Abstract
The results of low-temperature specific-heat measurements are presented for hydrogen-chemisorbed M (M=K,Rb), to clarify the effects of dissolved hydrogen on its electronic and lattice vibrational properties. The density of states at the Fermi level is suppressed through a charge transfer from M to hydrogen which is stabilized in interstitial sites in the intercalate layers. This finding is consistent with the results of ESR and positron-annihilation measurements. The introduction of hydrogen increases the acoustic and optic phonon energies for (x<0.1). The electronic effects of dissolved hydrogen are considered to be the cause of the increase. At the hydrogen-saturated concentration (), the phonon energies are lowered by an increase in the effective mass of the intercalants due to the strong ionic coupling between K and H through bondings with hydrogen. In the case of the Rb system, the acoustic-phonon energies increase while the optic-phonon ones decrease through the introduction of small concentrations of hydrogen (x<0.1). The effects of dissolved hydrogen on the superconductivity of are discussed using the specific-heat results.
- Received 21 January 1985
DOI:https://doi.org/10.1103/PhysRevB.32.2497
©1985 American Physical Society