The 2023 MDPI Annual Report has
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27 pages, 2549 KiB  
Article
An Assessment of the Impact of the Protection Zone Regime for Cultural Heritage Sites on the Value of Land for Individual Housing Construction in the Context of a Low-Activity Market
by Irina Dyachkova, Elena Bykowa, Vlada Dudina and Tatyana Banikevich
Heritage 2024, 7(6), 2682-2708; https://doi.org/10.3390/heritage7060128 (registering DOI) - 26 May 2024
Abstract
The preservation of cultural heritage plays a key role in the development of society. To preserve cultural heritage, protection zones are established, which represent an encumbrance on land plots and, therefore, should be taken into account in the valuation process. Currently, there is [...] Read more.
The preservation of cultural heritage plays a key role in the development of society. To preserve cultural heritage, protection zones are established, which represent an encumbrance on land plots and, therefore, should be taken into account in the valuation process. Currently, there is a problem that mass (cadastral) and individual valuation methods do not necessarily include cultural heritage objects and their zones in cost coefficients. The absence of a mechanism to address their individual characteristics in the real estate valuation system has a significant impact on the value of real estate and leads to unjustifiably inflated market value and, as a consequence, to disputing the results of cadastral valuation. This article is devoted to determining the impact of protection zones of cultural heritage objects on the value of land intended for individual housing construction, using the example of the city of Orenburg. This article considers various methods of identifying patterns of the influence of zones with special conditions of use of the territory on the market value of land and substantiates the use of the method of comparative sales in the conditions of a low-active land market in Orenburg, a statistical analysis of market information, on the basis of which the type of activity of the real estate market in Orenburg was determined. The patterns of the calculation of corrections for the remoteness of the studied land plots from the objects of the transport and social infrastructure of Orenburg were revealed in this work as well. Through the method of paired sales within the framework of an individual assessment of the land plot intended for individual housing construction, the diminishing impact of the zones of protection of cultural heritage objects on the market value of land plots was revealed. This allows for conclusions to be drawn as to whether objects of cultural heritage have an impact on the value of real estate, and as a result, there is a need to modify the applied methods of mass and individual real estate valuation within the boundaries of historical settlements. Full article
(This article belongs to the Section Cultural Heritage)
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19 pages, 2162 KiB  
Article
Robust Wideband Interference Suppression Method for GNSS Array Antenna Receiver via Hybrid Beamforming Technique
by Zhenxing Xu, Qijia Dong, Shenyang Li, Fuzhan Yue, Meng Wang, Zhenghuan Xia, Xiao Chen, Shuangna Zhang, Guoji Zou and Huizheng Wang
Remote Sens. 2024, 16(11), 1913; https://doi.org/10.3390/rs16111913 (registering DOI) - 26 May 2024
Abstract
Global navigation satellite system (GNSS) array antenna receivers are widely used to suppress wideband interference in navigation countermeasures. However, existing array antenna receivers all adopt a digital array structure and digital beamforming technique, and they have limited analog-front-end (AFE) dynamic range. In strong [...] Read more.
Global navigation satellite system (GNSS) array antenna receivers are widely used to suppress wideband interference in navigation countermeasures. However, existing array antenna receivers all adopt a digital array structure and digital beamforming technique, and they have limited analog-front-end (AFE) dynamic range. In strong interference scenarios, AFE saturation will occur, which limits the maximum interference suppression ability of the array receiver. Aiming at this issue, this paper proposes a robust wideband interference suppression method for GNSS array antenna receivers based on a hybrid beamforming technique. Firstly, a novel, fully connected hybrid array receiver structure is proposed. Secondly, the corresponding hybrid beamforming method is proposed at the same time, and it realizes the complete elimination of the strong wideband interference by joint suppression in the analog domain and digital domain. After mathematical simulations, it is verified that, compared to the digital beamforming-based anti-jamming technique, the proposed method can effectively suppress strong wideband interference, and the maximum interference suppression ability is improved by 36 dB. Full article
(This article belongs to the Special Issue Satellite Navigation and Signal Processing (Second Edition))
13 pages, 2311 KiB  
Article
Influence of Non-Ionic Surfactant and Silver on the Photocatalytic Activity of TiO2 Films for Degradation of Dyes in Distilled and Tap Water
by Dobrina Ivanova, Elisaveta Mladenova and Nina Kaneva
Appl. Sci. 2024, 14(11), 4571; https://doi.org/10.3390/app14114571 (registering DOI) - 26 May 2024
Abstract
This study describes the impact of surfactant molecular weights (PEG 2000 and PEG 4000) on the photocatalytic activity of TiO2 films, deposited via dip-coating from a PEG-stabilized suspension and silver-functionalized photo-fixation of Ag+ under UV illumination. The photocatalytic activity of pure [...] Read more.
