Abstract
The corresponding 1,2,3,4,4a, 9,9a, 10-octahydro derivatives were obtained in the catalytic hydrogenation of 10,10-dimethyl- and 10-methyl-10-phenyl-9,10-dihydro-10-sila-2-azaanthracenes. The hydrogenation of 10,10-dimethyl-10-sila-2-azaanthrone also leads to a substituted octahydrosilaazaanthracene. Isomeric (with respect to the position of the double bond in the nitrogen-containing ring) hexahydrosilaaza-9-anthrols were isolated as a result of the reduction of the methiodide of this silaazaanthrone with sodium borohydride.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature Cited
N. S. Prostakov, G. Alvorado-Urbina, M. A. Ryashentseva, and L. A. Gaivoronskaya, Khim. Geterotsikl. Soedin., No. 10, 1379 (1973).
N. S. Prostakov, V. I. Kuznetsov, M. A. Ryashentseva, and L. M. Kirillova, Khim. Geterotsikl. Soedin., No. 4, 517 (1979).
N. S. Prostakov, N. Saksena, A. V. Varlamov, and A. M. Klochkov, Khim. Geterotsikl. Soedin., No. 2, 240 (1981).
F. R. Jensen and C. H. Bushweller, Adv. Alicyclic Chem., 3, 139 (1971).
N. S. Prostakov, N. Saxena, P. I. Zakharov, and A. V. Varlamov, J. Organomet. Chem., 184, 167 (1980).
L. Bellamy, Infrared Spectra of Complex Molecules, Methuen, London (1958).
V. F. Bystrov, Usp. Khim., 41, 512 (1972).
V. A. Rezakov, S. K. Das, A. A. Fomichev, and N. S. Prostakov, Khim. Geterotsikl. Soedin., No. 10, 1367 (1986).
Author information
Authors and Affiliations
Additional information
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1279–1284, September, 1990.
Rights and permissions
About this article
Cite this article
Prostakov, N.A., Varlamov, A.V., Ryashentseva, M.A. et al. 10-Sila-2-azaanthracenes hydrogenated in the pyridine fragment. Chem Heterocycl Compd 26, 1068–1072 (1990). https://doi.org/10.1007/BF00472495
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00472495