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A kinetic study of the intercalation of ethanol into vanadyl phosphate

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Abstract

The course of intercalation of ethanol into VOPO4 has been studied by X-ray diffraction, thermomechanical analysis and a volumetric method. In all cases the kinetic curves were observed to have a sigmoidal shape. A model, based on the Avrami equation, has been proposed for description of the kinetic behavior. The activation energy of intercalation based on this model has been determined. The existence of the advancing phase boundary in the system during intercalation has been confirmed.

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Authors and Affiliations

  1. Joint Laboratory of Solid State Chemistry of the Academy of Sciences of the Czech Republic, University of Pardubice, Studentská 84, 530 09, Pardubice, Czech Republic

    Ludvík Beneš, Vítězslav Zima & Iveta Baudyšová

  2. Department of General and Inorganic Chemistry, University of Pardubice, Čs. Legii 565, 532 10, Pardubice, Czech Republic.

    Jiří Votinský

Authors
  1. Ludvík Beneš
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  2. Vítězslav Zima
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  3. Iveta Baudyšová
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  4. Jiří Votinský
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Beneš, L., Zima, V., Baudyšová, I. et al. A kinetic study of the intercalation of ethanol into vanadyl phosphate. J Incl Phenom Macrocycl Chem 26, 311–319 (1996). https://doi.org/10.1007/BF01053548

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  • DOI: https://doi.org/10.1007/BF01053548

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