ALBERT

Description: This data set includes grain size analyses and SST reconstructions from core AXC1432 in Nørre Skjoldungensund, SE-Greenland. Furthermore it contains water temperatures calculated from mesurements from https://www.ICES.dk and from the HadISST dataset. Heat transport via ocean currents can affect the melting of marine-terminating glaciers in Greenland. Studying past changes of marine-terminating glaciers allows assessing the regional sensitivity of the Greenland Ice Sheet (GrIS) to ocean temperature changes in the context of a warming ocean. Here, we present a high-resolution multi-proxy marine sediment core study from Skjoldungen Fjord, close to the marine-terminating Thrym Glacier. Grain-size data is obtained to reconstruct the calving activity of Thrym Glacier, sortable silt is used as a proxy for fjord water circulation and sea surface temperatures (SSTs) are reconstructed from alkenone paleothermometry (Uk'37). Measurements of 210Pb, 137Cs and 14C indicate that the core covers the past 220 years (1796 CE to 2013 CE). Comparisons with modelled SST data (HadISST) and instrumental temperatures (ICES) suggest that the SST proxy record reflects temperature variability of the surface waters over the shelf and that alkenones are advected into the fjord. Additionally, average temperatures and the amplitude of fluctuations are influenced by alkenones advected from upstream the Irminger Current. We find that the SST record compares well with other alkenone-based reconstructions from SE-Greenland, and thus features regional shelf water variability. The calving activity as well as the terminus position of Thrym Glacier did not seem to respond to the SST variability. Limited ice-ocean interactions owing to the specific setting of the glacier would explain this. Instead, the fjord circulation may have been influenced by enhanced meltwater production as well as to larger scale changes in the AMOC.

Description: Few studies have focused on past hydroclimatic changes in the tropical coastal regions of eastern South America compared to the core South American Monsoon System (SAMS) domain. We suggest that unlike the core monsoon region, the densely populated coastal zone of eastern Brazil (which is the focus of this study) may not adhere to the typical mechanism of precession has a dominant driver of precipitation changes. This study presents sediment color reflectance, benthic foraminifera stable isotope, X-ray fluorescence (XRF), and lipid biomarker data generated from piston core M125-73-3. Core M125‐73‐3 is 1,249 cm long and was retrieved from off the coast of eastern Brazil (14°10.608′S, 38°21.178′W) from a water depth of 2106.9 m in April 2016 during RV METEOR cruise M125. Our multiproxy reconstruction has a temporal span of ~850 kyr and represents the longest continuous record of South American climate variability to date.

Description: The evolution of the South Asian monsoon (SAM) is not well-constrained prior to the Pleistocene, primarily due to a lack of recovered marine sediment archives. This study presents geochemical data from Site NGHP-01-01A in the eastern Arabian Sea from the Oligocene to Early Miocene (~32–20 Ma) to reconstruct the oceanographic evolution of this region through this interval. Analyses consist of planktic and benthic foraminiferal oxygen and carbon isotopes, and planktic foraminiferal trace elements (Mg/Ca and Mn/Ca), as well as seawater d18O (d18Osw) and Mg/Ca-derived temperatures. Along with XRF-derived elemental analysis, these reveal the Oligocene–Miocene transition (~23.7–22.7 Ma) to be a key initiation/intensification of the proto-SAM system, with the development of an intense oxygen minimum zone and monsoonal atmospheric circulation.

Description: This dataset includes planktic foraminifera (Globigerinoides ruber sensu-stricto) stable oxygen isotope and Mg/Ca data from IODP Expedition 353, Sites U1446 and U1448 across Marine Isotope Stage 5 (140-70 ka). Additionally, included is a time-series of annual change in precipitation as emulated by PaleoPGEM across 6 large-scale low-latitude regions throughout Marine Isotope Stage 5 (140-70 Ka).

Description: We compiled modern and fossil relative abundance of coccolithophore species Florisphaera profunda from published and unpublished datasets, along with ocean environmental variable data from satellite remote sensing and physical measurements. The database includes relative abundances of F. profunda in sediment trap (n = 26) and core-top (n = 1258), and sediment core samples (n = 104). Downcore data covers the Last Glacial Maximum (n = 94, 24-19 ka) or the Mid-to-Late Holocene (n = 77, 〈6 ka). This database allows studying modern and past biogeography of F. profunda as a response to changing ocean and climate conditions, “Quantitative reconstruction of primary productivity in low latitudes during the last glacial maximum and the mid-to-late Holocene from a global Florisphaera. profunda calibration dataset” (Hernández-Almeida et al., 2018).

