ALBERT

Note: TABLE OF CONTENTS FOREWORD 1 INTRODUCTION AND SURVEY OF RADIOANALYSIS 1.1 Introduction 1.2 Principles of radioanalysis 1.2.1 General 1.2.2 Glossary of basic terms and concepts 1.3 Scope and contents References 2 SAMPLING AND PRECONCENTRATION 2.1 Survey and principles 2.1.1 Sampling 2.1.2 From sample to aliquot 2.1.2 .1 General 2.1.2.2 Granular material 2.1.2.3 Water 2.2 Sampling procedures 2.2.1 Rocks 2.2.2 Sediments and pore water 2.2.2.1 Sediments 2.2.2.2 Pore water 2.2.3 Fresh and ground water and related particulate matter 2.2.3.1 Fresh water 2.2.3.2 Ground water 2.2.4 Sea- and estuarine water and related particulate matter and sediments 2.2.4.1 Water 2.2.4.2 Particulate matter 2.2.4.3 Sediment cores 2.2.5 Rainwater and dry deposition 2.2.5.1 Rainwater 2.2.5.2 Dry deposition 2.3 Preconcentration 2.3.1 General 2.3.2 Fresh water and rainwater 2.3.3 Seawater 2.3.3.1 Survey 2.3.3.2 Scavenging procedures 2.3.3.3 Ion-exchange and solvent extraction procedures for Th, U and Pu 2.4 Reference materials 2.4.1 Principle 2.4.2 Survey of reference materials and SRM's 2.4.3 Use of reference materials and SRM's 2.4.3.1 Reference materials 2.4.3.2 SRM's 2.4.4 Reference materials for environmental radioactivity and isotopic ratio measurements References 3 INSTRUMENTAL RADIOANALYSIS OF GEOLOGICAL MATERIALS 3.1 Survey 3.1.1 Activation analysis 3.1.2 Photon activation analysis 3.1.3 Charged particle activation analysis (CPAA and HIAA) 3.1.4 Prompt techniques 3.1.4.1 Neutron induced prompt capture y-ray measurement (PGAA) 3.1.4.2 Proton induced X-ray emission (PIXE) 3.2 Principles 3.2.1 Principles of instrumental neutron activation analysis (INAA) 3.2.1.1 Activation 3.2.1.2 Standardization and flux monitoring 3.2.1.3 Count rate 3.2.1.4 Counting result 3.2.1.5 Sensitivity 3.2.1.6 Characteristic parameters of the three types of neutron activation 3.2.2 Delayed neutron counting 3.2.3 Activation analysis with high-energy photons 3.2.4 Principles of charged particle activation analysis (CPAA) 3.2.5 Principles of prompt techniques 3.2.5.1 Prompt capture gamma-ray measurements (PGAA) 3.2.5.2 Proton induced X-ray emission (PIXE) 3.3 Practical aspects of INAA, IPAA and PIXE 3.3.1 The radioanalytical laboratory 3.3.2 Irradiation facilities for NAA 3.3.2.1 Nuclear reactors 3.3.2.2 Rabbit systems 3.3.2.3 Epithermal activation 3.3.2.4 Neutron generators 3.3.2.5 Delayed neutron counting 3.3.3 Routing of INAA 3.3.4 Practical aspects of IPAA 3.3.5 Practical aspects of CPAA 3.3.6 Practical aspects of PGAA 3.3.7 Practical aspects of PIXE and PIGE 3.3.7.1 Proton induced X-ray emission (PIXE) 3.3.7.2 Proton induced prompt gamma emission (PIGE) 3.3.8 The error-budget 3.4 Multielement determination by INAA based on gamma-ray spectrometry 3.4.1 General 3.4.2 A practical procedure for INAA of silicates based on thermal neutrons 3.4.2.1 Preparation of sample and standards for irradiation 3.4.2.2 Irradiation and measurements 3.4.2.3 Conclusion 3.4.3 Rocks and ores 3.4.4 Meteorites 3.4.5 Sediments 3.4.6 Air-dust 3.4.7 Coal and ash 3.5 Instrumental neutron activation analysis of the lanthanides 3.6 Instrumental neutron activation analysis of uranium 3.7 Applications of instrumental neutron activation analysis with an isotopic neutron source and a 14.5 MeV neutron generator 3.7.1 Survey 3.7.2 INAA with isotopic neutron sources in the radiochemical laboratory 3.7.3 INAA with the neutron generator in the radiochemical laboratory 3.7.4. Conclusion 3.8 Applications of IPAA to silicates 3.9 Applications of IPAA to silicates 3.10 Applications of prompt techniques 3.10.1 Applications of PGAA and PIGE 3.10.2 Applications of PIXE References 4 NEUTRON ACTIVATION ANALYSIS INCLUDING CHEMICAL SEPARATION OF GEOLOGICAL SAMPLES 4.1 Introduction 4.2 Dissolution procedures and separation schemes 4.3 Lanthanides 4.3.1 General 4.3.2 Present procedures 4.4 Noble metals 4.4.1 General 4.4.2 Separation schemes 4.4.3 Single element determinations 4.5 Uranium and thorium 4.5.1 General 4.5.2 Procedures 4.5.2.1 Uranium 4.5.2.2 Thorium 4.6 Other elements 4.6.1 General 4.6.2 Alkali metals 4.6.3 Earth alkali metals 4.6.4 Copper and zinc 4.6.5 Mercury 4.6.6 Indium 4.6.7 Thallium 4.6.8 Tin 4.6.9 Elements with volatile halides and hydrides: Ga, Ge, As, Se, Sb, Te 4.6.9.1 Survey 4.6.9.2 Procedures 4.6.10 Vanadium and tantalum 4.6.11 Chromium 4.6.12 Molybdenum andtungsten 4.6.13 Halogens References 5 RADIOANALYSIS OF WATER 5.1 Survey 5.2 Elemental analysis of fresh water 5.2.1 Survey 5.2.2 Routine elemental analysis of rainwater 5.2.2.1 Sampling and sample treatment 5.2.2.2 Irradiation and processing of aliquots 5.2.2.3 Results 5.2.3 Special elemental analysis of rainwater 5.2.3.1 Bromine and iodine by isotopic exchange 5.2.3.2 Iodate by anion-exchange 5,2.3.3 Silver by cation-exchange and subsequent INAA 5.2.4 Routine elemental analysis of surface and ground water 5.2.4,1 General 5.2.4.2 Routine procedures 5.3 Elemental analysis of seawater 5.3.1 Survey 5.3.2 Routine elemental analysis of seawater by preconcentration on a "Chelex"-column and INAA 5.3.3 Routine elemental analysis of seawater by preconcentration on active carbon 5.3.3,1 General 5.3.3.2 Arsenic and antimony 5,3.3.3 Vanadium, iodine, tellurium and uranium 5.3.3.4 Total antimony, molybdenum and tungsten 5,3.3.5 Chromate, cobalt, nickel and tetravalent selenium 5.3.3,6 Mercury 5.3.4 Special elemental analysis of seawater 5.3.4.1 General 5.3.4.2 Rubidium and cesium 5.3.4.3 Strontium 5.3.4.4 Manganese and zinc 5,3,4.5 Tin 5.3.4.6 Nickel 5.3.4.7 Noble metals 5.3.4.8 Mercury References 6 RADIOTRACER EXPERIMENTS IN THE LABORATORY 6.1 Survey 6.2 Basic equations of radiotracer experiments in closed systems 6.3 Isotopic exchange in solution 6.4 Isotopic exchange between a solution and a solid 6.5 Reactions in solution 6.6 Reaction between a solution and a solid 6.6.1 Dissolution 6.6. 2 Leaching 6.6.3 Diffusion from solids 6.6.4 Sorption 6.7 Migration studies in solid-liquid systems 6.7.1 General 6.7.2 The determina tion of distribution coefficients in seawater 6.7.3 Radioecological column experiments in the laboratory 6.7.4 Laboratory experiments on very slow migration; the case of the actinides References 7 RADIOTRACER EXPERIMENTS IN THE FIELD 7.1 Survey 7.2 Principles of (radio)tracer experiments in open systems with flow in one direction 7.2.1 Basic concepts 7.2.2 Measurement of linear velocity and flow rate 7.2.3 Measurement of axial dispersion 7.2.4 Measurement of sedimentation rates 7.2.4.1 General 7.2.4.2 Lead-210 7.2.4.3 Cesium-137 7.2.5 Measurement of the degree of sediment mixing 7.2.6 Measurement of filtration velocity in case of horizontal groundwater flow 7.2.7 Measurement of groundwater flow in the unsaturated zone by radiocarbon 7.3 Principles of (radio)tracer experiments in open systems with flow in various directions 7.3.1 Survey 7.3.2 Measurement of sand or silt flow rates on the sea floor 7.3.3 Radiotracer measurements in water movement in the saturated zone 7.3.4 Radiotracer measurement on water movement in the unsaturated zone 7.4 Practical aspects of radiotracer experiments in the field 7.4.1 Preparation 7.4.2 Performance 7.4.3 Calculations References 8 MEASUREMENT OF NATURAL RADIOACTIVITY 8.1 General 8.1.1 Survey 8.1.2 Concentrations 8.1.3 Detection by direct measurement ofradiation 8.1.3.1 In situ measurements of uranium and thorium 8.1.3.2 Laboratory measurements 8.1.4 Detection by secundary effects 8.2 Measurement of low-level gamma-activities 8.2.1 General 8.2.2 A low background system (LBS) 8.2.2.1 Set-up 8.2.2.2 Limits of detection and determination 8.2.2.3 Processing of data 8.2.3. Anti-coincidence (AC)-counting 8.3 Measurements in rocks and sediments 8.3.1 General 8.3.2 Radon measurements (emanometry) 8.3.3 Age dating by measurement of disequilibrium in the natural decay-series 8.3.3.1 General 8.3.3.2 234U-230Th 8.3.3.3 235U-231Pa 8.3.3.4 232Th-230Th 8.3.3.5 230Th-231Pa 8.3.4 Environmental laboratory measurements on naturally occurring radionucl

