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  • Physics  (3,116)
  • 1995-1999  (576)
  • 1975-1979  (2,540)
  • 1
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    Electronic preprints point the way to 'author empowerment' (1996)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1996-02-09
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Taubes, G -- New York, N.Y. -- Science. 1996 Feb 9;271(5250):767-8.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/8628989" target="_blank"〉PubMed〈/a〉
    Keywords: Behavioral Sciences ; *Computer Communication Networks ; Costs and Cost Analysis ; Peer Review, Research ; *Periodicals as Topic/economics/standards ; Physical Phenomena ; Physics ; *Publishing/economics/standards
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
    Published by American Association for the Advancement of Science (AAAS)
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    PAPER CURRENT
  • 2
    Electronic Resource
    Electronic Resource
    Dual-mode free volume model for diffusion of gas molecules in glassy polymers (1997)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 1737-1746 
    Details
    ISSN: 0887-6266
    Keywords: free volume ; dual mode ; diffusion ; glassy polymer ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The development of a new model for the diffusion of gas molecules in glassy polymers is presented which utilizes concepts from free volume theory and relies on a dual-mode interpretation of sorptive dilation in glassy polymers. Three assumptions are made in the development of the model. First, the free volume available for molecular transport processes is taken as constant below the glass transition temperature. Second, two populations of gas molecules are assumed to exist - one which contributes to the maintenance of an iso-free volume state upon sorptive dilation and one which does not contribute owing to sorption into regions of unrelaxed volume. Third, the former population is assumed to be mobile while the latter is not. The resulting model predicts, at constant temperature, a diffusion coefficient that is independent of solute volume fraction. This is in contrast to the widely used dual-mode sorption model with partial immobilization for gas transport in glassy polymers which leads to a diffusion coefficient that is dependent on solute mole fraction through the molar gas concentration. The new model is used to interpret gas transport data from permeation experiments for carbon dioxide, methane, and ethylene in three polycarbonates. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 1737-1746, 1997
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 3
    Electronic Resource
    Electronic Resource
    Surface modification strategies for multicomponent polymer systems, Part I: Use of diblock copolymers as surface modifiers of rutile (1997)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 1793-1805 
    Details
    ISSN: 0887-6266
    Keywords: rutile ; surface modification ; diblock copolymer ; inverse gas chromatography ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Various functional diblock copolymers have been used as surface modifiers for rutile pigment in an effort to condition the solid for eventual use in multicomponent polymer systems. Coated surfaces were analyzed by inverse gas chromatography at infinite and finite dilution of the vapor phase, and by XPS. At high coverages (about 10% by weight of the pigment), the diblocks were randomly oriented at the air interface, effectively masking the surface of the rutile. At low diblock concentrations acid/base interactions dominated the orientation of the adsorbed molecule at the rutile interface, thereby also affecting the orientational states at the air interface. In this condition, the performance of the pigment in specified host polymer systems may be expected to vary with the selection of the diblock copolymer modifier. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 1793-1805, 1997
    Additional Material: 5 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    The phase morphology and crystal growth habits of DNA fractions. Optical microscopy and light scattering (1997)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 1843-1854 
    Details
    ISSN: 0887-6266
    Keywords: crystallization ; DNA ; fractionation ; gel-electrophoresis ; morphology ; phase transition ; SALLS ; sonication ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Polydisperse DNA of reasonable molecular weights was prepared from a mammalian source via sonication and fractionation. A method for characterizing the molecular weight using gel electrophoresis is described. Quiescent crystallization was studied in thin films of one of the fractions induced by rapidly changing the hydration state isothermally. We report the occurrence of the semicrystalline nature of DNA. The crystal growth occurring via aggregates is best described as sheaves and spherulites from DNA gels in the relative humidity range (RH) corresponding to A-DNA. These habits exhibit primary nucleation and secondary growth, which closely resemble those of melt-crystallized, synthetic macromolecules and, in a