Description: This dataset presents the XRF core-scanning record from International Ocean Discovery Program (IODP) Site U1478 off the Limpopo River mouth (Mozambique Channel, SW Indian Ocean) spanning the past c. 4 Ma. Site U1478 was drilled in the northernmost Natal Valley, on the Inharrime Terrace (25°49.26′ S; 34°46.16′ E) at a water depth of 488 m below sea level. The XRF core scanning of the ~257-m-long splice for Site U1478 was carried out using an Itrax Core Scanner at Lamont-Doherty Earth Observatory Core Repository, Columbia University (USA). In total, 239 sections (archive halves) were scanned at a voltage of 30 kV and a tube current of 55 mA using a Cr tube and employing an exposure time of 2 seconds. Measurement spacing was set at 2 mm, with downcore and crosscore slit sizes set at 2 mm and 2 cm, respectively. The individual element counts were normalized using the ratio of raw total counts of a given element to the total counts of all processed elements for the respective measurement position. To eliminate non-linear matrix effects and constant-sum constraints, log ratios were applied on the elemental ratios. The age model of Site U1478 is based on cyclostratigraphic analysis of the XRF-based log(Ti/Ca) record and its tuning to ice-volume, precession and eccentricity cycles.

Description: Seven different labs XRF scanned the same seven marine sediment sections. Additionally, four labs XRF scanned pellets that had known compositions determined by ICP-ES and ICP-MS. These datasets contain the XRF scanning results of the seven sediment section and four pellets. The seven 1.5 m core sections of marine sediment core used in this study were drilled during Integrated Ocean Drilling Program (IODP) Expedition 346 at Site U1424 in the Japan Basin (40°11.39'N, 138°13.90'E, 2808 m water depth) and Site U1425 on the Yamato Rise (39°29.43' N, 134°26.55' E, 1909 m water depth). The sections selected (Hole U1424C Sections 1H4, 2H5, 3H5 and Hole U1425C Sections 2H3, 2H4, and 2H6, and 3H6) cover a range of sediment compositions. U-channels extracted continuous marine sediment approximately 1 cm thick from the center of each split core section. One lab scanned sections from different holes at the same sites (U1424A, U1425B, and U1425D) that were stratigraphically aligned with the sections listed above. Over the course of four years (2014 to 2017), the set of seven u-channels was shipped around the world to seven labs with XRF scanners including, in no particular order, the Kochi Core Center at Kochi University (Japan), IODP Core Repository at Texas A&M University (U.S.A.), Nanjing Normal University (China), Rosenstiel School of Marine and Atmospheric Science at the University of Miami (U.S.A.), ETH Zurich (Switzerland), Woods Hole Oceanographic Institution (U.S.A.), and the Royal Netherlands Institute of Sea Research (The Netherlands). We intentionally do not identify which lab generated which scans, as many of the variables (e.g., X-ray tube aging, detector aging, and/or dehydration of the core material) could affect any instrument at various times or be exacerbated during the transit between labs. Instead, we label the XRF scans #1-#7 in the order in which they were scanned. The lead investigators overseeing the XRF scanning in these labs were shipboard participants on IODP Expedition 346 and are among the authors of this paper. The only instructions to each lab were "to XRF scan the seven sediment sections at 1mm or 2mm resolution using the approach and elements typical for paleoceanographic research performed in your lab." To emulate variations in the XRF results that have been previously published, these simple guidelines were intentionally broad and general to determine the degree of intercomparability between the labs amongst all the different settings and nuances of XRF scanning. The labs used various types and different generations of XRF scanning instruments (4 Avaatech Core Scanners, 2 ITRAX Core Scanners, and 1 Geotek Core Scanning Logger) with different X-ray sources (Rhodium, Molybdenum). Three of the labs scanned the cores at two or three excitation energies (e.g., 10 kV, 30 kV, and 50 kV). Each lab reported a different suite of elements, but all included Ca, Fe, K, Mn, Si, Sr, Ti, and Zr. Six labs also reported Al, Br, Cr, Cu, Ni, Pb, Rb, S, and Zn and five labs reported and Ba, Cl, Ga, Mo, V, and Y. In addition to the seven core sediment sections, we freeze-dried and powdered four discrete samples that were pressed into disc-shaped pellets about 2 cm in diameter from nearby Core MD01-2407 on the Oki Ridge (37°04'N, 134°42'E, 932m water depth). The four samples have a similar matrix to the seven sediment sections scanned in this study. The four samples from Core MD01-2407 covered a range of sediment types (calcareous, siliceous, light-, and dark-colored; Kido et al., 2007) that span the dynamic range of at least Fe and Ca element cps scanned for this study. A set of four pellets was sent to four of the seven labs (1 ITRAX and 3 Avaatech) involved in the study to be scanned using the same instrument parameters they used on the sediment sections. Three labs used the same instrument and parameters used for the sediment section, but the fourth lab replaced the X-ray tube in between scanning the pellets and sediment sections. The major and trace element concentrations of the pellets were also analyzed by inductively coupled plasma (ICP)-optical emission spectrometry (OES) and ICP-mass spectrometry (MS) in the Analytical Geochemistry Facilities at Boston University, Boston, MA, USA. The ICP analyses had ~2% precision and a standard reference material analyzed as an unknown alongside the samples was accurate within precision.