Note: Table of Contents: 1 The Solid Phase of Marine Sediments / DIETER K. FÜTTERER 1.1 Introduction 1.2 Sources and Components of Marine Sediments 1.2.1 Lithogenous Sediments 1.2.2 Biogenous Sediments 1.2.3 Hydrogenous Sediments 1.3 Classification of Marine Sediments 1.3.1 Terrigenous Sediments 1.3.2 Deep-Sea Sediments 1.4 Global Patterns of Sediment Distribution 1.4.1 Distribution Patterns of Shelf Sediments 1.4.2 Distribution Patterns of Deep-Sea Sediments 1.4.3 Distribution Patterns of Glay Minerals 1.4.4 Sedimentation Rates 2 Geophysical Perspectives in Marine Sediments 2.1 Physical Properties of Marine Sediments / MONIKA BREITZKE 2.1.1 Introduction 2.1.2 Porosity and Wet Bulk Density 2.1.2.1 Analysis by Weight and Volume 2.1.2.2 Gamma Ray Attenuation 2.1.2.3 Electrical Resistivity (Galvanic Method) 2.1.2.4 Electrical Resistivity (Inductive Method) 2.1.3 Permeability 2.1.4 Acoustic and Elastic Properties 2.1.4.1 Biot-Stoll Model 2.1.4.2 Full Waveform Ultrasonic Gore Logging 2.1.5 Sediment Classification 2.1.5.1 Full Waveform Gore Logs as Acoustic Images 2.1.5.2 P-and S-Wave Velocity, Attenuation, Elastic Moduli and Permeability 2.1.6 Sediment Echosounding 2.1.6.1 Synthetic Seismograms 2.1.6.2 Narrow-Beam Parasound Echosounder Recordings 2.2 Sedimentary Magnetism / ULRICH BLEIL 2.2.1 Introduction 2.2.2 Biogenie Magnetic Minerals in Marine Sediments 2.2.3 Reduction Diagenesis of Magnetic Minerals in Marine Environments 3 Quantification of Early Diagenesis: Dissolved Constituents in Marine Pore Water / HORST D. SCHULZ 3.1 Introduction: How to Read Pore Water Concentration Profiles 3.2 Calculation of Diffusive Fluxes and Diagenetic Reaction Rates 3.2.1 Steady State and Non-Steady State Situations 3.2.2 The Steady State Situation and Fick's First Law of Diffusion 3.2.3 Quantitative Evaluation of Steady State Concentration Profiles 3.2.4 The Non-Steady State Situation and Fick's Second Law of Diffusion 3.2.5 The Primary Redox-Reactions: Degradation of Organic Matter 3.3 Sampling of Pore Water for Ex-Situ Measurements 3.3.1 Obtaining Sampies of Sediment for the Analysis of Pore Water 3.3.2 Pore Water Extraction from the Sediment 3.3.3 Storage, Transport and Preservation of Pore Water 3.4 Analyzing Constituents in Pore Water, Typical Profiles 3.5 In-Situ Measurements 3.6 Influence of Bioturbation, Bioirrigation, and Advection 4 Organic Matter: The Driving Force for Early Diagenesis / JÜRGEN RULLKÖTTER 4.1 The Organic Carbon Cycle 4.2 Organic Matter Accumulation in Sediments 4.2.1 Productivity Versus Preservation 4.2.2 Primary Production of Organic Matter and Export to the Ocean Bottom 4.2.3 Transport of Organic Matter through the Water Column 4.2.4 The Influence of Sedimentation Rate on Organic Matter Burial 4.2.5 Allochthonous Organic Matter in Marine Sediments 4.3 Early Diagenesis 4.3.1 The Organic Carbon Content of Marine Sediments 4.3.2 Chemical Composition of Biomass 4.3.3 The Principle of Selective Preservation 4.3.4 The Formation of Fossil Organic Matter and its Bulk Composition 4.3.5 Early Diagenesis at the Molecular Level 4.3.6 Biological Markers (Molecular Fossils) 4.4 Organic Geochemical Proxies 4.4.1 Total Organic Carbon and Sulfur 4.4.2 Marine Versus Terrigenous Organic Matter 4.4.3 Molecular Paleo-Seawater Temperature and Climate Indicators 4.5 Analytical Techniques 4.5.1 Sam pie Requirements 4.5.2 Elemental and Bulk Isotope Analysis 4.5.3 Rock-Eval Pyrolysis and Pyrolysis Gas Chromatography 4.5.4 Organic Petrography 4.5.5 Bitumen Analysis 4.6 The Future of Marine Geochemistry of Organic Matter 5 Bacteria and Marine Biogeochemistry / Bo BARKER JORGENSEN 5.1 Role of Microorganisms 5.1.1 From Geochemistry to Microbiology - and back 5.1.2 Approaches in Marine Biogeochemistry 5.2 Life and Environments at Small Scale 5.2.1 Hydrodynamics of Low Reynolds Numbers 5.2.2 Diffusion at Small Scale 5.2.3 Diffusive Boundary Layers 5.3 Regulation and Limits of Microbial Processes 5.3.1 Substrate Uptake by Microorganisms 5.3.2 