Conclusions
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1.
A method has been worked out for radical addition of acetaldehyde to 1-olefins, which is initiated by atmospheric oxygen in the presence of catalytic amounts of cobalt acetate.
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2.
Initiation of reaction is effected because of decomposition of intermediate products of aldehyde oxidation by the catalyst.
Literature cited
G. I. Nikishin, M. G. Vinogradov, and R. V. Kereselidze, Izv. AN SSSR, ser. khim.,1966, 1846.
G. I. Nikishin, M. G. Vinogradov, and R. V. Kereselidze, Izv. AN SSSR, ser. khim.,1966, 1122.
N. M. Emanuel', E. T. Denisov, and Z. K. Maizus, Chain Reactions of Hydrocarbon Oxidation in the Liquid Phase, “Nauka” Press [in Russian], 1965, p. 206.
G. I. Nikishin, M. G. Vinogradov, and R. V. Kereselidze, Zh. Organ. Khimii,2, 1918 (1966).
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Translated from Izvestiya Akademii Nauk SSSR, No. 7, pp. 1624–1626, July, 1967.
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Nikishin, G.I., Vinogradov, M.G. & Kereselidze, R.V. Addition of acetaldehyde to 1-heptene initiated by catalytic oxidation. Russ Chem Bull 16, 1570–1572 (1967). https://doi.org/10.1007/BF00905380
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DOI: https://doi.org/10.1007/BF00905380