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Influence of iron oxide coating on the tribological behavior of sand grain contacts

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Abstract

Granular materials are often subjected to certain degrees of coating in natural conditions due to weathering and soil–environment interactions and the current literature has suggested that the development of surface coatings has an important influence on the macroscopic response of geological materials. In the present study, a new method was developed to artificially coat sand grains with iron oxides and a series of experiments were performed for surface morphological and mechanical characterization as well as quantification of the tribological behavior of iron oxides coated grains. Through the material characterization tests, it was observed that the artificial iron oxides coating notably altered the roughness and hardness of the grains, which in turn resulted in higher inter-particle friction and lower normal contact stiffness. Clear dependency of the coefficient of friction on the magnitude of normal load and the loading history was observed for the coated specimens, which is speculated to be attributed to asperity breakage, plowing damage and debris build-up of the surfaces as also supported by microscopic images. The test results could also provide, qualitatively, some multi-scale insights into the influence of iron oxide coating on the bulk behavior of natural soils as the increase in inter-particle friction angle can be linked with the observed trend of increased critical state strength.

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References

  1. Abreu MM, Robert M (1985) Characterization of maghemite in B horizons of three soils from Southern Portugal. Geoderma 36(2):97–108

    Google Scholar 

  2. Altuhafi FN, Coop MR (2011) Changes to particle characteristics associated with the compression of sands. Géotechnique 61(6):459–471

    Google Scholar 

  3. Anderson H, Berrow M, Farmer V, Hepburn A, Russell J, Walker A (1982) A reassessment of podzol formation processes. J Soil Sci 33(1):125–136

    Google Scholar 

  4. Barreto D (2009) Numerical and experimental investigation into the behaviour of granular materials under generalised stress states. Ph.D. thesis, University of London, Department of Civil Engineering, Imperial College of Science, Technology and Medicine

  5. Barreto D, O’Sullivan C (2012) The influence of inter-particle friction and the intermediate stress ratio on soil response under generalised stress conditions. Granular Matter 14:505–521

    Google Scholar 

  6. Benjamin MM, Sletten RS, Bailey RP, Bennett T (1996) Sorption and filtration of metals using iron-oxide-coated sand. Water Res 30(11):2609–2620

    Google Scholar 

  7. Birnie A, Paterson E (1991) The mineralogy and morphology of iron and manganese oxides in an imperfectly-drained Scottish soil. Geoderma 50(3):219–237

    Google Scholar 

  8. Chen X, Carpenter BM, Reches ZE (2020) Asperity failure control of stick-slip along brittle faults. Pure Appl Geophys 177(7):3225–3242. https://doi.org/10.1007/s00024-020-02434-y

    Article  Google Scholar 

  9. Choo H, Hwang J, Choi Y, Lee C, Lee W (2016) Geotechnical characteristics of volcanic beach sands with varying iron contents. Mar Georesour Geotechnol 34(6):571–580

    Google Scholar 

  10. Choo H, Larrahondo J, Burns SE (2015) Coating effects of nano-sized particles onto sand surfaces: small strain stiffness and contact mode of iron oxide–coated sands. J Geotech Geoenviron Eng 141(1):04014077

    Google Scholar 

  11. Cole DM, Hopkins MA (2016) The contact properties of naturally occurring geologic materials: contact law development. Granular Matter 19:5. https://doi.org/10.1007/s10035-016-0683-4

    Article  Google Scholar 

  12. Cole DM, Mathisen LU, Hopkins MA, Knapp BR (2010) Normal and sliding contact experiments on gneiss. Granular Matter 12(1):69–86

    Google Scholar 

  13. Cole DM, Peters JF (2007) A physically based approach to granular media mechanics: grain-scale experiments, initial results and implications to numerical modeling. Granular Matter 9:309–321

    Google Scholar 

  14. Emeh C, Igwe O, Onwo ES (2019) Potential effect of environmental pollution on the degree of dissolution of iron and aluminium oxides in lateritic soils. Environ Earth Sci 78:256