Temperature as a Regulating Factor 5.3.3 Other Regulating Factors 5.4 Energy Metabolism of Prokaryotes 5.4.1 Free Energy 5.4.2 Reduction-Oxidation Processes 5.4.3 Relations to Oxygen 5.4.4 Definitions of Energy Metabolism 5.4.5 Energy Metabolism of Microorganisms 5.4.6 Chemolithotrophs 5.4.7 Respiration and Fermentation 5.5 Pathways of Organic Matter Degradation 5.5.1 Depolymerization of Macromolecules 5.5.2 Aerobic and Anaerobic Mineralization 5.5.3 Depth Zonation of Oxidants 5.6 Methods in Biogeochemistry 5.6.1 Incubation Experiments 5.6.2 Radioactive Tracers 5.6.3 Example: Sulfate Reduction 5.6.4 Specific Inhibitors 5.6.5 Other Methods 6 Early Diagenesis at the Benthic Boundary Layer: Oxygen and Nitrate in Marine Sediments / CHRISTIAN HENSEN AND MATTHIAS ZABEL 6.1 Introduction 6.2 Oxygen and Nitrate Distribution in Seawater 6.3 The Role of Oxygen and Nitrate in Marine Sediments 6.3.1 Respiration and Redox Processes 6.3.1.1 Nitrification and Denitrification 6.3.1.2 Coupling of Oxygen and Nitrate to other Redox Pathways 6.3.2 Determination of Consumption Rates and Senthic Fluxes 6.3.2.1 Fluxes and Concentration Profiles Determined by In-Situ Devices 6.3.2.2 Ex-Situ Pore Water Data from Deep-Sea Sediments 6.3.2.3 Determination of Denitrification Rates 6.3.3 Oxic Respiration, Nitrification and Denitrification in Different Marine Environments 6.3.3.1 Quantification of Rates and Fluxes 6.3.3.2 Variation in Different Marine Environments: Case Studies 6.4 Summary 7 The Reactivity of Iron / RALF R. HAESE 7.1 Introduction 7.2 Pathways of Iron Input to Marine Sediments 7.2.1 Fluvial Input 7.2.2 Aeolian Input 7.3 Iron as a Limiting Nutrient for Primary Productivity 7.4 The Early Diagenesis of Iron in Sediments 7.4.1 Dissimilatary Iran Reductian 7.4.2 Solid Phase Ferric Iron and its Bioavailability 7.4.2.1 Properties of Iron Oxides 7.4.2.2 Bioavailability of Iron Oxides 7.4.2.3 Bioavailability of Sheet Silicate Sound Ferric lron 7.4.3 Iron and Manganese Redax Cycles 7.4.4 Iron Reactivity towards S, O2, Mn, NO3, P, HCO3, and Si-AI 7.4.4.1 lron Reduction by HS and Ligands 7.4.4.2 Iron Oxidation by O2, NO3, and Mn4+ 7.4.4.3 Iron-Sound Phosphorus 7.4.4.4 The Formation of Siderite 7.4.4.5 The Formation of lron Searing Aluminosilicates 7.4.5 Discussion: The Importance of Fe-and Mn-Reactivity in Various Enyironments 7.5 The Assay for Ferric and Ferrous Iron 8 Sulfate Reduction in Marine Sediments / SABINE KASTEN AND BO BARKER JØRGENSEN 8.1 Introduction 8.2 Sulfate Reduction and the Degradation of Organic Matter 8.3 Biotic and Abiotic Processes Coupled to Sulfate Reduction 8.3.1 Pyrite Formation 8.3.2 Effects of Sulfate Reduction on Sedimentary Solid Phases 8.4 Determination of Sulfate Reduction Rates 9 Marine Carbonates: Their Formation and Destruction / RALPH R. SCHNEIDER, HORST D. SCHULZ AND CHRISTIAN HENSEN 9.1 Introduction 9.2 Marine Environments of Carbonate Production and Accumulation 9.2.1 Shallow-Water Carbonates 9.2.2 Pelagic Calcareous Sediments 9.3 The Calcite-Carbonate-Equilibrium in Marine Aquatic Systems 9.3.1 Primary Reactions of the Calcite-Carbonate-Equilibrium with Atmospheric Contact in Infinitely Diluted Solutions 9.3.2 Primary Reactions of the Calcite-Carbonate-Equilibrium without Atmospheric Contact 9.3.3 Secondary Reactions of the Calcite-Carbonate-Equilibrium in Seawater 9.3.4 Examples for Calculation of the Calcite-Carbonate-Equilibrium in Ocean Waters 9.4 Carbonate Reservoir Sizes and Fluxes between Particulate and Dissolved Reservoirs 9.4.1 Production Versus Dissolution of Pelagic Carbonates 9.4.2 Inorganic and Organic Carbon Release trom Deep-Sea Sediments 10 Influences of Geochemical Processes on Stable Isotope Distribution in Marine Sediments / TORSTEN SICKERT 10.1 Introduction 10.2 Fundamentals 10.2.1 Principles of Isotopic Fractionation 10.2.2 Analytical Procedures 10.3 Geochemicallnfluences on 18O/16O Ratios 10.3.1 δ18O of Seawater 10.3.2 δ18O in Marine Carbonates 10.4 Geochemical Influences on 13C/12C Ratios 10.4.1