This study describes the impact of surfactant molecular weights (PEG 2000 and PEG 4000) on the photocatalytic activity of TiO2 films, deposited via dip-coating from a PEG-stabilized suspension and silver-functionalized photo-fixation of Ag+ under UV illumination. The photocatalytic activity of pure and Ag/TiO2 films is assessed in the aqueous-phase degradation of Malachite green and Methylene blue in distilled and tap water under UV and visible illumination. The results indicate a positive effect of both the higher-molecular-weight non-ionic surfactant and Ag-functionalization yield higher photocatalytic efficiency. Notably, films photo-fixed with 10−2 M Ag+ show the highest degradation percentages in all experimental conditions. A direct correlation between the concentration of Ag+ ions and the enhancement of the photocatalytic activity is revealed: pure TiO2 < Ag, 10−4/TiO2 < Ag, 10−3/TiO2 < Ag, 10−2/TiO2. Flame atomic absorption spectrometry is used to study the Ag+ leeching from the Ag/TiO2 films. The structural properties of the nanostructures are investigated through scanning electron microscopy, Brunauer–Emmett–Teller analysis, energy-dispersive X-ray spectroscopy, and X-ray diffraction. Additionally, after three cycles of operation, Ag, 10−2/TiO2 (PEG 4000) films can maintain their photocatalytic activity, suggesting a potential application in the treatment of dye wastewater. Full article
(This article belongs to the Special Issue Environmental Catalysis and Green Chemistry)
9 pages, 423 KiB  
Review
Work of Breathing: Physiology, Measurement, and Diagnostic Value in Childhood Pneumonia
by Israel Amirav, Aleeza Manucot, Jane Crawley and Sapir Levi
Children 2024, 11(6), 642; https://doi.org/10.3390/children11060642 (registering DOI) - 26 May 2024
Abstract
In clinical practice, increased “work of breathing” (WOB) is used to rapidly identify the acutely ill child in need of immediate clinical care, and is commonly used to support a clinical diagnosis of pneumonia. However, this key clinical sign is poorly understood and [...] Read more.
In clinical practice, increased “work of breathing” (WOB) is used to rapidly identify the acutely ill child in need of immediate clinical care, and is commonly used to support a clinical diagnosis of pneumonia. However, this key clinical sign is poorly understood and inconsistently defined. This review discusses the physiology, measurement, and clinical assessment of WOB, highlighting its utility in the recognition of pneumonia in under-resourced settings, where access to diagnostic imaging may be limited. Full article
17 pages, 1577 KiB  
Article
Analysis of Consumer Preferences for Green Tea Products: A Randomized Conjoint Analysis in Thai Nguyen, Vietnam
by Bui Xuan Hong, Masaru Ichihashi and Nguyen Thi Bich Ngoc
Sustainability 2024, 16(11), 4521; https://doi.org/10.3390/su16114521 (registering DOI) - 26 May 2024
Abstract
How local economies can successfully develop remains an important issue for any developing country. One mechanism for promotion of economic development is government-driven policy. The problem is that it is not clear whether public-led economic promotion attracts consumers and which promotion factors are [...] Read more.
