rock and individual mineral phases show also important differences making these samples rather unique. Metasomatism involving a melt requiring a trace element pattern very similar to the composition reported here has been suggested for the source region of rocks of the so-called durbachite suite, that is, ultrapotassic melanosyenites, which are found throughout the high-grade Variscan basement. Moreover, the Th, U, Pb, Nb, Ta, and Ti patterns of these newly studied melt inclusions (MI) strongly resemble those observed for peridotite and its enclosed pyroxenite from the T-7 borehole (Staré, České Středhoři Mountains) in N Bohemia. This suggests that a similar kind of crustal-derived melt also occurred here. This study of granitic MI in eclogites from peridotites has provided the first direct characterization of a preserved metasomatic melt, possibly responsible for the metasomatism of several parts of the mantle in the Variscides.
    Keywords: 551.9 ; clinopyroxenite ; eclogite ; melt inclusions ; metasomatism ; orogenic peridotite
    Language: English
    Type: article
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  • 4
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    The Preparation and Preliminary Characterisation of Three Synthetic Andesite Reference Glass Materials (ARM-1, ARM-2, ARM-3) for In Situ Microanalysis (2021)
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    Publication Date: 2021-07-27
    Description: Three synthetic reference glasses were prepared by directly fusing and stirring 3.8 kg of high-purity oxide powders to provide reference materials for microanalytical work. These glasses have andesitic major compositions and are doped with fifty-four trace elements in nearly identical abundance (500, 50, 5 µg g−1) using oxide powders or element solutions, and are named ARM-1, 2 and 3, respectively. We further document that sector-field (SF) ICP-MS (Element 2 or Element XR) is capable of sweeping seventy-seven isotopes (from 7Li to 238U, a total of sixty-eight elements) in 1 s and, thus, is able to quantify up to sixty-eight elements by laser sampling. Micro- and bulk analyses indicate that the glasses are homogeneous with respect to major and trace elements. This paper provides preliminary data for the ARM glasses using a variety of analytical techniques (EPMA, XRF, ICP-OES, ICP-MS, LA-Q-ICP-MS and LA-SF-ICP-MS) performed in ten laboratories. Discrepancies in the data of V, Cr, Ni and Tl exist, mainly caused by analytical limitations. Preliminary reference and information values for fifty-six elements were calculated with uncertainties [2 relative standard error (RSE)] estimated in the range of 1–20%.
    Keywords: 551.9 ; glass reference materials ; microanalysis ; sector-field ICP-MS ; LA-ICP-MS ; multiple-element quantification
    Language: English
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  • 5
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    Implications of Reactions Between SO2 and Basaltic Glasses for the Mineralogy of Planetary Crusts (2021)
    Details
    Publication Date: 2021-07-27
    Description: Basalts are ubiquitous in volcanic systems on several planetary bodies, including the Earth, Mars, Venus, and Jupiter's moon Io, and are commonly associated with sulfur dioxide (SO2) degassing. We present the results of an experimental study of reactions between SO2 and basaltic glasses. We examined Fe-free basalt, and Fe-bearing tholeiitic and alkali basalts with a range of Fe3+/Fetotal (0.05 to 0.79) that encompass the oxygen fugacities proposed for most terrestrial planetary bodies. Tholeiitic and alkali basalts were exposed to SO2 at 600, 700, and 800 °C for 1 hr and 24 hr. Surface coatings formed on the reacted basalts; these contain CaSO4, MgSO4, Na2SO4, Na2Ca(SO4)2, Fe2O3, Fe3O4, Fe-Ti-(Al)-oxides, and TiO2. Additionally, the SO2-basalt reaction drives nucleation of crystalline phases in the substrate to form pyroxenes and possible Fe-oxides. A silica-rich layer forms between the substrate and sulfate coatings. More oxidized basalts may readily react with SO2 to form coatings dominated by large Ca-sulfate and oxide grains. On less oxidized basalts (NNO−1.5 to NNO−5), reactions with SO2 will form thin, fine-grained aggregates of sulfates; such materials are less readily detected by spectroscopy and spectrometry techniques. In contrast, in very reduced basalts (lower than NNO−5), typical of the Moon and Mercury, SO2 is typically a negligible component in the magmatic gas, and sulfides are more likely.
    Keywords: 552.26 ; 551.9 ; gas-solid reaction ; sulfur dioxide ; planetary crust ; sulfate ; volcanology ; geochemistry
    Language: English
    Type: article
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  • 6
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    NanoSr – A New Carbonate Microanalytical Reference Material for In Situ Strontium Isotope Analysis (2021)
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    Publication Date: 2021-07-23
    Description: The in situ measurement of Sr isotopes in carbonates by MC-ICP-MS is limited by the availability of suitable microanalytical reference materials (RMs), which match the samples of interest. Whereas several well-characterised carbonate reference materials for Sr mass fractions 〉 1000 µg g−1 are available, there is a lack of well-characterised carbonate microanalytical RMs with lower Sr mass fractions. Here, we present a new synthetic carbonate nanopowder RM with a Sr mass fraction of ca. 500 µg g−1 suitable for microanalytical Sr isotope research (‘NanoSr’). NanoSr was analysed by both solution-based and in situ techniques. Element mass fractions were determined using EPMA (Ca mass fraction), as well as laser ablation and solution ICP-MS in different laboratories. The 87Sr/86Sr ratio was determined by well-established bulk methods for Sr isotope measurements and is 0.70756 ± 0.00003 (2s). The Sr isotope microhomogeneity of the material was determined by LA-MC-ICP-MS, which resulted in 87Sr/86Sr ratios of 0.70753 ± 0.00007 (2s) and 0.70757 ± 0.00006 (2s), respectively, in agreement with the solution data within uncertainties. Thus, this new reference material is well suited to monitor and correct microanalytical Sr isotope measurements of low-Sr, low-REE carbonate samples. NanoSr is available from the corresponding author.