Note: Hydrocarbon systems, by nature, are a complex interplay of elements that must be spatially and temporally aligned to result in the generation and preservation of subsurface hydrocarbon accumulations. To meet the increasing challenges of discovering hydrocarbon resources, it is essential that we advance our understanding of these systems through new geochemical approaches and analytical developments. Such development requires that academic- and industry-led research efforts converge in ways that are unique to the geosciences. The aim of this volume is to bring together a multidisciplinary geochemical community from industry and academia working in hydrocarbon systems to publish recent advances and state-of-the-art approaches to resolve the many remaining questions in hydrocarbon systems analysis. From Source to Seep presents geochemical and isotopic studies that are grouped into three themes: (1) source-rock identification and the temperature/timing of hydrocarbon generation; (2) mechanisms and time-scales associated with hydrocarbon migration, trapping, storage and alteration; and (3) the impact of fluid flow on reservoir properties. | Contents: Geochemical applications in petroleum systems analysis: new constraints and the power of integration / M. Lawson, M. J. Formolo, L. Summa and J. M. Eiler / Geological Society, London, Special Publications, 468, 1-21, 19 February 2018, https://doi.org/10.1144/SP468.6 --- Source-rock identification and the temperature/timing of hydrocarbon generation --- The utility of methane clumped isotopes to constrain the origins of methane in natural gas accumulations / Daniel A. Stolper, Michael Lawson, Michael J. Formolo, Cara L. Davis, Peter M. J. Douglas and John M. Eiler / Geological Society, London, Special Publications, 468, 23-52, 14 December 2017, https://doi.org/10.1144/SP468.3 --- The isotopic structures of geological organic compounds / John M. Eiler, Matthieu Clog, Michael Lawson, Max Lloyd, Alison Piasecki, Camilo Ponton and Hao Xie / Geological Society, London, Special Publications, 468, 53-81, 14 December 2017, https://doi.org/10.1144/SP468.4 --- Vanadium isotope composition of crude oil: effects of source, maturation and biodegradation / Yongjun Gao, John F. Casey, Luis M. Bernardo, Weihang Yang and K. K. (Adry) Bissada / Geological Society, London, Special Publications, 468, 83-103, 14 December 2017, https://doi.org/10.1144/SP468.2 --- Carbon and hydrogen isotopic compositions of n-alkanes as a tool in petroleum exploration / Nikolai Pedentchouk and Courtney Turich / Geological Society, London, Special Publications, 468, 105-125, 14 December 2017, https://doi.org/10.1144/SP468.1 --- Mechanisms and time-scales associated with hydrocarbon migration, trapping, storage and alteration --- Noble gases in conventional and unconventional petroleum systems / David J. Byrne, P. H. Barry, M. Lawson and C. J. Ballentine / Geological Society, London, Special Publications, 468, 127-149, 14 December 2017, https://doi.org/10.1144/SP468.5 --- Differentiating between biogenic and thermogenic sources of natural gas in coalbed methane reservoirs from the Illinois Basin using noble gas and hydrocarbon geochemistry / Myles T. Moore, David S. Vinson, Colin J. Whyte, William K. Eymold, Talor B. Walsh and Thomas H. Darrah / Geological Society, London, Special Publications, 468, 151-188, 18 January 2018, https://doi.org/10.1144/SP468.8 --- The impact of fluid flow on reservoir properties --- Testing clumped isotopes as a reservoir characterization tool: a comparison with fluid inclusions in a dolomitized sedimentary carbonate reservoir buried to 2–4 km / John M. MacDonald, Cédric M. John and Jean-Pierre Girard / Geological Society, London, Special Publications, 468, 189-202, 14 December 2017, https://doi.org/10.1144/SP468.7

