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  • 1
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    Inorganic carbon system dynamics in landfast Arctic sea ice during the early-melt period (2015)
    John Wiley & Sons
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 120 (2015): 3542-3566, doi:10.1002/2014JC010620.
    Description: We present the results of a 6 week time series of carbonate system and stable isotope measurements investigating the effects of sea ice on air-sea CO2 exchange during the early melt period in the Canadian Arctic Archipelago. Our observations revealed significant changes in sea ice and sackhole brine carbonate system parameters that were associated with increasing temperatures and the buildup of chlorophyll a in bottom ice. The warming sea-ice column could be separated into distinct geochemical zones where biotic and abiotic processes exerted different influences on inorganic carbon and pCO2 distributions. In the bottom ice, biological carbon uptake maintained undersaturated pCO2 conditions throughout the time series, while pCO2 was supersaturated in the upper ice. Low CO2 permeability of the sea ice matrix and snow cover effectively impeded CO2 efflux to the atmosphere, despite a strong pCO2 gradient. Throughout the middle of the ice column, brine pCO2 decreased significantly with time and was tightly controlled by solubility, as sea ice temperature and in situ melt dilution increased. Once the influence of melt dilution was accounted for, both CaCO3 dissolution and seawater mixing were found to contribute alkalinity and dissolved inorganic carbon to brines, with the CaCO3 contribution driving brine pCO2 to values lower than predicted from melt-water dilution alone. This field study reveals a dynamic carbon system within the rapidly warming sea ice, prior to snow melt. We suggest that the early spring period drives the ice column toward pCO2 undersaturation, contributing to a weak atmospheric CO2 sink as the melt period advances.
    Description: We acknowledge support from the Polar Continental Shelf Program (PCSP) of Natural Resources Canada, the Natural Sciences and Engineering Research Council of Canada, the Northern Scientific Training Program, Canada Economic Development, and Fisheries and Oceans Canada.
    Description: 2015-11-19
    Keywords: Sea ice ; Carbon cycling ; CO2 ; Brines ; Stable isotopes ; Arctic Ocean
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
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    Sea surface pCO2 and O2 dynamics in the partially ice-covered Arctic Ocean (2017)
    John Wiley & Sons
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 122 (2017): 1425–1438, doi:10.1002/2016JC012162.
    Description: Understanding the physical and biogeochemical processes that control CO2 and dissolved oxygen (DO) dynamics in the Arctic Ocean (AO) is crucial for predicting future air-sea CO2 fluxes and ocean acidification. Past studies have primarily been conducted on the AO continental shelves during low-ice periods and we lack information on gas dynamics in the deep AO basins where ice typically inhibits contact with the atmosphere. To study these gas dynamics, in situ time-series data have been collected in the Canada Basin during late summer to autumn of 2012. Partial pressure of CO2 (pCO2), DO concentration, temperature, salinity, and chlorophyll-a fluorescence (Chl-a) were measured in the upper ocean in a range of sea ice states by two drifting instrument systems. Although the two systems were on average only 222 km apart, they experienced considerably different ice cover and external forcings during the 40–50 day periods when data were collected. The pCO2 levels at both locations were well below atmospheric saturation whereas DO was almost always slightly supersaturated. Modeling results suggest that air-sea gas exchange, net community production (NCP), and horizontal gradients were the main sources of pCO2 and DO variability in the sparsely ice-covered AO. In areas more densely covered by sea ice, horizontal gradients were the dominant source of variability, with no significant NCP in the surface mixed layer. If the AO reaches equilibrium with atmospheric CO2 as ice cover continues to decrease, aragonite saturation will drop from a present mean of 1.00 ± 0.02 to 0.86 ± 0.01.
    Description: U.S. National Science Foundation Arctic Observing Network Grant Number: ARC-1107346 and ARC-0856479
    Description: 2017-08-25
    Keywords: Arctic Ocean ; CO2 ; O2 ; Biogeochemistry ; Dynamics ; Carbon cycle
    Repository Name: Woods Hole Open Access Server
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  • 3
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    Radium isotopes across the Arctic Ocean show time scales of water mass ventilation and increasing shelf inputs (2018)
    John Wiley & Sons
    Details
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 4853-4873, doi:10.1029/2018JC013888.