    Google Scholar 

  15. Farmer V (1984) Distribution of allophane and organic matter in podzol B horizons: reply to Buurman & Van Reeuwijk. J Soil Sci 35(3):453–458

    Google Scholar 

  16. Grotzinger J, Jordan TH (2014) Understanding earth, 7th edn. Macmillan Learning

    Google Scholar 

  17. Guillard F, Marks B, Einav I (2017) Dynamic X-ray radiography reveals particle size and shape orientation fields during granular flow. Sci Rep 7(1):8155

    Google Scholar 

  18. Hanaor DAH, Gan Y, Einav I (2013) Effects of surface structure deformation on static friction at fractal interfaces. Geotech Lett 3:52–58

    Google Scholar 

  19. Hanaor DAH, Gan Y, Einav I (2016) Static friction at fractal interfaces. Tribol Int 93:229–238

    Google Scholar 

  20. He H, Sandeep CS, Senetakis K (2019) The interface behavior of recycled concrete aggregate: a micromechanical grain-scale experimental study. Constr Build Mater 210:627–638

    Google Scholar 

  21. He H, Senetakis K (2019) An experimental study on the micromechanical behavior of pumice. Acta Geotech 14(6):1883–1904

    Google Scholar 

  22. He H, Senetakis K, Coop MR (2019) An investigation of the effect of shearing velocity on the inter-particle behavior of granular and composite materials with a new micromechanical dynamic testing apparatus. Tribol Int 134:252–263

    Google Scholar 

  23. He ZL, Zhang MK, Wilson MJ (2004) Distribution and classification of red soils in China. In: Wilson MJ, He ZL, Yang XE (eds) The red soils of China: their nature, management and utilization. Kluwer Academic Publishers, Dordrecht, pp 29–33

    Google Scholar 

  24. Hendershot WH, Lavkulich LM (1983) Effect of sesquioxide coatings on surface charge of standard mineral and soil samples. Soil Sci Soc Am J 47(6):1252–1260

    Google Scholar 

  25. Huang X, Hanley KJ, O’Sullivan C, Kwok CY (2014) Exploring the influence of interparticle friction on critical state behaviour using DEM. Int J Numer Anal Methods Geomech 38(12):1276–1297

    Google Scholar 

  26. Huang S, Misra A (2013) Micro–macro-shear-displacement behavior of contacting rough solids. Tribol Lett 51:431–436

    Google Scholar 

  27. Johnson KL (1985) Contact mechanics. Cambridge University Press, Cambridge

    MATH  Google Scholar 

  28. Joshi A, Chaudhuri M (1996) Removal of arsenic from ground water by iron oxide-coated sand. J Environ Eng 122(8):769–771

    Google Scholar 

  29. Kasyap SS, Li S, Senetakis K (2021) Investigation of the mechanical properties and the influence of micro-structural characteristics of aggregates using micro-indentation and Weibull analysis. Construct Build Mater 271:121509

    Google Scholar 

  30. Kasyap SS, Li S, Senetakis K (2021) Influence of natural coating type on the frictional and abrasion behaviour of siliciclastic-coated sedimentary sand grains. Eng Geol 281:105983

    Google Scholar 

  31. Kasyap SS, Senetakis K (2018) A micromechanical experimental study of kaolinite-coated sand grains. Tribol Int 126:206–217

    Google Scholar 

  32. Kasyap SS, Senetakis K (2019) Interface load–displacement behaviour of sand grains coated with clayey powder: experimental and analytical studies. Soils Found 59(6):1695–1710

    Google Scholar 

  33. Kasyap SS, Senetakis K (2022) Characterization of two types of shale rocks from Guizhou China through micro-indentation, statistical and machine-learning tools. J Petrol Sci Eng 208:109304

    Google Scholar 

  34. Kasyap SS, Senetakis K, Coop MR, Zhao J (2021) Micromechanical behaviour in shearing of reproduced flat LBS grains with strong and weak artificial bonds. Acta Geotech 16(5):1355–1376. https://doi.org/10.1007/s11440-020-01101-9