Note: Methodology of Lithium Analytical Chemistry and Isotopic MeasurementsCosmochemistry of Lithium -- Li Partitioning, Diffusion and Associated Isotopic Fractionation: Theoretical and Experimental Insights -- Lithium in the Deep Earth: Mantle and Crustal Systems -- The Surficial Realm: Low Temperature Geochemistry of Lithium..

Note: Table of Contents: CHAPTER 1: THE ENVIRONMENTAL ISOTOPES: Environmental Isotopes in Hydrogeology. - Stable Isotopes: Standards and Measurement. - Isotope Ratio Mass Spectrometry. - Radioisotopes. - Isotope Fractionation. - Isotope Fractionation (a), Enrichment (e), and Separation (D). - CHAPTER 2: TRACING THE HYDROLOGIGICAL CYCLE: Craig's Meteoric Relationship in Global Fresh Waters. - Partitioning of Isotopes Through the Hydrological Cycle. - Condensation, Precipitation, and the Meteoric Water Line. - A Closer Look at Rayleigh Distillation. - Effects of Extreme Evaporation. - CHAPTER 3: PRECIPITATION: The T - d18O Correlation in Precipitation. - Local Effects on T - d18O. - Ice Cores and Paleotemperature. - CHAPTER 4: GROUNDWATER: Recharge in Temperate Climates. - Recharge in Arid Regions. - Recharge from River-Connected Aquifers. - Hydrograph Separation in Catchment Studies. - Groundwater Mixing. - CHAPTER 5: TRACING THE CARBON CYCLE: Evolution of Carbon in Groundwaters. - Carbonate Geochemistry. - Carbon-13 in the Carbonate System. - Dissolved Organic Carbon. - Methane in Groundwaters. - Isotopic Composition of Carbonates. - CHAPTER 6: GROUNDWATER QUALITY: Sulphate, Sulphide and the Sulphur Cycle. - Nitrogen Cycles in Rural Watersheds. - The "Fuhrberger Feld" Study. - Source of Chloride Salinity. - Landfill Leachates. - Degredation of Chloro-organics and Hydrocarbon. - Sensitivity of Groundwater to Contamination. - Summary of Isotopes in Contaminant Hydrology. - CHAPTER 7: IDENTIYING AND DATING MODERN GROUNDWATERS: The "Age" of Groundwater. - Stable Isotopes. - Tritium in Precipitation. - Dating Groundwaters with Tritium. - Groundwater Dating with 3H -3He. - Chlorofluorocarbons (CFCs). - Thermonuclear 36Cl. - Detecting Modern Groundwaters with 85Kr . - Submodern Groundwater. - CHAPTER 8: AGE DATING OLD GROUNDWATERS: Stable Isotopes and Paleogroundwaters. - Groundwater Dating with Radiocarbon. - Correction for Carbonate Dissolution. - Some Additional Complications to 14C Dating. - 14C Dating with Dissolved Organic Carbon (DOC). - Case Studies for 14C dating with DOC and DIC. - Chlorine-36 and Very Old Groundwater. - The Uranium Decay Series. - CHAPTER 9: WATER-ROCK INTERACTION: Mechanisms of Isotope Exchange. - High Temperature Systems. - Low Temperature Water-Rock Interaction. - Strontium Isotopes in Water and Rock. - Isotope Exchange in Gas-Water Reactions. - High pH Groundwaters-The Effect of Cement Reactions. - CHAPTER 10: FIELD METHODS FOR SAMPLING: Groundwater. - Water in the Unsaturated Zone. - Precipitation. - Gases. - Geochemistry. - References. - Subject Index. - Each chapter has Problems sections.

Note: Chapter 1. Overview and General Concepts by Clark M. Johnson, Brian L. Beard and Francis Albarede, p. 1 - 24 Chapter 2. An Overview of Isotopic Anomalies in Extraterrestrial Materials and Their Nucleosynthetic Heritage by Jean Louis Birck, p. 25 - 64 Chapter 3. Applying Stable Isotope Fractionation Theory to New Systems by Edwin A. Schauble, p. 65 - 112 Chapter 4. Analytical Methods for Non-Traditional Isotopes by Francis AlbarÀde and Brian L. Beard, p. 113 - 152 Chapter 5. Developments in the Understanding and Application of Lithium Isotopes in the Earth and Planetary Sciences by Paul B. Tomascak, p. 153 - 196 Chapter 6. The Isotope Geochemistry and Cosmochemistry of Magnesium by Edward D. Young and Albert Galy, p. 197 - 230 Chapter 7. The Stable-Chlorine Isotope Compositions of Natural and Anthropogenic Materials by Michael A. Stewart and Arthur J. Spivack, p. 231 - 254 Chapter 8. Calcium Isotopic Variations Produced by Biological, Kinetic, Radiogenic and Nucleosynthetic Processes by Donald J. DePaolo, p. 255 - 288 Chapter 9. Mass-Dependent Fractionation of Selenium and Chromium Isotopes in Low-Temperature Environments by by Thomas M. Johnson and Thomas D. Bullen, p. 289 - 318 Chapter 10A. Fe Isotope Variations in the Modern and Ancient Earth and Other Planetary Bodies by Brian L. Beard and Clark M. Johnson, p. 319 - 358 Chapter 10B. Isotopic Constraints on Biogeochemical Cycling of Fe by Clark M. Johnson, Brian L. Beard, Eric E. Roden, Dianne K. Newman and Kenneth H. Nealson, p. 359 - 408 Chapter 11. The stable isotope geochemistry of copper and zinc by Francis Albarede, p. 409 - 428 Chapter 12. Molybdenum Stable Isotopes: Observations, Interpretations and Directions by Ariel D. Anbar, p. 429 - 454

