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Condensation of N-(p-nitrobenzyl)-10,10-dimethyl-9,10-dihydro-10-sila-2-azaanthracene bromide and its 9-oxo derivative with acetylenedicarboxylic ester

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Carbanions derived from N-(p-nitrobenzyl)-dihydrosilaazaanthracene condense with acetylenedicarboxylic ester to form substituted silanaphthoindolizines and silaazaaceanthrenes. The analogous salt of the 9-oxo derivative gave the oxo substituted silanaphthoindolizine. The compounds obtained were subjected to reduction, hydrolysis, and opening of the sila-ring.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 707–711, May, 1987.

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Prostakov, N.S., Varlamov, A.V., Islam, N. et al. Condensation of N-(p-nitrobenzyl)-10,10-dimethyl-9,10-dihydro-10-sila-2-azaanthracene bromide and its 9-oxo derivative with acetylenedicarboxylic ester. Chem Heterocycl Compd 23, 588–591 (1987). https://doi.org/10.1007/BF00476393

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  • DOI: https://doi.org/10.1007/BF00476393

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