ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Chromatography
  • Springer  (43)
  • American Chemical Society  (1)
  • 1
    Publication Date: 2022-05-27
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Gosselin, K. M., Nelson, R. K., Spivak, A. C., Sylva, S. P., Van Mooy, B. A. S., Aeppli, C., Sharpless, C. M., O’Neil, G. W., Arrington, E. C., Reddy, C. M., & Valentine, D. L. Production of two highly abundant 2-methyl-branched fatty acids by blooms of the globally significant marine cyanobacteria Trichodesmium erythraeum. ACS Omega, 6(35), (2021): 22803–22810, https://doi.org/10.1021/acsomega.1c03196.
    Description: The bloom-forming cyanobacteria Trichodesmium contribute up to 30% to the total fixed nitrogen in the global oceans and thereby drive substantial productivity. On an expedition in the Gulf of Mexico, we observed and sampled surface slicks, some of which included dense blooms of Trichodesmium erythraeum. These bloom samples contained abundant and atypical free fatty acids, identified here as 2-methyldecanoic acid and 2-methyldodecanoic acid. The high abundance and unusual branching pattern of these compounds suggest that they may play a specific role in this globally important organism.
    Description: This work was funded with grants from the National Science Foundation grants OCE-1333148, OCE-1333162, and OCE-1756254 and the Woods Hole Oceanographic Institution (IR&D). GCxGC analysis made possible by WHOI’s Investment in Science Fund.
    Keywords: Lipids ; Alkyls ; Bacteria ; Genetics ; Chromatography
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 116 (1985), S. 1129-1132 
    ISSN: 1434-4475
    Keywords: Chromatography ; “Binary solutions” model ; Activity coefficients
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract An explanation is given for the two possible ways of determination of the activity coefficients of solutes, when applying a new thermodynamic model of adsorption and partition chromatography, i. e. the “binary solutions” model.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    ISSN: 1572-8773
    Keywords: Ferritin ; Chromatography ; Fe/P ratio ; Electron probe microanalysis ; Electron spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Summary Cytosolic and lysosomal ferritin and haemosiderin were isolated from rat livers which had been iron-loaded by four intraperitoneal injections of iron-dextran. The cytosolic and lysosomal ferritins, prepared in a phosphate-free medium, were subjected to gel-filtration chromatography on Sepharose 613, yielding four fractions: a cytosolic monomeric (CMF) and void-volume ferritin fraction (CVVF), and a lysosomal monomeric (LMF) and void-volume ferritin fraction (LVVF). Of each fraction the following aspects were examined: (a) immunoreactivity against specific antiserum; (b) the Fe/P mass ratio and the effect of dialysis on this ratio using electron probe micro-analysis (EPMA); (c) morphology and Fespecific imaging using electron spectroscopic imaging (ESI) and electron energy loss spectroscopy (EELS). For haemosiderin one aspect, the Fe/P ratio, was determined before and after extensive purification. The following results were obtained (a) All ferritin fractions reacted with anti- (rat liver ferritin). (b) The Fe/P ratios as determined in CMF in an haemosiderin were not affected by dialysis or extensive purification, respectively. The Fe/P ratio in CWF was affected by dialysis. In the lysosomal fractions, only a trace of phosphorus (LVVF) or no phosphorus (LMF) was detected. (c) Morphologically, CMF and CVVF were found to be rather homogeneous; the iron core diameters of both fractions were in the known size range. LMF and LVVF were of rather heterogeneous composition; the core diameters of these fractions were different. In conclusion: the phosphorus in ferritin and haemosiderin is firmly bound; Haemosiderin, when derived from ferritin, has to take up phosphorus in the lysosomes.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 117 (1986), S. 471-474 
    ISSN: 1434-4475
    Keywords: Chromatography ; Binary solutions model ; Solubility ; Thermodynamics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Die physikalisch-chemische Basis einer direkten chromatographischen Bestimmung der Löslichkeit von schwerlöslichen Substanzen mit Hilfe der Adsorptions- und Verteilungsdünnschichtchromatographie wird diskutiert. Die Möglichkeit einer solchen Bestimmung ist die praktische Konsequenz des chromatographischen Modells der „binären Lösungen”, einer neuen semiempirischen, auf der phänomenologischen Thermodynamik begründeten Methode.
    Notes: Abstract The physico-chemical basis for a direct chromatographic determination of solubility of low soluble substances by means of adsorption and partition TLC is discussed. This method is a practical consequence of the chromatographic “binary solutions” model, a new semi-empirical approach based on phenomenological thermodynamics.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 118 (1987), S. 879-882 
    ISSN: 1434-4475
    Keywords: Chromatography ; Solubility determination ; Thermodynamics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung An den gewählten Beispielen wird die Bestimmung der Löslichkeit schwerlöslicher Substanzen mit Hilfe der planaren Dünnschichtchromatographie demonstriert. Dieses Verfahren stellt eine neue, einfache und schnelle Methode dar, die in einem gewissen Maß in Konkurrenz zu den älteren und anerkannten Methoden tritt. Die Methode ist die praktische Konsequenz der thermodynamischen Betrachtung des chromatographischen Prozesses in der Adsorptions- und Verteilungsdünnschichtchromatographie.