Note: Contents 1 Scope / G. Matthess 2 Polar Organic Substances and Their Role in the Water-Saturated and -Unsaturated Zones 2.0 Introduction / F.H. Frimmel 2.1 Isolation Procedures and Characterization Methods 2.1.1 Isolation and General Characterization of Organic Acids from Pore Water / F.H. Frimmel 2.1.2 Isolation and Characterization of Soil Humic Matter / W. Finger, B. Post and H. Klamberg 2.1.3 Isolation and Characterization of Organic Substancesin Ground Water and Sediments / F. Selenka and A. Hack 2.1.4 Chromatographie Characterization of the Acid-Soluble Part of Humic Substances / F.H. Frimmel 2.1.5 Spectroscopic Characterization of Humic Substances in the Ultraviolet and Visible Region and by Infrared Spectroscopy / G. Abbt-Braun 2.1.6 Temperature-Programmed/Time-Resolved Pyrolysis Field lonization Mass Spectrometry - a New Method for the Characterization of Humic Substances / H.-R. Schulten 2.1.7 Interpretation of the Pyrolysis Products of Isolated Humic and Fulvic Acids / G. Abbt-Braun 2.1.8 Characterization of Isolated Humic Material by 13C Nuclear Magnetic Resonance Spectroscopy /J. Buddrus and P. Burba 2.1.9 Characterization of Humic Substances Extracted by Organic Solvents / B. Post and H. Klamberg 2.2 Interaction of Inorganics with Humic Substances 2.2.1 Investigation of Metal Complexation by Polarography and Fluorescence Spectroscopy / F.H. Frimmel 2.2.2 Determination of Complexation Equilibria by the Ion-Exchange Method / W. Finger and H. Klamberg 2.2.3 Sorption of Metals on Humic Material / R. Becker and H. Klamberg 2.2.4 Interactions of Humic Substances with Iodine / K. G. Heumann and C. Reifenhäuser 2.2.5 Experiments on the Influence of Organic Ligands upon Kinetics of Feldspar Weathering / A. Petersen, G. Matthess and D. Schenk 2.3 Characterization of Some Organic Acids in the Subsurface of the Sandhausen Ecosystem / T. Cordt and H. Kussmaul 2.3.4 Organic Acids 2.3.5 Conclusions 3 Carbonate Systems 3.0 Introduction / E. Usdowski 3.1 Dissolution Kinetics in the Generation of Carbonate Ground Waters 3.1.1 Theoretical and Experimental Results of the Kinetics of Calcite Dissolution and Precipitation / W. Dreybrodt 3.1.2 Field Measurements and Laboratory Experiments on Calcite Dissolution Kinetics of Natural Porous Media / J. Baumann and H.D. Schulz 3.2 Field Studies on Subsurface Water of Selected Sites / B. Merkel and J. Grossmann 3.2.1 Pore Water Sampling in Carbonate Terrains 3.2.2 Variation of Inorganic Carbon in the Unsaturated Zone of a Carbonate Gravel System / L. Eichinger and B. Merkel 3.2.3 Isotope Geochemistry of the Subsurface Carbonate System in Sandhausen and Bocholt / H. Dörr, W. Leuchs, P. Obermann, W. Regenberg and C. Sonntag 3.2.4 Application of Stable Carbon and Sulfur Isotope Models to the Development of Ground Water in a Limestone-Dolomite-Anhydrite-Gypsum Area / K.W. Schaefer and E. Usdowski 3.2.5 A dissolution Front at the Contact of Sandsto Marly Limestone Aquifers / H.R. Langguth and R. Schulz 3.2.6 Carbonate Rock Dissolution Under Intermediate System Conditions / J. Michaelis 3.3 Alteration in Karst Systems 3.3.1 Mineralogy and Hydrogeochemistry of the Gypsum Karst of Foum Tatahouine, South Tunisia / W. Smykatz-Kloss, H. Hötzl and H. Kössl 3.3.2 Dedolomitization and Salt Formationin a Semi-Arid Environment / W. Smykatz-Kloss, and J. Goebelbecker 3.3.3 Transformation Processes in Paleokarst Sediments and Chemistry of Modern Waters in the Aladag Region, Turkey / M. Cevrini and W. Echle 4 Silicate Systems 4.0 Introduction / G. Matthess 4.1 Redox Reactions in the Subsurface 4.1.1 Anoxic Reaction Zones in an Aquifer Influenced by Increasing Nitrate and Sulfate Contents / W. Leuchs and P. Obermann 4.1.2 Nitrogen and Oxygen Isotopes as Indicators for Nitrification and Denitrification / H.-L. Schmidt, S. Voerkelius and A. Amberger 4.1.3 Redox Conditions and Microbial Sulfur Reactions in the Fuhrberger Field Sandy Aquifer / J. Böttcher, O. Strebet and W. Kölle 4.1.4 Influence of Fine-Grained Cover Beds on the Chemistry of Shallow Ground Water / G. Ebhardt and P. Fritsch 4.1.5 Hydrogeochemical Processes During the Passage of Surface Water and Ground Water Through Genetically Different Organic Sediments / H. Brühl, A. Moschick and H. Verleger 4.1.6 Hydrochemical Phenomena in the Dorsten Leakage System / M. Hoffmann, H.R. Langguth and J. Larue 4.1.7 Hydrogeochemical Processes in the Hamburg Deep Aquifer System / E.P. Loehnert, W. Bauhus and C. Sonntag 4.2 Rock-Water Interaction 4.2.1 Aluminium Speciation in Acid Soil Water and Ground Water / G. Dietze and B. Ulrich 4.2.2 Mineral-Pore Water Interaction in Two Soil Types on Pleistocene Sediments at Hamburg / F. Sztuka and I. Valeton 4.2.3 Subsurface Hydrochemical Reactions in the Sandhausen Forest Ecosystem / H. Jacob, W. Regenberg and C. Sonntag 4.3 Reaction Kinetics 4.3.1 Experimental Methods for Determining Dissolution Rates of Silicates - a Comparison / D. Schenk, G. Matthess, A. Dahmke and A. Petersen 4.3.2 Field Studies on the Kinetics of Silicate Minerals/Water Interaction / G. Matthess, A. Petersen, D. Schenk and A. Dahmke 5 Microbiology 5.0 Introduction / P. Hirsch 5.1 Characterization of the Natural Subsurface Environment 5.1.1 Morphological and Taxonomic Diversity of Ground Water Microorganisms / P. Hirsch, E. Rades-Rohkohl, J. Kölbel-Boelke and A. Nehrkorn 5.1.2 Methods of Studying Ground Water Microbiology: Critical Evaluations and Method suggestions / P. Hirsch, E. Rades-Rohkohl, J. Kölbel-Boelke, A. Nehrkorn, R. Schweisfurth, F. Selenka and A. Hack 5.1.3 Organic Substances in Ground Water and Sediments and Their Relationships to Microorganisms in a Sandy Aquifer / E Selenka and A. Hack 5.2 Microbial Activities 5.2.1 Observations on the Physiology of Microorganisms from Pristine Ground Water Environments / P. Hirsch 5.2.2 Formation and Transformation of Manganese Oxidation States by Bacteria / J. Gottfreund and R. Schweisfurth 5.2.3 Interactions Between Humic Acids and Microorganisms / G.-J. Tuschewitzki, B. Langer and H. Otremba 5.3 Microbiology of Selected Locations 5.3.1 Subsurface Microbial Activities in the Sandhausen Forest Ecosystem / R. Weyandt and R. Schweisfurth 5.3.2 Heterotrophic Bacterial Communities in the Bocholt Aquifer System / J. Kölbel-Boelke and A. Nehrkorn 5.3.3 The Natural Microflora of the Segeberger Forest Aquifer System / P. Hirsch and E. Rades-Rohkohl 5.3.4 Microbiological Observations of the Unsaturated Zone of a Quaternary Gravel Profile / I. Alexander, G. Freitag, J. Grossmann, Β. Merkel, P. Udluft and I. Ullsperger 6 Hydrogeochemical and Geochemical-Hydraulic Models and Model Concepts 6.0 Introduction / H.-D. Schulz 6.1 Hydrogeochemical Models and Concepts 6.1.1 Development of Secondary Permeability of a Fracture Aquifer in Carbonate Rocks: a Model / W. Dreybrodt 6.1.2 Some Aspects of Modelling the Carbon System in the Unsaturated Zone / B. Merkel, L. Eichinger and P. Udluft 6.1.3 Methodical Concepts in Silicate-Water Interaction - a Comparison of Results / A. Dahmke, G. Matthess, A. Petersen and D. Schenk 6.2 Combination of Transport and Geochemical Reactions 6.2.1 Water Movement and Geochemical Reactions in the Unsaturated Zone of Sands with Low Calcite Contents / H.-D. Schulz 6.2.2 Physical and Biochemical Processes Affecting Mass Transport in the Bocholt Aquifer System / C. Bugner and R. Mull 6.2.3 Tritium and 3He Measurements as Calibration Data for Ground Water Transport Models / H. Dörr, P. Schlosser, M. Stute and C. Sonntag 6.2.4 39Ar-, 85Kr-, 3He- and 3H Isotope Dating of Ground Water in the Bocholt and Segeberger Forst Aquifer Systems / M. Forster, H. Loosli and S. Weise 6.2.5 Modelling of Mass Balance and of Microbial Transformations in the Fuhrberger Feld Sandy Aquifer / O. Strebet, J. Böttcher and W.H.M. Duynisveld 6.3 Description of Geochemical Environments with Thermodynamic Equilibrium Models / M. Rolling and H.-D. Schulz 6

