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Reaction of chlorofluorocarbene with with cyclopentadiene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetics of the gas-phase reaction of chlorofluorocarbene with cyclopentadiene, leading to the formation of fluorobenzene, was studied and the rate constant was determined.

  2. 2.

    The value of the a tivation energy for the reactions of carbenes, containing multiple bonds, was experimentally determined for the first time on the example of the reaction of CClF with cyclopentadiene.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    I. D. Kushina, O. M. Nefedov, A. A. Ivashenko, S. F. Politanskii, V. U. Shevchuk, I. M. Gutor & A. Ya. Shteinshneider

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  1. I. D. Kushina
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  2. O. M. Nefedov
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  3. A. A. Ivashenko
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  4. S. F. Politanskii
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  5. V. U. Shevchuk
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  6. I. M. Gutor
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  7. A. Ya. Shteinshneider
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 728–731, March, 1974.

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Kushina, I.D., Nefedov, O.M., Ivashenko, A.A. et al. Reaction of chlorofluorocarbene with with cyclopentadiene. Russ Chem Bull 23, 696–698 (1974). https://doi.org/10.1007/BF00921179

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  • DOI: https://doi.org/10.1007/BF00921179

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