Abstract
By static magnetic measurements it was found that the ability to reduction of an amorphous NiO−Al2O3/SiO2 catalyst decreases in the order: but-2-enes∼hydrogen∼ ∼isobutene>but-1-ene>propene∼ethene. The reduction temperatures are significantly higher than the dimerization reaction temperatures.
Abstract
На основе статических магнитных измерений было найдено, что способность к восстановлению на аморфном катализаторе NiO−Al2O3/SiO2 уменьшается в следующем порядке: бутилен-2∼водород∼изобутилен>бутилен-1> пропилен∼этилен. Температуры восстановления значительно выше температур димеризации.
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Kiessling, D., Wendt, G., Jusek, M. et al. Reduction of an amorphous NiO−Al2O3/SiO2 catalyst by different olefins and hydrogen. React Kinet Catal Lett 43, 255–259 (1991). https://doi.org/10.1007/BF02075442
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DOI: https://doi.org/10.1007/BF02075442