Note: Zugl.: Karlsruhe, Univ. Fridericiana, Diss, 2009

Note: San Diego, Univ. of California, Diss., 1992

Note: Chapter 1. Preface: Noble Gases – Noble Science by Alex N. Halliday, p. 1 - 20 Chapter 2. An Overview of Noble Gas Geochemistry and Cosmochemistry by Donald Porcelli, Chris J. Ballentine, Rainer Wieler, p. 21 - 70 Chapter 3. Noble Gases in the Solar System by Rainer Wieler, p. 71 - 100 Chapter 4. Noble Gases in the Moon and Meteorites: Radiogenic Components and Early Volatile Chronologies by Timothy D. Swindle, p. 101 - 124 Chapter 5. Cosmic-Ray-Produced Noble Gases in Meteorites by Rainer Wieler, p. 125 - 170 Chapter 6. Martian Noble Gases by Timothy D. Swindle, p. 171 - 190 Chapter 7. Origin of Noble Gases in the Terrestrial Planets by Robert O. Pepin, Donald Porcelli, p. 191 - 246 Chapter 8. Noble Gas Isotope Geochemistry of Mid-Ocean Ridge and Ocean Island Basalts: Characterization of Mantle Source Reservoirs by David W. Graham, p. 247 - 318 Chapter 9. Noble Gases and Volatile Recycling at Subduction Zones by David R. Hilton, Tobias P. Fischer, Bernard Marty, p. 319 - 370 Chapter 10. The Storage and Transport of Noble Gases in the Subcontinental Lithosphere by Tibor J. Dunai, Donald Porcelli, p. 371 - 410 Chapter 11. Models for the Distribution of Terrestrial Noble Gases and the Evolution of the Atmosphere by Donald Porcelli, Chris J. Ballentine, p. 411 - 480 Chapter 12. Production, Release and Transport of Noble Gases in the Continental Crust by Chris J. Ballentine, Pete G. Burnard, p. 481 - 538 Chapter 13. Tracing Fluid Origin, Transport and Interaction in the Crust by Chris J. Ballentine, Ray Burgess, Bernard Marty, p. 539 - 614 Chapter 14. Noble Gases in Lakes and Ground Waters by Rolf. Kipfer, Werner. Aeschbach-Hertig, Frank. Peeters, Martin. Stute, p. 615 - 700 Chapter 15. Noble Gases in Ocean Waters and Sediments by Peter Schlosser, Gisela Winckler, p. 701 - 730 Chapter 16. Cosmic-Ray-Produced Noble Gases in Terrestrial Rocks: Dating Tools for Surface Processes by Samuel Niedermann, p. 731 - 784 Chapter 17. K-Ar and Ar-Ar Dating by Simon P. Kelley, p. 785 - 818 Chapter 18. (U-Th)/He Dating: Techniques, Calibrations, and Applications by Kenneth A. Farley, p. 819 - 844