    Notes: Abstract Using selected examples we demonstrate the determination of solubility of low soluble substances with the help of planar chromatography, which is a new, simple and rapid approach to the problem, to a certain extent challenging the established methods. Our approach is a practical consequence of the thermodynamic view of the chromatographic processes, involving either the adsorption or partition mechanism of separation.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Methods in cell science 16 (1994), S. 223-226 
    ISSN: 1573-0603
    Keywords: Adhesive proteins ; Chromatography ; Purification ; Von Willebrand factor
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary Von Willebrand factor (vWF) and fibronectin (Fn), as a by-product, were prepared from human plasma cryoprecipitate by a three-step chromatographic procedure. The respective final products were concentrated (80 U RCo/ml and 5 g/l, respectively), highly purified (specific activity 〉180 U RCo/mg protein and 〉95%, respectively) and biologically active.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of biomedical science 4 (1997), S. 315-318 
    ISSN: 1423-0127
    Keywords: Hemoglobin variant ; Hemoglobinopathy ; High-performance liquid chromatography ; Cation exchange ; Chromatography
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract This report describes a unique cation exchange high-performance liquidchromatography capable of separating more than 40 frequently encountered human hemoglobins and variants within 12 min. Some of these variants are unresolvable by the conventional electrophoretic methods and would thus lead to an incorrect diagnosis of hemoglobinpathy. The method provides high sensitivity, superior resolution and accurate quantitation of hemoglobin concentrations. It can also be fully automated thus make it an ideal methodology for the diagnosis of hemoglobin disorders in a routine clinical laboratory.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Accreditation and quality assurance 5 (2000), S. 180-181 
    ISSN: 1432-0517
    Keywords: Key words Selectivity ; Specificity ; Chromatography
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract   Analytical chemists should be aware of the differences between selectivity and specificity. Few analytical methods, including the chromatographic analytical methods, are truly specific. The International Union of Pure and Applied Chemistry (IUPAC) recommends that specificity is the ultimate of selectivity, therefore, analysts should promote this concept and aim to achieve highly selective analytical methods.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geology 34 (1998), S. 31-38 
    ISSN: 1432-0495
    Keywords: Key words Spectroscopy ; Chromatography ; Species ; Selenium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Aqueous extracts of five mine soil samples and a set of selenite (SeO3 2–)–selenate (SeO4 2–) solutions (0.5, 1, 5, 10 and 25 mg/l) were speciated using atomic absorption spectroscopy with hydride generation (AAS-HG) and ion chromatography (IC) to compare these methods for Se speciation. In another experiment, a SeO3 2––SeO4 2––SO4 2– solution (25 mg/l) was reacted with CaO, MgO, MnO2, CuO, La2O3, and WO3 to evaluate the relative distribution of the Se species and SO4 2– in the SORB (sorbed ions that were desorbed by NaOH), SOLN (equilibrium concentrations), CMPX (irreversibly sorbed and neutral ion pair complexes) fractions. The AAS-HG method was capable of analyzing Se as low as 0.002 mg/l, which was below the detection limit of IC. High concentration of SO4 2– affected the chromatographic Se speciation either by shifting or overlapping Se peaks, in which AAS-HG was more useful. However, IC was capable of speciating aqueous SeO3 2––SeO4 2– directly without any sample pretreatment, whereas AAS-HG measured SeO3 2–+SeO4 2–, and SeO3 2– in separate runs and SeO4 2– was calculated from the difference, i.e., spectrophotometric speciation was an indirect method. For both Se species, AAS-HG and IC data were comparable within detection standard deviations. Ratios of different Se species at measured soil pH and pe indicated that SeO3 2– or SeO4 2– would be the dominant Se species; the p(SeO4 2–/SeO3 2–) values further suggested SeO4 2– would be the major solution species. Except for CaO and MgO treatments, the %SeO3 2– in the SORB fraction was ≥%SeO4 2–. In the SOLN fraction %SeO4 2– was ≥%SeO3 2– for all oxides but CaO, whereas in the CMPX fraction this order was observed for only CaO and MnO2. The %SeO3 2– was highest in the SOLN fraction for all oxides but MgO and La2O3 for these two oxides SeO3 2– dominated in CMPX and SORB fractions, respectively. The SOLN fraction also contained the highest %SeO4 2– for all oxides but MgO which retained SeO4 2– primarily in the SORB fraction. The %SeO3 2– and %SeO4 2– in the CMPX fraction were highest for MgO, thus, suggesting a possible formation of MgSeO3 0 and MgSeO4 0. A similar trend of SORB %SO4 2– and SORB %SeO4 2– was attributed to the analogous adsorption mechanisms (outer-sphere complexation). For all oxides but MgO, %SO4 2– was 〈%SeO4 2– in the SOLN fraction and ≥%SeO4 2– in the CMPX fraction. Comparative ionic distributions provide an overall picture of the relative abundance of different Se species in various fractions associated with different oxides present in micro- and macrolevels in soils and geological materials.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Accreditation and quality assurance 4 (1999), S. 185-190 
    ISSN: 1432-0517
    Keywords: Key words Identification ; Chromatography ; Spectrometry ; Gas chromatography-mass spectrometry ; Measures of similarity ; Samples of unknown composition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract  Characteristic features of identification procedures of chemical substances are described and the metrological requirements for identification are discussed. The procedures are considered to be rigorous enough, if quantitative criteria such as the measure of similarity between physicochemical properties or spectra of the unknown substance and reference materials are used. Identification involves expert opinion which is of prime importance in the analysis of samples of unknown composition. The reliability of substance recognition can be increased by selecting highly qualified personnel, establishing a good information supply, using an on-line combination of separation and detection instruments such as chromatography-spectrometry and estimating the probability of identification. Standard conditions for reliable identification including quantitative criteria are examined using gas chromatography-mass spectrometry as an example.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...