    Article  Google Scholar 

  35. Kasyap SS, Senetakis K, Zhao J (2021) Cyclic normal load–displacement behaviour of clay-coated sand grain contacts. Geotechnique 71(3):216–225

    Google Scholar 

  36. Kawamoto R, Andò E, Viggiani G, Andrade JE (2018) All you need is shape: predicting shear banding in sand with LSDEM. J Mech Phys Solids 111:375–392

    Google Scholar 

  37. Khare V, Mullet M, Hanna K, Blumers M, Abdelmoula M, Klingelhöfer G, Ruby C (2008) Comparative studies of ferric green rust and ferrihydrite coated sand: role of synthesis routes. Solid State Sci 10(10):1342–1351

    Google Scholar 

  38. Lai CH, Lo SL, Lin CF (1994) Mechanisms of iron oxide coating onto sand surface and its adsorption behaviors for copper. Toxicol Environ Chem 46(1–2):107–118

    Google Scholar 

  39. Larrahondo JM, Burns SE (2014) Laboratory-prepared iron oxide coatings on sands: surface characterization and strength parameters. J Geotech Geoenviron Eng 140(4):04013052

    Google Scholar 

  40. Larrahondo JM, Choo H, Burns SE (2011) Laboratory-prepared iron oxide coatings on sands: submicron-scale small-strain stiffness. Eng Geol 121(1–2):7–17

    Google Scholar 

  41. Li S, Kasyap SS, Senetakis K (2021) A study on the failure behavior of sand grain contacts with Hertz modeling, image processing, and statistical analysis. Sensors 21:4611. https://doi.org/10.3390/s21134611

    Article  Google Scholar 

  42. Li W, Kwok C, Sandeep C, Senetakis K (2019) Sand type effect on the behaviour of sand-granulated rubber mixtures: integrated study from micro-to macro-scales. Powder Technol 342:907–916

    Google Scholar 

  43. Liu B, Nie Y, Gao X, Hu K, Yang J (2017) The diagenetic geochemistry and contamination assessment of iron, cadmium, and lead in the sediments from the Shuangtaizi estuary, China. Environ Earth Sci 76:168

    Google Scholar 

  44. Liu D, Sandeep CS, Senetakis K, Nardelli V, Lourenço SDN (2019) Micromechanical behaviour of a polymer-coated sand. Powder Technol 347:76–84

    Google Scholar 

  45. Lo S-L, Jeng H-T, Lai C-H (1997) Characteristics and adsorption properties of iron-coated sand. Water Sci Technol 35(7):63–70

    Google Scholar 

  46. Luo L, Ren J, Kasyap SS, Senetakis K (2021) A note on the influence of smectite coating on the coefficient of restitution of natural sand particles impacting granitic blocks. Coatings 11:996. https://doi.org/10.3390/coatings11080996

    Article  Google Scholar 

  47. Marzulli V, Sandeep CS, Senetakis K, Cafaro F, Pöschel T (2021) Scale and water effects on the friction angles of two granular soils with different roughness. Powder Technol 377:813–826. https://doi.org/10.1016/j.powtec.2020.09.060

    Article  Google Scholar 

  48. Mate CM (2008) Tribology on the small scale: a bottom up approach to friction, lubrication, and wear. Oxford University Press

    Google Scholar 

  49. Mindlin RD, Deresiewicz H (1953) Elastic spheres in contact under varying oblique forces. J Appl Mech 20:327–344

    MathSciNet  MATH  Google Scholar 

  50. Misra A (2002) Effect of asperity damage on shear behavior of single fracture. Eng Fract Mech 69:1997–2014

    Google Scholar 

  51. Misra A, Marangos O (2011) Rock-joint micromechanics: relationship of roughness to closure and wave propagation. Int J Geomech 11(6):431–439

    Google Scholar 

  52. Mollon G, Quacquarelli A, Ando E, Viggiani G (2020) Can friction replace roughness in the numerical simulaiton of granular materials? Granular Matter 22:42. https://doi.org/10.1007/s10035-020-1004-5

