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Behavior of octamethylbiphenylene in strongly acid media

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Octamethylbiphenylene is protonated in strong acids to give the 2-H-1,2,3,4,5,6, 7,8-octamethylbiphenylenonium ion.

  2. 2.

    Preliminary data were obtained that testify to the progress of the degenerate rearrangement of ion (II) via the 1,2-shift of the hydrogen atom (for the HCl-Al2Cl6-CH2Cl2 system ΔG ≠3 ∘ ≈ 15 kcal/mole.

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Literature cited

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Authors and Affiliations

  1. Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    S. V. Morozov, M. M. Shakirov & V. G. Shubin

Authors
  1. S. V. Morozov
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  2. M. M. Shakirov
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  3. V. G. Shubin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 204–206, January, 1983.

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Morozov, S.V., Shakirov, M.M. & Shubin, V.G. Behavior of octamethylbiphenylene in strongly acid media. Russ Chem Bull 32, 178–180 (1983). https://doi.org/10.1007/BF01167787

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  • DOI: https://doi.org/10.1007/BF01167787

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