    Description: The first full transarctic section of 228Ra in surface waters measured during GEOTRACES cruises PS94 and HLY1502 (2015) shows a consistent distribution with maximum activities in the transpolar drift. Activities in the central Arctic have increased from 2007 through 2011 to 2015. The increased 228Ra input is attributed to stronger wave action on shelves resulting from a longer ice‐free season. A concomitant decrease in the 228Th/228Ra ratio likely results from more rapid transit of surface waters depleted in 228Th by scavenging over the shelf. The 228Ra activities observed in intermediate waters (〈1,500 m) in the Amundsen Basin are explained by ventilation with shelf water on a time scale of about 15–18 years, in good agreement with estimates based on SF6 and 129I/236U. The 228Th excess below the mixed layer up to 1,500 m depth can complement 234Th and 210Po as tracers of export production, after correction for the inherent excess resulting from the similarity of 228Ra and 228Th decay times. We show with a Th/Ra profile model that the 228Th/228Ra ratio below 1,500 m is inappropriate for this purpose because it is a delicate balance between horizontal supply of 228Ra and vertical flux of particulate 228Th. The accumulation of 226Ra in the deep Makarov Basin is not associated with an accumulation of Ba and can therefore be attributed to supply from decay of 230Th in the bottom sediment. We estimate a ventilation time of 480 years for the deep Makarov‐Canada Basin, in good agreement with previous estimates using other tracers.
    Description: U.S. National Science Foundation Grant Numbers: OCE‐1458305, OCE‐1458424; US NSF Grant Number: OCE‐1433922
    Keywords: Radium‐228 ; Thorium‐228 ; Arctic Ocean ; Transpolar drift ; GEOTRACES
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  • 4
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    Variability and redistribution of heat in the Atlantic Water boundary current north of Svalbard (2018)
    John Wiley & Sons
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    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 6373-6391, doi:10.1029/2018JC013814.
    Description: We quantify Atlantic Water heat loss north of Svalbard using year‐long hydrographic and current records from three moorings deployed across the Svalbard Branch of the Atlantic Water boundary current in 2012–2013. The boundary current loses annually on average 16 W m−2 during the eastward propagation along the upper continental slope. The largest vertical fluxes of 〉100 W m−2 occur episodically in autumn and early winter. Episodes of sea ice imported from the north in November 2012 and February 2013 coincided with large ocean‐to‐ice heat fluxes, which effectively melted the ice and sustained open water conditions in the middle of the Arctic winter. Between March and early July 2013, a persistent ice cover‐modulated air‐sea fluxes. Melting sea ice at the start of the winter initiates a cold, up to 100‐m‐deep halocline separating the ice cover from the warm Atlantic Water. Semidiurnal tides dominate the energy over the upper part of the slope. The vertical tidal structure depends on stratification and varies seasonally, with the potential to contribute to vertical fluxes with shear‐driven mixing. Further processes impacting the heat budget include lateral heat loss due to mesoscale eddies, and modest and negligible contributions of Ekman pumping and shelf break upwelling, respectively. The continental slope north of Svalbard is a key example regarding the role of ocean heat for the sea ice cover. Our study underlines the complexity of the ocean's heat budget that is sensitive to the balance between oceanic heat advection, vertical fluxes, air‐sea interaction, and the sea ice cover.
    Description: Arctic Ocean program at the FRAM-High North Research Centre for Climate and the environment; National Science Foundation (NSF) Grant Number: ARC-1264098; Polish-Norwegian Research Programme Grant Number: POL-NOR/202006/10/2013; Research Council of Norway Grant Number: 276730; Steven Grossman Family Foundation
    Keywords: Atlantic Water ; Arctic Ocean ; Heat flux ; Nansen Basin ; Boundary current ; A‐TWAIN
    Repository Name: Woods Hole Open Access Server
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  • 5
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    Subsea ice-bearing permafrost on the U.S. Beaufort Margin : 2. Borehole constraints (2017)
    John Wiley & Sons
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 17 (2016): 4333–4353, doi:10.1002/2016GC006582.
    Description: Borehole logging data from legacy wells directly constrain the contemporary distribution of subsea permafrost in the sedimentary section at discrete locations on the U.S. Beaufort Margin and complement recent regional analyses of exploration seismic data to delineate the permafrost's offshore extent. Most usable borehole data were acquired on a ∼500 km stretch of the margin and within 30 km of the contemporary coastline from north of Lake Teshekpuk to nearly the U.S.-Canada border. Relying primarily on deep resistivity logs that should be largely unaffected by drilling fluids and hole conditions, the analysis reveals the persistence of several hundred vertical meters of ice-bonded permafrost in nearshore wells near Prudhoe Bay and Foggy Island Bay, with less permafrost detected to the east and west. Permafrost is inferred beneath many barrier islands and in some nearshore and lagoonal (back-barrier) wells. The analysis of borehole logs confirms the offshore pattern of ice-bearing subsea permafrost distribution determined based on regional seismic analyses and reveals that ice content generally diminishes with distance from the coastline. Lacking better well distribution, it is not possible to determine the absolute seaward extent of ice-bearing permafrost, nor the distribution of permafrost beneath the present-day continental shelf at the end of the Pleistocene. However, the recovery of gas hydrate from an outer shelf well (Belcher) and previous delineation of a log signature possibly indicating gas hydrate in an inner shelf well (Hammerhead 2) imply that permafrost may once have extended across much of the shelf offshore Camden Bay.
