Summary
The reactions of 1,3-phenylenediacetatodicopper(I) pyridine, prepared from 1,3-phenylenediacetatocopper(II) by metallic copper, were studied. On oxygenation, a copper-dioxygen complex was formed, whereas carbon monoxide yielded an unstable carbonyl complex. The complexes were characterised by spectroscopic measurements.
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References
K. D. Karlin and J. Zubieta (Eds), Copper Coordination Chemistry: Biochemical and Inorganic Perspectives, Adenine Press, New York, 1983.
R. A. Sheldon and J. K. Kochi (Eds), Metal-Catalyzed Oxiations of Organic Compounds, Academic Press, New York, 1981.
D. W. Margerun and G. D. Owens, Met. Ions. Biol. Syst., 13, 73 (1981).
R. S. Himmelwright, N. C. Eickman and E. I. Solomon, J. Am. Chem. Soc., 101, 1576 (1979).
R. S. Himmelwright, N. C. Eickman, C. D. LuBien and E. I. Solomon, J. Am. Chem. Soc., 102, 5378 (1980).
R. S. Himmelwright, N. C. Eickman, C. D. LuBien, K. Lerch and E. I. Solomon, J. Am. Chem. Soc., 102, 7339 (1980).
R. J. Motekaitis and A. E. Martell, Inorg. Chem., 18, 2982 (1979).
J. E. Bulkowski, P. L. Burk, M. F. Ludmann and J. A. Osborn, J. Chem. Soc., Chem. Commun., 498 (1977).
P. L. Burk, J. A. Osborn, M. T. Youinou, Y. Agnus, R. Louis and R. Weiss, J. Am. Chem. Soc., 103, 1273 (1981).
K. D. Karlin, R. M. Cruse, G. F. Kokoska and J. J. Orsini, Inorg. Chim. Acta, 66, L57 (1982).
K. D. Karlin, J. R. Hyde and J. Zubieta, Inorg. Chim. Acta, 66, L23 (1982).
K. D. Karlin, P. L. Dahlstrom, S. N. Cozzette, P. M. Scensny and J. Zubieta, J. Chem. Soc., Chem. Commun., 881 (1981).
K. D. Karlin, Y. Gultneh, J. P. Hutchinson and J. Zubieta, J. Am. Chem. Soc., 104, 5240 (1982).
L. Casella and L. Rigoni, J. Chem. Soc., Chem. Commun., 1668 (1985).
Z. Tyeklár and K. D. Karlin, Acc. Chem. Res., 22, 241 (1989).
K. D. Karlin, B. I. Cohen, A. Farooq, S. Liu and J. Zubieta, Inorg. Chim. Acta, 153, 9 (1988).
N. J. Blackburn, K. D. Karlin, M. Concannon, J. C. Hayes, Y. Gultneh and J. Zubieta, J. Chem. Soc., Chem. Commun., 939 (1984).
T. N. Sorrell, M. R. Malachowski and D. L. Jameson, Inorg. Chem., 21, 3250 (1982).
L. Casella and S. Ghelli, Inorg. Chem., 22, 2458 (1983).
R. C. Mehrotra and R. Bohra, Metal Carboxylates, Academic Press, London, 1983.
B. Hammond, F. H. Jardine and A. G. Vohra, J. Inorg. Nucl. Chem., 33, 1017 (1971).
M. A. Cabras and L. Naldini, Inorg. Chim. Acta, 104, L19 (1985).
G. Speier and Z. Tyeklár, Transition Met. Chem., 17, 348 (1992).
S. Kitagawa and M. Munakata, Inorg. Chem., 20, 2261 (1981).
M. Pasquali, C. Floriani, A. Gaetani-Manfredotti and C. Guastini, J. Am. Chem. Soc., 103, 185 (1981).
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Balogh-Hergovich, É., Speier, G. Reaction of the 1,3-phenylenediacetatodicopper(I) pyridine complex with dioxygen, hydrogen peroxide and carbon monoxide. Transition Met Chem 19, 123–125 (1994). https://doi.org/10.1007/BF00166287
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DOI: https://doi.org/10.1007/BF00166287