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  • Inorganic Chemistry  (83,670)
  • ASTROPHYSICS  (16,581)
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  • 1
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    [Editors' Choice] A pair of tablemates for aromatic benzene (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-09-09
    Description: Author: Jake Yeston
    Keywords: Inorganic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
    Published by American Association for the Advancement of Science (AAAS)
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  • 2
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    [Editors' Choice] Fluorine frolicking with eight friends (2017)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2017-02-10
    Description: Author: Jake Yeston
    Keywords: Inorganic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
    Published by American Association for the Advancement of Science (AAAS)
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  • 3
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    [This Week in Science] Coordinated scission of N–H or O–H bonds (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-11-11
    Description: Author: Jake Yeston
    Keywords: Inorganic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
    Published by American Association for the Advancement of Science (AAAS)
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  • 4
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    [This Week in Science] A salty route to an all-nitrogen ring (2017)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2017-01-27
    Description: Author: Jake Yeston
    Keywords: Inorganic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
    Published by American Association for the Advancement of Science (AAAS)
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  • 5
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    [Perspective] Polynitrogen chemistry enters the ring (2017)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2017-01-27
    Description: Polynitrogens have the potential for ultrahigh-performing explosives or propellants because singly or doubly bonded polynitrogens can decompose to triply bonded dinitrogen (N2) with an extraordinarily large energy release. The large energy content and relatively low activation energy toward decomposition makes the synthesis of a stable polynitrogen allotrope an extraordinary challenge. Many elements exist in different forms (allotropes)—for example, carbon can exist as graphite, diamond, buckyballs, or graphene. However, no stable neutral allotropes are known for nitrogen, and only two stable homonuclear polynitrogen ions had been isolated until now—namely, the N3− anion (1) and the N5+ cation (2). On page 374 of this issue, Zhang et al. (3) report the synthesis and characterization of the first stable salt of the cyclo-N5− anion, only the third stable homonuclear polynitrogen ion ever isolated. Author: Karl O. Christe
    Keywords: Inorganic Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
    Published by American Association for the Advancement of Science (AAAS)
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  • 6
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    ICE navigation support (1986)
    In:  CASI
    Details
    Publication Date: 2009-11-17
    Description: The International Cometary Explorer (ICE) encounter with Comet Giacobini-Zinner took place 7 years after the spacecraft's original launch on 12 August 1978 as the International Sun Earth Explorer 3 (ISEE-3), part of a three-spacecraft project to study the interaction between the solar wind and the Earth's magnetosphere. Transfer to an interplanetary trajectory was performed via a 119-km-altitute, gravity-assist, lunar swingby on December 1983. Navigation support during interplanetary cruise and comet encounter was provided by orbit determination utilizing radio metric data from the DSN 64-meter antennas in Goldstone, California and Madrid, Spain. Orbit solutions yielding predictions of 50-km geocentric delivery accuracy in the target aim plane were achieved during interplanetary cruise and at comet encounter using 6-to-12-week data arcs between periodic attitude-change maneuvers. One-sigma two-way range and range rate residuals were consistently 40 meters and 0.2 mm/s or better, respectively. Non-gravitational forces affected the comet's motion during late August and early September 1985 and caused a 2300-km shift in the orbit of the comet relative to the spacecraft. This necessitated a final ICE orbit trim maneuver 3 days prior to encounter. Near-real-time assessment of two-way 2-GHz (S-band) Doppler pseudo-residuals during the June and July 1985 trajectory change maneuvers aided in calibration of the spacecraft's thrusters in preparation for this final critical maneuver. Post-flight analysis indicates tail centerline passage was achieved within 10 seconds of the predicted time and geocentric position uncertainty at encounter was less than 40 km.