How local economies can successfully develop remains an important issue for any developing country. One mechanism for promotion of economic development is government-driven policy. The problem is that it is not clear whether public-led economic promotion attracts consumers and which promotion factors are relatively significant for boosting particular goods. This paper examines attributes of green tea products likely influencing consumer preferences, focusing on the Thai Nguyen area in Vietnam as an example. In this area, the “One Commune, One Product” (OCOP) project has been implemented by the local government. This study employs randomized conjoint analysis based on data collected from 450 randomly selected consumers in several local supermarkets. Interestingly, the results show that online style sales have a negative preference for the purchase of green tea products, while transparency, such as the traceability of the product and product information, and reliability, such as certification, enhance the purchase of these products by consumers. However, this finding is not necessarily robust because our results indicate that approximately 90% of consumers tend to choose the default pair, which means that they do not actively prefer the product, possibly implying that this kind of public-led promotion is not yet broadly familiar to all people. Full article
13 pages, 1164 KiB  
Article
Clinical Features and Survival Outcome in Aggressive-Type Adult T-Cell Leukemia/Lymphoma Patients: Real-Life Experience of a Single Center from an HTLV-1 Endemic Country
by Iuliana Iordan, Ana-Maria Vlădăreanu, Cristina Mambet, Minodora Onisâi, Diana Cîșleanu and Horia Bumbea
Medicina 2024, 60(6), 872; https://doi.org/10.3390/medicina60060872 (registering DOI) - 26 May 2024
Abstract
Background and Objectives: Adult T-cell leukemia/lymphoma (ATLL) is a highly aggressive T-cell lymphoproliferative disease associated with the human T-cell lymphotropic virus type I (HTLV-1). ATLL is a rare disease, found more frequently in HTLV-1-endemic areas, Romania being one of them. Despite treatment [...] Read more.
Background and Objectives: Adult T-cell leukemia/lymphoma (ATLL) is a highly aggressive T-cell lymphoproliferative disease associated with the human T-cell lymphotropic virus type I (HTLV-1). ATLL is a rare disease, found more frequently in HTLV-1-endemic areas, Romania being one of them. Despite treatment advances, the prognosis remains dismal. We aimed to describe the clinical, biological, and survival outcome features of Romanian patients with aggressive-type ATLL. Materials and Methods: We report the data of a prospective, observational, and unicentric study of all 20 patients diagnosed with lymphoma and acute types of ATLL at our center over the past 12 years. Data were collected from the patients’ medical records. Results: Lymphoma-type ATLL (60%) was more common than acute-type ATLL (40%). Median age at diagnosis was 40.5 years, and most patients were female. Laboratory data revealed significant differences between acute and lymphoma-type ATLL, namely, higher leukocyte (p = 0.02) and lymphocyte counts (p = 0.02) and higher levels of corrected calcium (p = 0.001) in acute-type ATLL. All patients received chemotherapy, and only two underwent allogeneic stem cell transplantation. Only six patients obtained a complete or partial response to chemotherapy, mostly the lymphoma-type ones. The median survival for all patients was 6.37 months, with higher survival in the lymphoma-type ATLL (8.16 months) than in the acute-type (3.60 months). Normal calcium levels (p = 0.011), uric acid (p = 0.005), BUN score (p = 0.000), JCOG-PI moderate risk (p = 0.038), and obtaining complete or partial response (p = 0.037) were associated with higher survival. Conclusion: Aggressive-type ATLL among Romanian patients presents distinct characteristics, including younger age at diagnosis, female predominance, and higher incidence of lymphoma-type ATLL compared to currently reported data. Survival remains very low, with all subtypes experiencing a median survival of less than one year. Full article
(This article belongs to the Section Hematology and Immunology)
10 pages, 9586 KiB  
Communication
Wideband Terminal Antenna System Based on Babinet’s Principle for Sub-6 GHz and Wi-Fi 6E/7 Applications
by Chong-Zhi Han, Guji Gong, Yan Wang, Jie Guo and Liang Zhang
Micromachines 2024, 15(6), 705; https://doi.org/10.3390/mi15060705 (registering DOI) - 26 May 2024
Abstract
In this paper, a novel input impedance analysis methodology based on Babinet’s principle to broaden bandwidth is proposed, and a broadband multiple-input and multiple-output (MIMO) antenna system is designed, fabricated, and measured for fifth-generation (5G) and Wireless Fidelity (Wi-Fi) 6E/7 mobile applications. By [...] Read more.
