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  • Articles  (68,341)
  • 2000-2004  (68,341)
  • Energy, Environment Protection, Nuclear Power Engineering  (68,341)
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  • Articles  (68,341)
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  • 1
    Electronic Resource
    Electronic Resource
    Field Tests of a DNAPL Characterization System Using Cone Penetrometer-Based Raman Spectroscopy (2000)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 20 (2000), S. 0 
    Details
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Cone penctrometer test (CPT) based Raman spectroscopy was used to identify separate phase tetrachloroethylene (PCE) and trichlorocthylene (TCE) contamination in the subsurface at two locations during field tests conducted at the U.S. Department of Energy's (DOE) Savannah River site. Clear characteristic Raman spectral peaks for PCE and TCE were observed at two sites and several depths during CPT deployment. Because of the uniqueness of a Raman spectrum for a given compound, these data are compelling evidence of the presence of the two compounds. The Raman spectral results correlated with high PCE and TCE concentrations in soil samples collected from the same subsurface zones, confirming that the method is a viable dense nonaqueous phase liquid (DNAPL) characterization technique. The Raman spectroscopic identification of PCE and TCE in these tests represents the first time that DNAPLs have been unequivocally located in the subsurface by an in situ technique.The detection limit of the Raman spectroscopy is related to the probability of contaminant droplets appearing on the optical window in the path of the probe light. Based on data from this fieldwork the Raman technique may require a threshold quantity of DNAPL to provide an adequate optical cross section for spectroscopic response. The low aqueous solubility of PCE and TCE and relatively weak optical intensity of the Raman signal precludes the detection of aqueous phase contaminants by this method, making it selective for DNAPL contaminants only.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6592.2000.tb00291.x
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  • 2
    Electronic Resource
    Electronic Resource
    Recent Examples of Pesticide Assessment and Regulation Under FQPA (2000)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 20 (2000), S. 0 
    Details
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6592.2000.tb00248.x
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  • 3
    Electronic Resource
    Electronic Resource
    Looking Forward (2000)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 20 (2000), S. 0 
    Details
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6592.2000.tb00250.x
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  • 4
    Electronic Resource
    Electronic Resource
    Decontaminating Materials Used in Ground Water Sampling Devices: Organic Contaminants (2000)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 20 (2000), S. 0 
    Details
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: In these studies, the efficiency of various decontamination protocols was tested on small pieces of materials commonly used in ground water sampling devices. Three materials, which ranged in ability to sorb organic solutes, were tested: stainless steel (SS), rigid polyvinyl chloride (PVC), and polytetrafluoroethylene (PTFE). The test pieces were exposed to two aqueous test solutions: One contained three volatile organic compounds (VOCs) and one nitroaromatic compound, and the other contained four pesticides. Also, three types of polymeric tubing were exposed to pesticide solutions. Generally, the contact times were 10 minutes and 24 hours for sorption and desorption.The contaminants were removed from the nonpermeable SS and the less-sorptive rigid PVC test pieces simply by washing with a hot detergent solution and rinsing with hot water. Additional treatment was required for the PTFE test pieces exposed to the VOCs and for the low-density polyethylene (LDPE) tubing exposed to the pesticide test solution. Solvent rinsing did not improve removal of the three VOCs from the PTFE and only marginally improved removal of the residual pesticides from the LDPE. However, a hot water and detergent wash and rinse followed by oven drying at approximately 105°C was effective for removing the VOCs from the PTFE and substantially reduced pesticide contamination from the LDPE.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6592.2000.tb00252.x
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  • 5
    Electronic Resource
    Electronic Resource
    An Evaluation of Horizontal Recirculation Using Single-Well Tests, Pumping Tests, Tracer Tests, and the Colloidal Borescope (2000)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 20 (2000), S. 0 
    Details
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Extensive hydrodynamic testing was performed as part of a program to evaluate horizontal recirculation as a means of removing contaminants from thin, interbedded aquifers. Two test sites, each containing a pair of horizontal recirculation wells, were evaluated using various hydraulic tests. Results of these evaluations showed that ground water was intercepted more than 100 feet beyond the wells, and that the hydraulic gradient increased by more than two orders of magnitude. Aquifer heterogeneity, however, controlled the efficiency and uniformity of ground water flow. Heterogeneity was assessed with a variety of techniques. Bromide tracer tests and the colloidal borescope provided the most useful data. For example, at an uncontaminated site, the leading edge of the bromide tracer traversed the 100 feet between the injection and extraction wells in 21 hours, and the peak bromide concentration was observed in 2.6 days, compared with the four days predicted by a pumping test. The resulting maximum velocity calculation was consistent with measurements made with the borescope in preferential flow zones. Data obtained from a highly contaminated location indicated that assessments of aquifer heterogeniety are further complicated by the presence of DNAPL. Very low flow occurred in a highly contaminated zone, despite the fact that lithologic descriptions indicated that this region contained permeable sand and gravel.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6592.2000.tb00254.x
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  • 6
    Electronic Resource
    Electronic Resource
