Abstract
Hydrochloric acid catalyzed hydrolysis of benzohydroxamic acid (C6H5CONHOH) has been studied in dioxane, acetone, DMSO, DMF, methanol, ethanol and isopropanol of varying compositions (10–70 vol.%) at 55°C. The anomalous behavior has been explained on the basis of solvent properties, solvation of the transition state and dielectric constant.
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Ghosh, K.K., Krishnani, K.K. Medium effects in the acid catalyzed hydrolysis of benzohydroxamic acid in binary aqueous mixtures. React Kinet Catal Lett 49, 403–409 (1993). https://doi.org/10.1007/BF02067709
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DOI: https://doi.org/10.1007/BF02067709