Note: Chapter 1. The Crystal Structure of Apatite, Ca5(PO4)3(F,OH,Cl) by John M. Hughes and John Rakovan, p. 1 - 12 Chapter 2. Compositions of the Apatite-Group Minerals: Substitution Mechanisms and Controlling Factors by Yuanming Pana and Michael E. Fleet, p. 13 - 50 Chapter 3. Growth and Surface Properties of Apatite by John Rakovan, p. 51 - 86 Chapter 4. Synthesis, Structure and Properties of Monazite, Pretulite, and Xenotime by Lynn A. Boatner, p. 87 - 122 Chapter 5. The Crystal Chemistry of the Phosphate Minerals by Danielle M.C. Huminicki and Frank C. Hawthorne, p. 123 - 254 Chapter 6. Apatite in Igneous Systems by Philip M. Piccoli and Philip A. Candela, p. 255 - 292 Chapter 7. Apatite, Monazite, and Xenotine in Metamorphic Rocks by Frank S. Spear and Joseph M. Pyle, p. 293 - 336 Chapter 8. Electron Microprobe Analysis of REE in Apatite, Monazite and Xenotime: Protocols and Pitfalls by Joseph M. Pyle, Frank S. Spear, and David A. Wark, p. 337 - 362 Chapter 9. Sedimentary Phosphorites - An Example: Phosphoria Formation, Southeastern Idaho, U.S.A by Andrew C. Knudsen and Mickey E. Gunter, p. 363 - 390 Chapter 10. The Global Phosphorus Cycle by Gabriel M. Filippelli, p. 391 - 426 Chapter 11. Calcium Phosphate Biominerals by James C. Elliott, p. 427 - 454 Chapter 12. Stable Isotope Composition of Biological Apatite by Matthew J. Kohn and Thure E. Cerling, p. 455 - 488 Chapter 13. Trace Elements in Recent and Fossil Bone Apatite by Clive N. Trueman and Noreen Tuross, p. 489 - 522 Chapter 14. U-TH-Pb Dating of Phosphate Minerals by T. Mark Harrison, Elizabeth J. Catlos, and Jean-Marc Montel, p. 523 - 558 Chapter 15. (U-Th)/He Dating of Phosphates: Apatite, Monazite, and Xenotime by Kenneth A. Farley and Daniel F. Stockli, p. 559 - 578 Chapter 16. Fission Track Dating of Phosphate Minerals and the Thermochronology of Apatite by Andrew J.W. Gleadow, David X. Belton, Barry P. Kohn, and Roderick W. Brown, p. 579 - 630 Chapter 17. Biomedical Application of Apatites by Karlis A. Gross and Christopher C. Berndt, p. 631 - 672 Chapter 18. Phosphates as Nuclear Waste Forms by Rodney C. Ewing and LuMin Wang, p. 673 - 700 Chapter 19. Apatite Luminescence by Glenn A. Waychuna, p. 701 - 742

Note: Chapter 1. New Developments in Deformation Studies: High-Strain Deformation by Stephen J. Mackwell and Mervyn S. Paterson, p. 1 - 20 Chapter 2. New Developments in Deformation Experiments at High Pressure by William B. Durham, Donald J. Weidner, Shun-ichiro Karato, and Yanbin Wang, p. 21 - 50 Chapter 3. Deformation of Granitic Rocks: Experimental Studies and Natural Examples by Jan Tullis, p. 51 - 96 Chapter 4. Laboratory Constraints on the Rheology of the Upper Mantle by Greg Hirth, p. 97 - 120 Chapter 5. Partial Melting and Deformation by David L. Kohlstedt, p. 121 - 136 Chapter 6. Dislocations and Slip Systems of Mantle Minerals by Patrick Cordier, p. 137 - 180 Chapter 7. Instability of Deformation by Harry W. Green II and Chris Marone, p. 181 - 200 Chapter 8. Brittle Failure of Ice by Erland M. Schulson, p. 201 - 525 Chapter 9. Seismic Wave Attenuation: Energy Dissipation in Viscoelastic Crystalline Solids by Reid F. Cooper, p. 253 - 290 Chapter 10. Texture and Anisotropy by Hans-Rudolf Wenk, p. 291 - 330 Chapter 11. Modeling Deformation of Polycrystalline Rocks by Paul R. Dawson, p. 331 - 352 Chapter 12. Seismic Anisotropy and Global Geodynamics by Jean-Paul Montagner and Laurent Guillot, p. 353 - 386 Chapter 13. Theoretical Analysis of Shear Localization in the Lithosphere by David Bercovici and Shun-ichiro Karato, p. 387 - 420

Note: Chapter 1. Introduction to U-series Geochemistry by Bernard Bourdon, Simon Turner, Gideon M. Henderson and Craig C. Lundstrom, p. 1 - 22 Chapter 2. Techniques for Measuring Uranium-series Nuclides: 1992-2002 by Steven J. Goldstein and Claudine H. Stirling, p. 23 - 58 Chapter 3. Mineral-Melt Partitioning of Uranium, Thorium and Their Daughters by Jonathan Blundy and Bernard Wood, p. 59 - 124 Chapter 4. Timescales of Magma Chamber Processes and Dating of Young Volcanic Rocks by Michel Condomines, Pierre-Jean Gauthier, and Olgeir Sigmarsson, p. 125 - 174 Chapter 5. Uranium-series Disequilibria in Mid-ocean Ridge Basalts: Observations and Models of Basalt Genesis by Craig C. Lundstrom, p. 175 - 214 Chapter 6. U-series Constraints on Intraplate Basaltic Magmatism by Bernard Bourdon and Kenneth W. W. Sims, p. 215 - 254 Chapter 7. Insights into Magma Genesis at Convergent Margins from U-series Isotopes by Simon Turner, Bernard Bourdon and Jim Gill, p. 255 - 316 Chapter 8. The Behavior of U- and Th-series Nuclides in Groundwater by Donald Porcelli and Peter W. Swarzenski, p. 317 - 362 Chapter 9. Uranium-series Dating of Marine and Lacustrine Carbonates by R. L. Edwards, C. D. Gallup, and H. Cheng, p. 363 - 406 Chapter 10. Uranium-series Chronology and Environmental Applications of Speleothems by David A. Richards and Jeffrey A. Dorale, p. 407 - 460 Chapter 11. Short-lived U/Th Series Radionuclides in the Ocean: Tracers for Scavenging Rates, Export Fluxes and Particle Dynamics by J. K. Cochran and P. Masquè, p. 461 - 492 Chapter 12. The U-series Toolbox for Paleoceanography by Gideon M. Henderson and Robert F. Anderson, p. 493 - 532 Chapter 13. U-Th-Ra Fractionation During Weathering and River Transport by F. Chabaux, J. Riotte and O. Dequincey, p. 533 - 576 Chapter 14. The Behavior of U- and Th-series Nuclides in the Estuarine Environment by Peter W. Swarzenski, Donald Porcelli, Per S. Andersson and Joseph M. Smoakv, p. 577 - 606 Chapter 15. U-series Dating and Human Evolution by A. W. G. Pike and P. B. Pettitt, p. 607 - 630 Chapter 16. Mathematical-Statistical Treatment of Data and Errors for 230Th/U Geochronology by K. R. Ludwig, p. 631 - 656

Note: Potsdam, Univ., Diss., 2003

Note: Zugl.: Braunschweig, Techn. Univ., Diss., 2003