    Elements in Cottonwood Trees as an Indicator of Ground Water Contaminated by Landfill Leachate (2000)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 20 (2000), S. 0 
    Details
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Ground water at the Norman Landfill Research Site is contaminated by a leachate plume emanating from a closed, unlined landfill formerly operated by the city of Norman, Oklahoma, Ground water contaminated by the leachate plume is known to be elevated in the concentration of many, organic and inorganic constituents. Specific conductance, alkalinity, chloride, dissolved organic carbon, boron, sodium, strontium, and deuterium in ground water are considered to be indicators of the leachate plume at this site.Leaf samples of broad-leafed cottonwood, Populus deltoides, were collected from 57 sites around the closed landfill. Cottonwood, a phreatophyte or “well plant,” functions as a & surrogate well and serves as a ground water quality sampler. The leaf samples were combusted to ash and analyzed by instrumental neutron activation for 35 elements and by prompt-gamma instrumental neutron activation, for boron. A monitoring well was located within a few meters of a sampled cottonwood tree at 15 of the 57 sites, and ground water samples were collected from these monitoring wells simultaneously with a leaf sample. The chemical analyses of the ground water and leaf samples from these 15 sites indicated that boron, bromine, sodium, and strontium concentrations in leaves were significantly correlated with leachate indicator constituents in ground water. A point-plot map of selected percentiles indicated high concentrations of boron, bromine, and sodium in leaf ash from sites downgradient of the most recent landfill and from older landfills nearby.Data from leaf analysis greatly extended the known areal extent of the leachate plume previously determined from a network of monitoring wells and geophysical surveys. This phytosgeochemical study provided a cost-effective method for assessing the extent of a leachate plume from an old landfill. Such a method may be useful as a preliminary sampling tool to guide the design of hydrogeochemical and geophysical studies.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6592.2000.tb00258.x
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  • 7
    Electronic Resource
    Electronic Resource
    A County-Level Assessment of Ground Water Contamination by Pesticides (2000)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 20 (2000), S. 0 
    Details
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: A pesticide screening model was integrated with a geographic information system (GIS) for evaluating the ground water vulnerability to pesticide contamination in Albemarle County, Virginia. The attenuation factor (AF). an index of pesticide mass emission from the vadose zone, was used to evaluate the relative contamination potential of 70 pesticides used in the county. Results for only three pesticides—atrazine, dicamba, and lindane—are discussed in this paper. Spatial (land use, soils, and hydrogeology) and relational (soil and pesticide properties) data layers were combined with the AF model within the GIS environment for spatial computation of AF for actual and 2 m ground water depths. For each pesticide, a ground water vulnerability map with five contamination potential categories (high, medium, low, very low, and unlikely) was generated, based on the spatial distribution of AF for each cell size of 0.27 acre (0.11 ha). To consider the variability in pesticide transport, model simulations were performed for “maximum,”“average,” and “minimum” scenarios of pesticide leaching. Under the average leaching scenario (2 m depth), the three pesticides were found to have very low to low levels of contamination potential in some areas. For maximum leaching scenario (2 m depth), contamination potential of these three pesticides increased to low to medium levels. When actual ground water depth was used, no significant contamination potential was indicated by any of the three pesticides. The modeling approach was evaluated using the data from a limited monitoring study in Albemarle County. Although agreement between the model prediction and actual pesticide detection was observed, extent of the data was not sufficient enough to draw firm conclusions about the model's success in predicting contamination potential. A sensitivity analysis of the methodology revealed that significant uncertainty can be involved in predicting the county-scale contamination potential. To make better use of this study, it is recommended that a comprehensive pesticide monitoring be undertaken in Albemarle County.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6592.2000.tb00257.x
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  • 8
    Electronic Resource
    Electronic Resource
    News Briefs/ (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 24 (2004), S. 0 
    Details
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6592.2004.tb01301.x
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  • 9
    Electronic Resource
    Electronic Resource
    Got NAPL? (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 24 (2004), S. 0 
    Details
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6592.2004.tb01300.x
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  • 10
    Electronic Resource
    Electronic Resource
    Real-Time Analysis of Small Volume Samples with Micro Ion-Selective Electrodes (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water monitoring & remediation 24 (2004), S. 0 
    Details
    ISSN: 1745-6592
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Microelectrode and micro ion-selective electrode (ISE) technologies were applied to obtain real-time analysis of pH, Eh, and major ions (Cl−, Na+, Ca2+ and K+) in pore water samples. The precision and accuracy of micro ISEs were significantly improved by standardizing the solution matrix, accounting for electrode drift and implementing an iterative calibration procedure with analyses of selected samples by conventional techniques. Reliable results were obtained for a chemically complex pore water effluent which ranged in concentration from 〈 5 to 500 mmol/L. Although labor intensive, this procedure enabled real-time analysis of samples from a column test of very low permeability clay-rich till, which produced effluent sample volumes of only 0.2 to 0.5 mL/d.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6592.2004.tb01303.x
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