Description: The early Eocene epoch was characterized by extreme global warmth, which in terrestrial settings was characterized by an expansion of near-tropical vegetation belts into the high latitudes. During the middle to late Eocene, global cooling caused the retreat of tropical vegetation to lower latitudes. In high-latitude settings, near-tropical vegetation was replaced by temperate floras. This floral change has recently been traced as far south as Antarctica, where along the Wilkes Land margin paratropical forests thrived during the early Eocene and temperate Nothofagus forests developed during the middle Eocene. Here we provide both qualitative and quantitative palynological data for this floral turnover based on a sporomorph record recovered at Integrated Ocean Drilling Program (IODP) Site U1356 off the Wilkes Land margin. Following the nearest living relative concept and based on a comparison with modern vegetation types, we examine the structure and diversity patterns of the Eocene vegetation along the Wilkes Land margin. Our results indicate that the early Eocene forests along the Wilkes Land margin were characterized by a diverse canopy composed of plants that today occur in tropical settings; their richness pattern was similar to that of present-day forests from New Caledonia. The middle Eocene forests were characterized by a canopy dominated by Nothofagus and exhibited richness patterns similar to modern Nothofagus forests from New Zealand.

Description: Neodymium isotopes are becoming widely used as a palaeoceanographic tool for reconstructing the source and flow direction of water masses. A new method using planktonic foraminifera which have not been chemically cleaned has proven to be a promising means of avoiding contamination of the deep ocean palaeoceanographic signal by detrital material. However, the exact mechanism by which the Nd isotope signal from bottom waters becomes associated with planktonic foraminifera, the spatial distribution of rare earth element (REE) concentrations within the shell, and the possible mobility of REE ions during changing redox conditions, have not been fully investigated. Here we present REE concentration and Nd isotope data from mixed species of planktonic foraminifera taken from plankton tows, sediment traps and a sediment core from the NW Atlantic. We used multiple geochemical techniques to evaluate how, where and when REEs become associated with planktonic foraminifera as they settle through the water column, reside at the surface and are buried in the sediment. Analyses of foraminifera shells from plankton tows and sediment traps between 200 and 2938 m water depth indicate that only ~20% of their associated Nd is biogenically incorporated into the calcite structure. The remaining 80% is associated with authigenic metal oxides and organic matter, which form in the water column, and remain extraneous to the carbonate structure. Remineralisation of these organic and authigenic phases releases ions back into solution and creates new binding sites, allowing the Nd isotope ratio to undergo partial equilibration with the ambient seawater, as the foraminifera fall through the water column. Analyses of fossil foraminifera shells from sediment cores show that their REE concentrations increase by up to 10-fold at the sediment-water interface, and acquire an isotopic signature of bottom water. Adsorption and complexation of REE3+ ions between the inner layers of calcite contributes significantly to elevated REE concentrations in foraminifera. The most likely source of REE ions at this stage of enrichment is from bottom waters and from the remineralisation of oxide phases which are in chemical equilibrium with the bottom waters. As planktonic foraminifera are buried below the sediment-water interface redox-sensitive ion concentrations are adjusted within the shells depending on the pore-water oxygen concentration. The concentration of ions which are passively redox sensitive, such as REE3+ ions, is also controlled to some extent by this process. We infer that (a) the Nd isotope signature of bottom water is preserved in planktonic foraminifera and (b) that it relies on the limited mobility of particle reactive REE3+ ions, aided in some environments by micron-scale precipitation of MnCO3. This study indicates that there may be sedimentary environments under which the bottom water Nd isotope signature is not preserved by planktonic foraminifera. Tests to validate other core sites must be carried out before downcore records can be used to interpret palaeoceanographic changes.

Description: Few high-latitude terrestrial records document the timing and nature of the Cenozoic "Greenhouse" to "Icehouse" transition. Here we exploit the bulk geochemistry of marine siliciclastic sediments from drill cores on Antarctica's continental margin to extract a unique semiquantitative temperature and precipitation record for Eocene to mid-Miocene (~54-13 Ma). Alkaline elements are strongly enriched in the detrital mineral fraction in fine-grained siliciclastic marine sediments and only occur as trace metals in the biogenic fraction. Hence, terrestrial climofunctions similar to the chemical index of alteration (CIA) can be applied to the alkaline major element geochemistry of marine sediments on continental margins in order to reconstruct changes in precipitation and temperature. We validate this approach by comparison with published paleotemperature and precipitation records derived from fossil wood, leaves, and pollen and find remarkable agreement, despite uncertainties in the calibrations of the different proxies. A long-term cooling on the order of 〉=8°C is observed between the Early Eocene Climatic Optimum (~54-52 Ma) and the middle Miocene (~15-13 Ma) with the onset of transient cooling episodes in the middle Eocene at ~46-45 Ma. High-latitude stratigraphic records currently exhibit insufficient temporal resolution to reconstruct continental aridity and inferred ice-sheet development during the middle to late Eocene (~45-37 Ma). However, we find an abrupt aridification of East Antarctica near the Eocene-Oligocene transition (~34 Ma), which suggests that ice coverage influenced high-latitude atmospheric circulation patterns through albedo effects from the earliest Oligocene onward.