    Article  Google Scholar 

  53. Nadimi S, Ghanbarzadeh A, Neville A, Ghadiri M (2020) Effect of particle roughness on the bulk deformation using coupled boundary element and discrete element methods. Comput Part Mech 7:603–613

    Google Scholar 

  54. Nadimi S, Otsubo M, Fonseca J, O'Sullivan C (2019) Numerical modelling of rough particle contacts subject to normal and tangential loading. Granular Matter 21:108. https://doi.org/10.1007/s10035-019-0970-y

    Article  Google Scholar 

  55. Nardelli V, Coop M, Andrade J, Paccagnella F (2017) An experimental investigation of the micromechanics of Eglin sand. Powder Technol 312:166–174

    Google Scholar 

  56. Ng CWW, Akinniyi DB, Zhou C (2020) Influence of structure on the compression and shear behaviour of a saturated lateritic clay. Acta Geotech 15:3433–3441

    Google Scholar 

  57. O’Sullivan C (2011) Particulate discrete element modelling: a geomechanics perspective. CRC Press

    Google Scholar 

  58. Otsubo M, O’Sullivan C (2018) Experimental and DEM assessment of the stress-dependency of surface roughness effects on shear modulus. Soils Found 58(3):602–614

    Google Scholar 

  59. Öztel MD, Akbal F, Altaş L (2015) Arsenite removal by adsorption onto iron oxide-coated pumice and sepiolite. Environ Earth Sci 73:4461–4471

    Google Scholar 

  60. Persson BNJ (2007) Relation between interfacial separation and load: a general theory of contact mechanics. Phys Rev Lett 99(12):125502

    Google Scholar 

  61. Pohrt R, Popov VL (2012) Normal contact stiffness of elastic solids with fractal rough surfaces. Phys Rev Lett 108(10):104301

    Google Scholar 

  62. Rasheed R, Meera V (2016) Synthesis of iron oxide nanoparticles coated sand by biological method and chemical method. Procedia Technol 24:210–216

    Google Scholar 

  63. Ren J, Li S, He H, Senetakis K (2021) The tribological behavior of iron tailing sand grain contacts in dry, water and biopolymer immersed states. Granular Matter 23(1):12

    Google Scholar 

  64. Sandeep CS, He H, Senetakis K (2018) An experimental micromechanical study of sand grain contacts behavior from different geological environments. Eng Geol 246:176–186

    Google Scholar 

  65. Sandeep CS, Li S, Senetakis K (2021) Scale and surface morphology effects on the micromechanical contact behavior of granular materials. Tribol Int 159:106929 https://doi.org/10.1016/j.triboint.2021.106929

    Article  Google Scholar 

  66. Sandeep CS, Senetakis K (2018) Effect of Young’s modulus and surface roughness on the inter-particle friction of granular materials. Materials 11(2):217

    Google Scholar 

  67. Sandeep CS, Senetakis K (2018) The tribological behavior of two potential-landslide saprolitic rocks. Pure Appl Geophys 175(12):4483–4499. https://doi.org/10.1007/s00024-018-1939-1

    Article  Google Scholar 

  68. Sandeep CS, Senetakis K (2018) Grain-scale mechanics of quartz sand under normal and tangential loading. Tribol Int 117:261–271

    Google Scholar 

  69. Sandeep CS, Senetakis K (2019) An experimental investigation of the microslip displacement of geological materials. Comput Geotech 107:55–67

    Google Scholar 

  70. Sandeep CS, Todisco MC, Nardelli V, Senetakis K, Coop MR, Lourenco SDN (2018) A micromechanical experimental study of highly/completely decomposed tuff granules. Acta Geotech 13(6):1355–1367

    Google Scholar 

  71. Sazzad MdM, Suzuki K (2011) Effect of interparticle friction on the cyclic behavior of granular materials using 2D DEM. J Geotech Geoenviron Eng 137(5):545–549

    Google Scholar 

  72. Scheidegger A, Borkovec M, Sticher H (1993) Coating of silica sand with goethite: preparation and analytical identification. Geoderma 58(1–2):43–65