In this paper, a novel input impedance analysis methodology based on Babinet’s principle to broaden bandwidth is proposed, and a broadband multiple-input and multiple-output (MIMO) antenna system is designed, fabricated, and measured for fifth-generation (5G) and Wireless Fidelity (Wi-Fi) 6E/7 mobile applications. By analyzing the input impedance of open-slot antennas and planar monopole antennas using numerical calculations, the characteristics of the input impedance can be obtained. We find that combining the two antenna types in parallel can significantly enhance the bandwidth. Then, the four-dimensional image calculated by MATLAB based on the parallel impedance formula is processed to validate the methodology. Thus, a broad antenna element based on the impedance property analysis methodology is achieved, which operates ranging from 2.6 GHz to 7.46 GHz. Moreover, the equivalent circuit of the antenna element is established to further verify the validity of the methodology. Finally, a broadband MIMO antenna system consisting of eight antenna elements is designed, fabricated, and measured, and the isolation performance is better than 12 dB. Acceptable total efficiency higher than 45% is also obtained with envelope correlation coefficients (ECCs) lower than 0.05. The proposed impedance property analysis methodology innovatively proposes a new way to increase bandwidth, which can be widely applied in various antenna designs. Also, reasonable results show that the proposed MIMO antenna system is a good candidate for 5G and Wi-Fi 6E/7 mobile applications. Full article
21 pages, 1027 KiB  
Article
Study of Methane Solubility Calculation Based on Modified Henry’s Law and BP Neural Network
by Ying Zhao, Jiahao Yu, Hailei Shi, Junyao Guo, Daqian Liu, Ju Lin, Shangfei Song, Haihao Wu and Jing Gong
Processes 2024, 12(6), 1091; https://doi.org/10.3390/pr12061091 (registering DOI) - 26 May 2024
Abstract
Methane (CH4), a non-polar molecule characterized by a tetrahedral structure, stands as the simplest organic compound. Predominantly constituting conventional natural gas, shale gas, and combustible ice, it plays a pivotal role as a carbon-based resource and a key raw material in [...] Read more.
Methane (CH4), a non-polar molecule characterized by a tetrahedral structure, stands as the simplest organic compound. Predominantly constituting conventional natural gas, shale gas, and combustible ice, it plays a pivotal role as a carbon-based resource and a key raw material in the petrochemical industry. In natural formations, CH4 and H2O coexist in a synergistic system. This interplay necessitates a thorough examination of the phase equilibrium in the CH4-H2O system and CH4’s solubility under extreme conditions of temperature and pressure, which is crucial for understanding the genesis and development of gas reservoirs. This study synthesizes a comprehensive solubility database by aggregating extensive solubility data of CH4 in both pure and saline water. Utilizing this database, the study updates and refines the key parameters of Henry’s law. The updated Henry’s law has a prediction error of 22.86% at less than 40 MPa, which is an improvement in prediction accuracy compared to before the update. However, the modified Henry’s law suffers from poor calculation accuracy under certain pressure conditions. To further improve the accuracy of solubility prediction, this work also trains a BP (Back Propagation) neural network model based on the database. In addition, MSE (Mean-Square Error) is used as the model evaluation index, and pressure, temperature, compression coefficient, salinity, and fugacity are preferred as input variables, which finally reduces the mean relative error of the model to 16.32%, and the calculation results are more accurate than the modified Henry’s law. In conclusion, this study provides a novel and more accurate method for predicting CH4 solubility by comparing modified Henry’s law to neural network modeling. Full article
(This article belongs to the Section Energy Systems)
14 pages, 4453 KiB  
Article
Effects of Raman Labeling Compounds on the Stability and Surface-Enhanced Raman Spectroscopy Performance of Ag Nanoparticle-Embedded Silica Nanoparticles as Tagging Materials
by Cho-Hee Yang, Hye-Seong Cho, Yoon-Hee Kim, Kwanghee Yoo, Jaehong Lim, Eunil Hahm, Won Yeop Rho, Young Jun Kim and Bong-Hyun Jun
Biosensors 2024, 14(6), 272; https://doi.org/10.3390/bios14060272 (registering DOI) - 26 May 2024
Abstract
Surface-enhanced Raman spectroscopy (SERS) tagging using silica(SiO2)@Ag nanoparticles (NPs) is easy to handle and is being studied in various fields, including SERS imaging and immunoassays. This is primarily due to its structural advantages, characterized by high SERS activity. However, the Ag [...] Read more.
