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Synthesis and structure of 2,5,7,10-tetramethyl-2,4,8,10-tetraazabicyclo[4.4.0]decane-3,9-dione

  • Organic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

2,5,7,10-Tetramethyl-2,4,8,10-tetraazabicyclo[4.4.0]decane-3,9-dione, a regioisomer of the previously known 2,5,7,8-tetramethyl-2,4,8,10-tetraazabicyclo[4.4.0]decane-3,9-dione, has been synthesized, and its structure has been established by X-ray diffraction analysis. The bicyclic system of this molecule is formed by two heterocyclescis-annelated through the C(1)-C(6) bond. The relative configurations of the asymmetric centers areS for C(5), andR for C(7). In the monohydrate crystal studied, the molecules are linked by O...H-Ow and O...H-N type H-bonds forming a three-dimensional framework.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    M. O. Dekaprilevich, A. N. Kravchenko, L. I. Khmel'nitskii, O. V. Lebedev & Yu. A. Strelenko

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    Yu. T. Struchkov

Authors
  1. M. O. Dekaprilevich
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  2. A. N. Kravchenko
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  3. L. I. Khmel'nitskii
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  4. O. V. Lebedev
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  5. Yu. T. Struchkov
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  6. Yu. A. Strelenko
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 136–138, January, 1995.

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Dekaprilevich, M.O., Kravchenko, A.N., Khmel'nitskii, L.I. et al. Synthesis and structure of 2,5,7,10-tetramethyl-2,4,8,10-tetraazabicyclo[4.4.0]decane-3,9-dione. Russ Chem Bull 44, 131–133 (1995). https://doi.org/10.1007/BF00696973

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  • DOI: https://doi.org/10.1007/BF00696973

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