    Google Scholar 

  73. Sharma A, Syed Z, Brighu U, Gupta AB, Ram C (2019) Adsorption of textile wastewater on alkali-activated sand. J Clean Prod 220:23–32

    Google Scholar 

  74. Silva MB, Ojea FG (1991) Iron oxide accumulations in tertiary sediments of the Roupar Basin, Galicia, NW Spain. CATENA 18(1):31–43

    Google Scholar 

  75. Soga K, O’Sullivan C (2010) Modeling of geomaterials behavior. Soils Found 50(6):861–875

    Google Scholar 

  76. Taylor R (1988) Proposed mechanism for the formation of soluble Si-Al and Fe(III)-Al hydroxy complexes in soils. Geoderma 42(1):65–77

    Google Scholar 

  77. Thirunavukkarasu OS, Viraraghavan T, Subramanian KS (2003) Arsenic removal from drinking water using iron oxide-coated sand. Water Air Soil Pollut 142(1):95–111

    Google Scholar 

  78. Tian Y, Kasyap SS, Senetakis K (2021) Influence of loading history and soil type on the normal contact behavior of natural sand grain-elastomer composite interfaces. Polymers 13:1830. https://doi.org/10.3390/polym13111830

    Article  Google Scholar 

  79. Vu-Quoc L, Zhang X (1999) An accurate and efficient tangential force–displacement model for elastic frictional contact in particle-flow simulations. Mech Mater 31(4):235–269

    Google Scholar 

  80. Wiebicke M, Ando E, Herle I, Viggiani G (2017) On the metrology of interparticle contacts in sand from x-ray tomography images. Meas Sci Technol 28(12):124007

    Google Scholar 

  81. Wiebicke M, Andò E, Šmilauer V, Herle I, Viggiani G (2019) A benchmark strategy for the experimental measurement of contact fabric. Granular Matter 21(3):54

    Google Scholar 

  82. Wiebicke M, Andò E, Viggiani G, Herle I (2020) Measuring the evolution of contact fabric in shear bands with X-ray tomography. Acta Geotech 15(1):79–93

    Google Scholar 

  83. Wooldridge LJ, Worden RH, Griffiths J, Utley JE (2019) How to quantify clay-coat grain coverage in modern and ancient sediments. J Sediment Res 89(2):135–146

    Google Scholar 

  84. Yang ZX, Yang J, Wang LZ (2012) On the influence of inter-particle friction and dilatancy in granular materials: a numerical analysis. Granular Matter 14:433–447

    Google Scholar 

  85. Yao T, Baudet BA, Lourenço SDN (2021) Evolution of surface roughness of single sand grain with normal loading. Géotechnique. https://doi.org/10.1680/jgeot.20.P.310

    Article  Google Scholar 

  86. Yimsiri S, Soga K (2000) Micromechanics-based stressstrain behaviour of soils at small strains. Geotechnique 50(5):559–571

    Google Scholar 

  87. Zhang HB, Luo YM, Wong MH, Zhao QG, Zhang GL (2006) Distributions and concentrations of PAHs in Hong Kong soils. Environ Pollut 141(1):107–114

    Google Scholar 

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Acknowledgements

The work was fully supported by a grant from the Research Grants Council of the Hong Kong Special Administrative Region, China, project no. “CityU 11210419”. The authors also acknowledge the constructive comments and suggestions by the anonymous reviewers that helped use to improve the quality of our manuscript.

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Authors and Affiliations

  1. Department of Architecture and Civil Engineering, City University of Hong Kong, Yeung Kin Man Academic Building, Blue Zone 6/F, Kowloon, Hong Kong SAR, China

    Jing Ren & Kostas Senetakis

  2. Institute of Geotechnical Engineering, Southeast University, Nanjing, 210096, China

    Huan He

  3. Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong SAR, China

    Kai-Chung Lau

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Ren, J., He, H., Lau, KC. et al. Influence of iron oxide coating on the tribological behavior of sand grain contacts. Acta Geotech. 17, 2907–2929 (2022). https://doi.org/10.1007/s11440-021-01367-7

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