Surface-enhanced Raman spectroscopy (SERS) tagging using silica(SiO2)@Ag nanoparticles (NPs) is easy to handle and is being studied in various fields, including SERS imaging and immunoassays. This is primarily due to its structural advantages, characterized by high SERS activity. However, the Ag NPs introduced onto the SiO2 surface may undergo structural transformation owing to the Ostwald ripening phenomenon under various conditions. As a result, the consistency of the SERS signal decreases, reducing their usability as SERS substrates. Until recently, research has been actively conducted to improve the stability of single Ag NPs. However, research on SiO2@Ag NPs used as a SERS-tagging material is still lacking. In this study, we utilized a Raman labeling compound (RLC) to prevent the structural deformation of SiO2@Ag NPs under various conditions and proposed excellent SiO2@Ag@RLC-Pre NPs as a SERS-tagging material. Using various RLCs, we confirmed that 4-mercaptobenzoic acid (4-MBA) is the RLC that maintains the highest stability for 2 months. These results were also observed for the SiO2@Ag NPs, which were unstable under various pH and temperature conditions. We believe that SERS tags using SiO2@Ag NPs and 4-MBA can be utilized in various applications on based SERS because of the high stability and consistency of the resulting SERS signal. Full article
(This article belongs to the Special Issue Nanoparticle-Based Biosensors and Their Applications)
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14 pages, 286 KiB  
Systematic Review
A Systematic Review of Congenital Insensitivity to Pain, a Rare Disease
by Raquel Rodríguez-Blanque, Laura Maria Nielsen, Beatriz Piqueras-Sola, Juan Carlos Sánchez-García, Celia Cortés-Martín, Andrés Reinoso-Cobo and Jonathan Cortés-Martín
J. Pers. Med. 2024, 14(6), 570; https://doi.org/10.3390/jpm14060570 (registering DOI) - 26 May 2024
Abstract
Introduction: Pain perception, far from being a pathological mechanism, is a crucial protective stimulus to prevent additional injuries. Any disturbance in this complex system poses significant risks to individuals, affecting their quality of life and even their survival. Objective: This review aims to [...] Read more.
Introduction: Pain perception, far from being a pathological mechanism, is a crucial protective stimulus to prevent additional injuries. Any disturbance in this complex system poses significant risks to individuals, affecting their quality of life and even their survival. Objective: This review aims to explore congenital insensitivity to pain, an extremely rare genetic disorder with an autosomal recessive pattern that results in the inability to perceive pain. We will focus on the well-known subtype, congenital insensitivity to pain with anhidrosis (CIPA). Our research seeks to update existing knowledge through a comprehensive literature review. Methodology: The review employs a systematic literature review, analyzing various sources and scientific documents, primarily emphasizing CIPA. The review follows the PROSPERO protocol, registered under CRD42023394489. The literature search was performed on the Scopus, PubMed, and Cinahl databases. Results: Our review reveals secondary complications associated with CIPA, such as recurrent bone fractures, temperature insensitivity, self-mutilation, and, occasionally, intellectual disabilities. The limited available information underscores the need for expanding our knowledge. Conclusions: In summary, CIPA, particularly, presents a significant medical challenge with adverse impacts on quality of life. Early diagnosis, education for families and healthcare professionals, and appropriate nursing care are essential for effective management. This review highlights the necessity of further research and awareness to enhance support for those affected. Full article
(This article belongs to the Section Mechanisms of Diseases)
22 pages, 4857 KiB  
Article
Distinct Effects of Respiratory Viral Infection Models on miR-149-5p, IL-6 and p63 Expression in BEAS-2B and A549 Epithelial Cells
by Nafeesa Shahdab, Christopher Ward, Philip M. Hansbro, Stephen Cummings, John S. Young and Fatemeh Moheimani
Cells 2024, 13(11), 919; https://doi.org/10.3390/cells13110919 (registering DOI) - 26 May 2024
Abstract
Respiratory viruses cause airway inflammation, resulting in epithelial injury and repair. miRNAs, including miR-149-5p, regulate different pathological conditions. We aimed to determine how miR-149-5p functions in regulating pro-inflammatory IL-6 and p63, key regulators of airway epithelial wound repair, in response to viral proteins [...] Read more.