    Keywords: ASTROPHYSICS
    Type: The Telecommunications and Data Acquisition Report (date]; p 268 - 283
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  • 7
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    An ensemble pulsar time (1993)
    In:  CASI
    Details
    Publication Date: 2004-12-03
    Description: Millisecond pulsars are galactic objects that exhibit a very stable spinning period. Several tens of these celestial clocks have now been discovered, which opens the possibility that an average time scale may be deduced through a long-term stability algorithm. Such an ensemble average makes it possible to reduce the level of the instabilities originating from the pulsars or from other sources of noise, which are unknown but independent. The basis for such an algorithm is presented and applied to real pulsar data. It is shown that pulsar time could shortly become more stable than the present atomic time, for averaging times of a few years. Pulsar time can also be used as a flywheel to maintain the accuracy of atomic time in case of temporary failure of the primary standards, or to transfer the improved accuracy of future standards back to the present.
    Keywords: ASTROPHYSICS
    Type: NASA. Goddard Space Flight Center, The 24th Annual Precise Time and Time Interval (PTTI) Applications and Planning Meeting; p 73-86
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  • 8
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    Potential applications of GSC-2 for GAIA operations (1995)
    In:  Other Sources
    Details
    Publication Date: 2011-08-24
    Description: The second guide star catalog (GSC-2) is a project that aims to create a complete catalog of stars and galaxies to about the 18th magnitude, and would contain colors, magnitudes, positions and proper motions. The catalog would provide an object list for the construction of an input catalog for possible future astrometric satellites, such as the global astrometric interferometer for astrophysics (GAIA) satellite. With a schedule that is compatible with the projected timeframe of GAIA, the GSC-2 could be available in time to support the preparatory astrophysical observations for an input catalog. The availability of the digitalized images for the preparation of finding charts would improve the efficiency of this task.
    Keywords: ASTROPHYSICS
    Type: ESA, Future Possibilities for Astrometry in Space; p 137-141
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  • 9
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    Time delay in the Einstein ring PKS 1830-211 (1995)
    In:  Other Sources
    Details
    Publication Date: 2011-08-24
    Description: We present radio observations of the gravitational lens PKS 1830-211 at 8.4 and 15 GHz acquired using the Very Large Array. The observations were made over a 13 month period. Significant flux density changes over this period provide strong constraints on the time delay between the two lensed images and suffest a value of 44 +/- 9 days. This offers new direct evidence that this source is indeed a gravitational lens. The lens distance is dependent upon the model chosen, but reasonable limits on the mass of the lensing galaxy suggest that it is unlikely to be at a redshift less than a few tenths, and may well be significantly more distant.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 444; 2; p. 561-566
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  • 10
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    Calculations of the outflow velocity of envelopes of cool giants (1994)
    In:  Other Sources
    Details
    Publication Date: 2011-08-24
    Description: We study the transfer of momentum from photons to dust grains to (molecular) gas in the outflow around cool giants (carbon-stars, Mira variables and OH/IR stars) beyond the radius where the dust grains condense. The problem is circular: radiation pressure determines the outflow velocity of the dust and thus also the dust density; on the other hand the dust density determines, via radiative transfer effects, the spectrum of the photons and thus the effective radiation pressure. This circular problem is solved by a rapidly converging iterative procedure. We compare our predictions with observed properties of a large sample of OH/IR stars and of Miras and find a good qualitative and quantitative agreement. We confirm a conclusion by Wood et al. (1993) that very luminous OH/IR stars in the Large Magellanic Cloud (LMC) owe their low outflow velocity to the low dust-to-gas ratio, a consequence of the low metallicity of the LMC. Similarly we consider a sample of about 100 OH/IR stars within 200 pc from the galactic center that has an average asymptotic giant branch (AGB) luminosity and an uncommonly high value of v(sub out); we conclude that these stars are probably very metal rich, perhaps even more than the stars in the Baade window studied by Rich (1990).
    Keywords: ASTROPHYSICS
    Type: Astronomy and Astrophysics (ISSN 0004-6361); 286; 2; p. 523-534
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