Abstract
Carbanions derived from N-(p-nitrobenzyl)-dihydrosilaazaanthracene condense with acetylenedicarboxylic ester to form substituted silanaphthoindolizines and silaazaaceanthrenes. The analogous salt of the 9-oxo derivative gave the oxo substituted silanaphthoindolizine. The compounds obtained were subjected to reduction, hydrolysis, and opening of the sila-ring.
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Literature Cited
A. V. Varlamov, H. Saksena, and N. S. Prostakov, Reactivity of Azines, Novosibirsk (1979), p. 102.
N. S. Prostakov, N. Saksena, A. V. Varlamov, and A. A. Fomichev, J. Organomet. Chem., 218, 17 (1981).
N. S. Prostakov, A. V. Varlamov, N. Saksena, and A. A. Fomichev, All-Union Conference On the Chemistry and Practical Uses of Organosilicon Compounds (Summary Reports), Vol. 1, Moscow (1980), p. 61.
N. S. Prostakov, A. V. Varlamov, H. Saksena, and A. A. Fomichev, Khim. Geterotsikl. Soedin., No. 1, 123 (1980).
H. J. Timpe and A. V. El'tsov, Advances in Heterocyclic Chemistry, Vol. 33, Academic Press (1983), p. 185.
W. Treibs, J. Hiebsch, and H. J. Neupert, Chem. Ber., 92, 606 (1959).
A. G. Anastassion, E. Reichmanis, and S. I. Girgent, J. Am. Chem. Soc., 99, 7392 (1977).
A. G. Anderson and H. L. Ammon, Tetrahedron, 23, 3601 (1967).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 707–711, May, 1987.
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Prostakov, N.S., Varlamov, A.V., Islam, N. et al. Condensation of N-(p-nitrobenzyl)-10,10-dimethyl-9,10-dihydro-10-sila-2-azaanthracene bromide and its 9-oxo derivative with acetylenedicarboxylic ester. Chem Heterocycl Compd 23, 588–591 (1987). https://doi.org/10.1007/BF00476393
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DOI: https://doi.org/10.1007/BF00476393