Phase transitions induced by electric fields in near-critical polymer solutions

Denis Wirtz and Gerald G. Fuller
Phys. Rev. Lett. 71, 2236 – Published 4 October 1993
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Abstract

A time-dependent small-angle light scattering (SALS) study is presented which demonstrates the feasibility of electric-field-induced phase transitions in nonionic binary liquids near the critical point. Mixing of two-phase solutions induced by electric fields is shown to be a universal feature shared by a wide class of systems including upper and lower critical point polymer solutions and mixtures of low-molecular-weight molecules in a solvent. The shift of the critical temperature is computed from SALS measurements and is quadratic in the electric-field strength.

  • Received 7 June 1993

DOI:https://doi.org/10.1103/PhysRevLett.71.2236

©1993 American Physical Society

Authors & Affiliations

Denis Wirtz and Gerald G. Fuller

  • Department of Chemical Engineering, Stanford University, Stanford, California 94305-5025

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Issue

Vol. 71, Iss. 14 — 4 October 1993

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