    Description: 2017-05-04
    Keywords: Permafrost ; Arctic Ocean ; Climate change ; Borehole logging ; Gas hydrates
    Repository Name: Woods Hole Open Access Server
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  • 6
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    Spatial variability of the Arctic Ocean's double-diffusive staircase (2017)
    John Wiley & Sons
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 122 (2017): 980–994, doi:10.1002/2016JC012419.
    Description: The Arctic Ocean thermohaline stratification frequently exhibits a staircase structure overlying the Atlantic Water Layer that can be attributed to the diffusive form of double-diffusive convection. The staircase consists of multiple layers of O(1) m in thickness separated by sharp interfaces, across which temperature and salinity change abruptly. Through a detailed analysis of Ice-Tethered Profiler measurements from 2004 to 2013, the double-diffusive staircase structure is characterized across the entire Arctic Ocean. We demonstrate how the large-scale Arctic Ocean circulation influences the small-scale staircase properties. These staircase properties (layer thicknesses and temperature and salinity jumps across interfaces) are examined in relation to a bulk vertical density ratio spanning the staircase stratification. We show that the Lomonosov Ridge serves as an approximate boundary between regions of low density ratio (approximately 3–4) on the Eurasian side and higher density ratio (approximately 6–7) on the Canadian side. We find that the Eurasian Basin staircase is characterized by fewer, thinner layers than that in the Canadian Basin, although the margins of all basins are characterized by relatively thin layers and the absence of a well-defined staircase. A double-diffusive 4/3 flux law parametrization is used to estimate vertical heat fluxes in the Canadian Basin to be O(0.1) W m−2. It is shown that the 4/3 flux law may not be an appropriate representation of heat fluxes through the Eurasian Basin staircase. Here molecular heat fluxes are estimated to be between O(0.01) and O(0.1) W m−2. However, many uncertainties remain about the exact nature of these fluxes.
    Description: National Science Foundation Division of Polar Programs
    Description: 2017-08-08
    Keywords: Arctic Ocean ; Double-diffusion ; Atlantic Water
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  • 7
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    Diffusive vertical heat flux in the Canada Basin of the Arctic Ocean inferred from moored instruments (2014)
    John Wiley & Sons
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 119 (2014): 496-508, doi:10.1002/2013JC009346.
    Description: Observational studies have shown that an unprecedented warm anomaly has recently affected the temperature of the Atlantic Water (AW) layer lying at intermediate depth in the Arctic Ocean. Using observations from four profiling moorings, deployed in the interior of the Canada Basin between 2003 and 2011, the upward diffusive vertical heat flux from this layer is quantified. Vertical diffusivity is first estimated from a fine-scale parameterization method based on CTD and velocity profiles. Resulting diffusive vertical heat fluxes from the AW are in the range 0.1–0.2 W m−2 on average. Although large over the period considered, the variations of the AW temperature maximum yields small variations for the temperature gradient and thus the vertical diffusive heat flux. In most areas, variations in upward diffusive vertical heat flux from the AW have only a limited effect on temperature variations of the overlying layer. However, the presence of eddies might be an effective mechanism to enhance vertical heat transfer, although the small number of eddies sampled by the moorings suggest that this mechanism remains limited and intermittent in space and time. Finally, our results suggest that computing diffusive vertical heat flux with a constant vertical diffusivity of ∼2 × 10−6 m2 s−1 provides a reasonable estimate of the upward diffusive heat transfer from the AW layer, although this approximation breaks down in the presence of eddies.
    Description: C. Lique acknowledge support from JISAO and the Program on Climate Change of the University of Washington. J. Guthrie and J. Morison are supported by National Science Foundation grants ARC-0909408 and ARC-0856330. M. Steele is supported by the Office of Naval Researches Arctic and Global Prediction Program, by NSFs Division of Polar Programs, and by NASAs Cryosphere and Physical Oceanography programs. Support for the BGOS program and R. Krishfield was provided by the National Science Foundation (under grants ARC-0806115, ARC-0631951, ARC-0806306, and ARC-0856531) and Woods Hole Oceanographic Institution internal funding. For A. Proshutinsky, this research is supported by the National Science Foundation Office of Polar Programs, awards ARC-1203720 and ARC-0856531.