    Keywords: 551.9 ; strontium isotopes ; laser ablation ; reference material ; calcium carbonate ; nanopowder ; MC-ICP-MS
    Language: English
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  • 7
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    Intercalibration of Mg Isotope Delta Scales and Realisation of SI Traceability for Mg Isotope Amount Ratios and Isotope Delta Values (2021)
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    Publication Date: 2021-07-21
    Description: The continuous improvement of analytical procedures using multi-collector technologies in ICP-mass spectrometry has led to an increased demand for isotope standards with improved homogeneity and reduced measurement uncertainty. For magnesium, this has led to a variety of available standards with different quality levels ranging from artefact standards to isotope reference materials certified for absolute isotope ratios. This required an intercalibration of all standards and reference materials, which we present in this interlaboratory comparison study. The materials Cambridge1, DSM3, ERM-AE143, ERM-AE144, ERM-AE145, IRMM-009 and NIST SRM 980 were cross-calibrated with expanded measurement uncertainties (95% confidence level) of less than 0.030‰ for the δ25/24Mg values and less than 0.037‰ for the δ26/24Mg values. Thus, comparability of all magnesium isotope delta (δ) measurements based on these standards and reference materials is established. Further, ERM-AE143 anchors all magnesium δ-scales to absolute isotope ratios and therefore establishes SI traceability, here traceability to the SI base unit mole. This applies especially to the DSM3 scale, which is proposed to be maintained. With ERM-AE144 and ERM-AE145, which are product and educt of a sublimation–condensation process, for the first time a set of isotope reference materials is available with a published value for the apparent triple isotope fractionation exponent θapp, the fractionation relationship ln α(25/24Mg)/ln α(26/24Mg).
    Keywords: 551.9 ; delta scale ; traceability ; scale anchor ; absolute isotope ratio ; comparability ; triple isotope fractionation
    Language: English
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  • 8
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    Comparison of the effects of industrial demand side management and other flexibilities on the performance of the energy system (2020)
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    Publication Date: 2021-05-06
    Description: In order to ensure security of supply in a future energy system with a high share of volatile electricity generation, flexibility technologies are needed. Industrial demand-side management ranks as one of the most efficient flexibility options. This paper analyses the effect of the integration of industrial demand-side management through the flexibilisation of aluminium electrolysis and other flexibilities of the electricity system and adjacent sectors. The additional flexibility options include electricity storage, heat storage in district heating networks, controlled charging of electric vehicles, and buffer storage in hydrogen electrolysis. The utilisation of the flexibilities is modelled in different settings with an increasing share of renewable energies, applying a dispatch model. This paper compares which contributions the different flexibilities can make to emission reduction, avoidance of curtailment, and reduction of fuel and CO2 costs, and which circumstances contribute to a decrease or increase of overall emissions with additional flexibilities. The analysis stresses the rising importance of flexibilities in an energy system based on increasing shares of renewable electricity generation, and shows that flexibilities are generally suited to reduce carbon emissions. It is presented that the relative contribution towards the reduction of curtailment and costs of flexibilisation of aluminium electrolysis are high, whereby the absolute effect is small compared to the other options due to the limited number of available processes.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: article , doc-type:article
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  • 9
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    Resource efficiency and the circular economy in Europe 2019 : even more from less ; an overview of the policies, approaches and targets of 32 European countries (2020)
    Publications Office of the European Union : Luxembourg
    Details
    Publication Date: 2020-08-03
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: report , doc-type:report
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  • 10
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    Water scenarios modelling for renewable energy development in southern Morocco (2020)
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    Publication Date: 2021-05-06
    Description: Water and energy are two pivotal areas for future sustainable development, with complex linkages existing between the two sectors. These linkages require special attention in the context of the energy transition. Against this background, this paper analyses the role of water availability in the development of solar thermal and photovoltaic power plants for the case of the Draa Valley in southern Morocco. Located in a semi-arid to arid mountainous area, the Drâa Valley faces high water stress - a situation expected to worsen due to climate change. At the same time, the region has one of the greatest potentials for solar energy in the world. To examine whether limited water availability could accelerate or delay the implementation of solar thermal and photovoltaic power plants, this paper compares regional water availability and demand in the Draa Valley for different scenarios, paying particular attention to potential socio-economic development pathways. The Water Evaluation and Planning System software is applied to allocate the water resources in the study region. The water supply is modelled under the Representative Concentration Pathway 8.5 climate scenario, while the water demand for the Drâa Valley is modelled for a combination of three socio-economic and two energy scenarios. The climate scenario describes a significant decrease in water availability by 2050, while the socio-economic and energy scenarios show an increase in water demand. The results demonstrate that during a sequence of dry years the reservoirs water availability is reduced and shortages in water supply can result in high levels of unmet demand. If this situation occurs, oasis farming, water for drinking and energy production could compete directly with each other for water resources. The energy scenarios indicate that the use of dry cooling technologies in concentrated solar power and photovoltaic hybrid systems could be one option for reducing competition for the scarce water resources in the region. However, given that energy generation accounts for only a small share of the regional water demand, the results also suggest that socio-economic demand reduction, especially in the agricultural sector, for example by reducing the cultivated area, will most likely become necessary.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: article , doc-type:article
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