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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 264 (1986), S. 1010-1016 
    ISSN: 1435-1536
    Keywords: Oriented polymers ; elastic anisotropy ; aggregate model ; orientation parameters
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A reinvestigation of the single phase aggregate model (SPAM) of Ward applied to the elastic properties of uniaxially oriented polymers is presented. It is shown that the Voigt and the Reuss orientation average of elastic constants can be represented as a linear transformation in a 5-dimensional vector space. The corresponding transformation matrix can be diagonalized, showing that the eigenvalues of this transformation are the orientation parametersP 0 =1,P 2 andP 4 . Taking advantage of this representation an easy test of applicability of the SPAM is proposed. Possibilities to evaluate the SPAM parameters are reviewed.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1435-1536
    Keywords: Polycarbonate ; oriented polymers ; elastic and optical anisotropy ; Brillouin spectroscopy ; aggregate model ; orientation parameters
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract High resolution Brillouin spectroscopy (BS) has been used to investigate elastic and optical properties of uniaxially drawn samples of polycarbonate (PC). The results are discussed in the framework of the single phase aggregate model (SPAM) of Ward. According to a recently developed evaluation technique, the SPAM parameters of PC are determined, resulting in the following elastic constants of the structural units:c 33 0 =33 GPa,c 11 0 =7 GPa,c 13 0 =9.7 GPa,c 44 0 =1.4 GPa, andc 66 0 =1 GPa. A nearly quadratic dependence of the orientation parameterP 4 onP 3 results, which can be explained by a modified pseudoaffine deformation scheme.
    Type of Medium: Electronic Resource
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