follow-up report, will be shown to be lamellar in nature. Small, needle-like crystals are observed for B-DNA hydration levels, and are unstable at lower hydration levels. A transformation from needle to lamellar crystals can occur, even when the primary nucleation of lamellar forms is otherwise absent at that hydration level, through a cylindrical phase exhibiting selective reflection of colored bands. The hydration level plays, in part, the role of the supercooling in this system and the long-known hysteresis in the formation and dissolution of the A-DNA (crystals) can now be viewed in light of those factors known to operate in semicrystalline systems. A morphological phase diagram is developed and is in accord with the known physical evidence. Because this preparation and these morphological observations are without precedence, substantial detail into methodology is included for this first article in the series. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 1843-1854, 1997
    Additional Material: 10 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    The first 85% kraft lignin-based thermoplasticsPaper No. 22,538 of the Scientific Journal Series of the Minnesota Agricultural Experiment Station, funded through Minnesota Agricultural Experiment Station Project No. 43-68, supported by Hatch Funds. (1997)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 1899-1910 
    Details
    ISSN: 0887-6266
    Keywords: kraft lignin ; thermoplastics ; polymer association ; poly(vinyl acetate) ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Interest in the development of lignin-containing polymeric materials has been upheld more or less continuously for the past 20 years. Tendencies toward high moduli and poorly defined thermal transitions have been regarded as imposing inevitable limitations upon the use of lignin derivatives for such purposes. Incorporation of more than 25-40% (w/w) lignin had usually resulted in materials that were brittle and weak. For the first time, however, from homogeneous blends containing 85% (w/w) underivatized industrial kraft lignin with poly(vinyl acetate) and two plasticizers, a series of thermoplastics has been fabricated with promising mechanical properties. The tensile behavior of these new polymeric materials depends directly upon the degree of association between the intrinsic kraft lignin components. In extending to values about 25 MPa and 1.5 GPa, respectively, the tensile strengths and Young's moduli vary linearly with the effective M̄w for the kraft lignin species, under conditions where the proportions of the individual molecular components, both associated and discrete, do not change. Moreover, melt-flow index measurements indicate that these polymeric materials are amenable to thermal processing by extrusion molding. Thus a significant step has been taken toward developing a new generation of thermoplastics that are lignin-based in a very fundamental way. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 1899-1910, 1997
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Viscoelasticity and self-diffusion in melts of entangled linear polymers (1997)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 1933-1942 
    Details
    ISSN: 0887-6266
    Keywords: self-diffusion ; viscosity ; polymer melt ; entanglement ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Dynamic properties in the melt state for two saturated hydrocarbon polymers, poly(ethylene-alt-propylene) (PEP) and head-to-head polypropylene (HHPP), were investigated by viscoelastic and diffusion measurements. Several nearly monodisperse linear samples of each species were used. Zero-shear viscosity η0 and self-diffusion coefficient D varied with temperature in accord with the WLF equation, and they also varied with molecular weight M in a manner that was consistent with the behavior of other species. The product η0D was of particular interest because extensive previous results for two other species, polystyrene and polyethylene, had led Pearson et al. to suggest that η0D/(η0D)Rouse is a universal function of the number of entanglements per molecule M/Me. With values for the Rouse model product for each species calculated from chain dimensions, and entanglement molecular weight from the plateau modulus, we show that the data for PEP and HHPP also support the Pearson universal form. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 1933-1942, 1997
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Dynamic mechanical behavior of fluorinated aromatic poly(ethers) (1997)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 1963-1971 
    Details
    ISSN: 0887-6266
