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Reaction of alkyl diazoacetates with gaseous vinyl chloride

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The thermal and thermal catalytic gas-phase reactions of alkyl diazoacetates with excess vinyl chloride form the corresponding isomeric 2-chlorocyclopropanecarboxylic acid esters. The trans-isomer predominates and methyl diazoacetate gives maximum yield.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    I. E. Dolgii, E. A. Shapiro, A. Ya. Shteinshneider & O. M. Nefedov

Authors
  1. I. E. Dolgii
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  2. E. A. Shapiro
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  3. A. Ya. Shteinshneider
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  4. O. M. Nefedov
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Additional information

Translated from Izvestiya Akademiya Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2515–2517, November, 1977.

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Dolgii, I.E., Shapiro, E.A., Shteinshneider, A.Y. et al. Reaction of alkyl diazoacetates with gaseous vinyl chloride. Russ Chem Bull 26, 2329–2332 (1977). https://doi.org/10.1007/BF00958719

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  • DOI: https://doi.org/10.1007/BF00958719

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