    Description: 2014-07-22
    Keywords: Arctic Ocean ; Atlantic water ; Mixing
    Repository Name: Woods Hole Open Access Server
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  • 8
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    Dynamics of an idealized Beaufort Gyre : 1. The effect of a small beta and lack of western boundaries (2016)
    John Wiley & Sons
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 121 (2016): 1249–1261, doi:10.1002/2015JC011296.
    Description: The Beaufort Gyre in the Arctic Ocean differs from a typical moderate-latitude gyre in some major aspects of its dynamics. First, it is located in a basin without a western boundary, which is essential for closing midlatitude circulations. Second, the gradient in Coriolis parameter, β, is small and so the validity of the Sverdrup balance is uncertain. In this paper, we use an idealized two-layer model to examine several processes that are related to these two issues. In a circular basin with closed geostrophic contours in interior, the variability of vorticity in the upper layer is dominated by eddies. But in the time-mean circulation, the main dynamical balance in the basin's interior is between the curl of wind stress and the eddy vorticity fluxes. The torque of friction becomes important along the boundary where the rim current is strong. It is found that the smallness of β has only a relatively small impact in a circular basin without a meridional boundary. The gyre is considerably more sensitive to the existence of a meridional boundary. The time-mean circulation weakens considerably when a peninsula is inserted between the model's center and the rim. (One side of the peninsula is dynamically equivalent to a midlatitude western boundary.) The gyre's sensitivity to β has also increased significantly when a meridional boundary is present. Subsurface ridges have similar effects on the gyre as a boundary, indicating that such topographic features may substitute, to some extents, the dynamical role of a western boundary.
    Description: This study has been supported by the National Science Foundation's Arctic Natural Science Program for J.Y. and A.P. via grant PRL-1107412, and for AP via grants PRL-1313614, PRL-1302884, and PRL-1107277.
    Description: 2016-08-12
    Keywords: Arctic Ocean ; Beaufort Gyre ; Freshwater content ; Beta effect ; Western boundary
    Repository Name: Woods Hole Open Access Server
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  • 9
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    Sources of dissolved inorganic carbon to the Canada Basin halocline : a multitracer study (2016)
    John Wiley & Sons
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 121 (2016): 2918–2936, doi:10.1002/2015JC011535.
    Description: We examine the dissolved inorganic carbon maximum in the Canada Basin halocline using a suite of geochemical tracers to gain insight into the factors that contribute to the persistence of this feature. Hydrographic and geochemical samples were collected in the upper 500 m of the southwestern Canada Basin water column in the summer of 2008 and fall of 2009. These observations were used to identify conservative and nonconservative processes that contribute dissolved inorganic carbon to halocline source waters, including shelf sediment organic matter remineralization, air-sea gas exchange, and sea-ice brine export. Our results indicate that the remineralization of organic matter that occurs along the Bering and Chukchi Sea shelves is the overwhelming contributor of dissolved inorganic carbon to Pacific Winter Water that occupies the middle halocline in the southwestern Canada Basin. Nonconservative contributions from air-sea exchange and sea-ice brine are not significant. The broad salinity range associated with the DIC maximum, compared to the narrow salinity range of the nutrient maximum, is due to mixing between Pacific and Atlantic water and not abiotic addition of DIC.
    Description: NSERC; Fisheries and Oceans Canada; US National Science Foundation Office of Polar Programs Grant Number: OPP-0424864; Canadian International Polar Year Office
    Description: 2016-11-04
    Keywords: Arctic Ocean ; Dissolved inorganic carbon ; Nutrients ; Stable isotopes ; Shelf-basin CO2 pump
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  • 10
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    Evolution of the eddy field in the Arctic Ocean's Canada Basin, 2005–2015 (2016)
    John Wiley & Sons
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 43 (2016): 8106–8114, doi:10.1002/2016GL069671.
    Description: The eddy field across the Arctic Ocean's Canada Basin is analyzed using Ice-Tethered Profiler (ITP) and moored measurements of temperature, salinity, and velocity spanning 2005 to 2015. ITPs encountered 243 eddies, 98% of which were anticyclones, with approximately 70% of these having anomalously cold cores. The spatially and temporally varying eddy field is analyzed accounting for sampling biases in the unevenly distributed ITP data and caveats in detection methods. The highest concentration of eddies was found in the western and southern portions of the basin, close to topographic margins and boundaries of the Beaufort Gyre. The number of lower halocline eddies approximately doubled from 2005–2012 to 2013–2014. The increased eddy density suggests more active baroclinic instability of the Beaufort Gyre that releases available potential energy to balance the wind energy input; this may stabilize the Gyre spin-up and associated freshwater increase.
    Description: National Science Foundation Division of Polar Programs Grant Number: 1350046
    Description: 2017-02-03
    Keywords: Arctic Ocean ; Eddies ; Beaufort Gyre
    Repository Name: Woods Hole Open Access Server
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