    Keywords: dynamic mechanical analysis ; fluorinated poly(ethers) ; intermolecular cooperativity ; relaxation behavior ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The relaxation behavior of six fluorinated aromatic poly(ethers) was investigated using dynamic mechanical analysis. The glass transition temperature was found to increase as the size and rigidity of linking groups increased and varied between 168°C for a dimethyl linking group and 300°C for a bicyclic benzoate ether-linking group. For the α-relaxation the steepness of time/temperature plots and broadness of the loss curves could be qualitatively correlated with chemical structure in a manner predicted by the coupling model of relaxation. Well-separated sub-Tg transitions were also observed, as a shoulder on the low temperature side of the α-peak, and as a broad, low loss transition around -100°C. The higher temperature process was similar to the structural relaxation often found in quenched glassy polymers, while the position, intensity, and breadth of the subambient process was sensitive to chemical structure. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 1963-1971, 1997
    Additional Material: 7 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    FTIR studies of conformational energies of poly(acrylic acid) in cast films (1997)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 507-515 
    Details
    ISSN: 0887-6266
    Keywords: poly(acrylic acid) ; FTIR ; polyelectrolyte ; conformation ; conformers ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Fourier transform infrared (FTIR) spectroscopic measurements have been undertaken to estimate the conformational energies of poly(acrylic acid) (PAA) cast films in the temperature range of 40-130°C. The temperature dependence of the IR spectra in the C=O stretching region has been analyzed to yield the side-chain and backbone conformational energies. The estimated energies are close to those previously obtained by polarized Raman spectroscopic measurements for PAA solutions. Combining the FTIR value of conformational energy with the simplified rotational isomeric state (RIS) model proposed in the Raman analysis provides a persistence length in accordance with earlier SAXS experiments. The data also agree with the Gibbs-DiMarzio predictions, further substantiating the validity of the analysis. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys, 35: 507-515, 1997
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  • 9
    Electronic Resource
    Electronic Resource
    Computer-simulation analysis of the ESR spectra of mechanoradicals in PMMA (1997)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 2195-2200 
    Details
    ISSN: 0887-6266
    Keywords: ESR ; mechanoradicals ; PMMA ; drilling apparatus ; computer simulation ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: In this study, initially, we tried to obtain the mechanoradicals of PMMA (poly(methyl methacrylate)). For this purpose, we designed a simple drilling apparatus. Using this apparatus, we prepared some PMMA samples at 77 K in vacuum. Later, by using an ESR (electron spin resonance spectrometer), we observed ESR signals for these samples at 77 K. This means that mechanoradicals have been successfully produced by mechanical fracture in PMMA using our drilling apparatus. Secondly, we tried to identify the radicals from these spectra through using theoretical analyses and, some computer simulations have been done by suggesting two different theoretical models for these ESR signals. Finally, by using experimental and theoretical data, we showed that our simple apparatus could be used to obtain mechanoradicals from polymers. Results were seen to be in very good agreement with the literature. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 2195-2200, 1997
    Additional Material: 5 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Measurement of crystalline index in nylons by DSC: Complexities and recommendations (1997)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 2219-2231 
    Details
    ISSN: 0887-6266
    Keywords: nylons ; crystallinity ; DSC ; x-ray diffraction ; complications ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Differential scanning calorimetry (DSC) is one of the most widely used technique for measuring crystallinity in the polymer industry. The major source of error in the crystalline index (CIDSC) of low crystallinity polymeric articles, is the development of further crystallinity during the DSC scan. Although, this type of cold crystallization is obvious, and thus accounted for in polymers like polyethylene terephthalate, nylons are a difficult class of materials in that respect. The major contributing factors to the failure of DSC in measuring low levels of crystallinity in nylons are identified to be (1) silent crystallization between the glass (Tg) and melting (Tm) transitions, (2) extreme difficulties in packing a moisture-free nylon in the sample pan (the response due to traces of moisture being a broad endotherm competing with a broad exothermic crystallization), and (3) a sub-Tm exotherm, especially in low crystallinity nylons, due to relaxation of the processing-induced stresses. These factors, specific to nylons, mask the observation of cold crystallization and lead to substantially higher than real crystallinities. This manuscript deals with such complications and corrective actions using commercial nylon 6 films of CIDSC = 0-40%. X-ray diffraction measurements have been included to support the validity of our improved DSC methodology. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 2219-2231, 1997
    Additional Material: 9 Ill.
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