Respiratory viruses cause airway inflammation, resulting in epithelial injury and repair. miRNAs, including miR-149-5p, regulate different pathological conditions. We aimed to determine how miR-149-5p functions in regulating pro-inflammatory IL-6 and p63, key regulators of airway epithelial wound repair, in response to viral proteins in bronchial (BEAS-2B) and alveolar (A549) epithelial cells. BEAS-2B or A549 cells were incubated with poly (I:C, 0.5 µg/mL) for 48 h or SARS-CoV-2 spike protein-1 or 2 subunit (S1 or S2, 1 μg/mL) for 24 h. miR-149-5p was suppressed in BEAS-2B challenged with poly (I:C), correlating with IL-6 and p63 upregulation. miR-149-5p was down-regulated in A549 stimulated with poly (I:C); IL-6 expression increased, but p63 protein levels were undetectable. miR-149-5p remained unchanged in cells exposed to S1 or S2, while S1 transfection increased IL-6 expression in BEAS-2B cells. Ectopic over-expression of miR-149-5p in BEAS-2B cells suppressed IL-6 and p63 mRNA levels and inhibited poly (I:C)-induced IL-6 and p63 mRNA expressions. miR-149-5p directly suppressed IL-6 mRNA in BEAS-2B cells. Hence, BEAS-2B cells respond differently to poly (I:C), S1 or S2 compared to A549 cells. Thus, miR-149-5p dysregulation may be involved in poly (I:C)-stimulated but not S1- or S2-stimulated increased IL-6 production and p63 expression in BEAS-2B cells. Full article
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14 pages, 2938 KiB  
Article
The Designed Phase Mask for Suppressing the Inter-Pixel Crosstalk Noise in Intensity-Modulated Multilevel Holographic Data Storage Systems
by Takuya Nonaka, Soki Hirayama, Tsutomu Shimura and Ryushi Fujimura
Photonics 2024, 11(6), 507; https://doi.org/10.3390/photonics11060507 (registering DOI) - 26 May 2024
Abstract
Intensity-modulated signals have the advantage of being directly detectable by the image sensor but have the drawback that the signal quality is easily deteriorated by crosstalk noise, in contrast to phase-modulated signals. In order to suppress the crosstalk noise, we propose a new [...] Read more.
Intensity-modulated signals have the advantage of being directly detectable by the image sensor but have the drawback that the signal quality is easily deteriorated by crosstalk noise, in contrast to phase-modulated signals. In order to suppress the crosstalk noise, we propose a new signal arrangement for multilevel intensity-modulated signals. The concept of our method is to reduce the number of adjacent pixels that are a source of inter-pixel crosstalk noise and to minimize intensity modulation owing to interference with crosstalk noise. We have numerically and experimentally demonstrated that our method can reduce the error rate and improve the recording density compared to the conventional signal arrangement. Our proposed method offers a promising solution for achieving higher recording densities in intensity-modulated holographic data storage systems. Full article
(This article belongs to the Special Issue Holographic Information Processing)
27 pages, 1183 KiB  
Article
Development and Validation of the Readiness to Change Scale (RtC) for Sustainability
by Mirko Duradoni, Giulia Valdrighi, Alessia Donati, Maria Fiorenza, Luisa Puddu and Andrea Guazzini
Sustainability 2024, 16(11), 4519; https://doi.org/10.3390/su16114519 (registering DOI) - 26 May 2024
Abstract
The climate emergency is increasingly looming, and its consequences on nature and human systems are increasingly severe and pervasive, as reported by the world’s leading conferences and organizations on the subject. There appears to be an immediate need to adopt more sustainable behaviors [...] Read more.
The climate emergency is increasingly looming, and its consequences on nature and human systems are increasingly severe and pervasive, as reported by the world’s leading conferences and organizations on the subject. There appears to be an immediate need to adopt more sustainable behaviors in order to stem consequences that are becoming increasingly dramatic. In this regard, environmental psychology and other related disciplines have sought and still seek to understand how to translate the environmental concerns of individuals and communities into effective and efficient conservation and protection actions to contain the emergency and avoid further consequences. The contribution of psychological theories, particularly the transtheoretical model of change and the planned behavior model, appears very promising for assessing and promoting the potential for activation toward sustainability. The aim of this study was to develop a new conceptualization of the psychological construct of readiness to change (RtC) applied to sustainability issues and validated internally and externally through two separate studies (N1 = 228, N2 = 713). The sample for the two studies was recruited by distributing an anonymous online survey. For Study 1, we administered an online survey investigating basic sociodemographic characteristics and the preliminary set of 42 items of the readiness to change scale. For Study 2, the survey was composed of the following tools: a sociodemographic form, the readiness to change scale, a connectedness to nature scale, a climate change attitude survey, consumers’ perceived readiness toward green products, and a pro-environmental behaviors scale. Through exploratory factor analysis and confirmatory factor analysis, 29 items were selected from an initial set of 42. The 29 items were divided and organized into seven factors (namely: perceived importance of the problem/change, motivation, self-efficacy, effectiveness of the proposed solution, social support, action and involvement, and perceived readiness). Each factor showed adequate reliability (McDonald’s ω range: 0.74–0.87). Regarding external validity, the scale showed correlations—with typical to large effect sizes—with pro-environmental identity, green attitudes, sustainable intentions, and pro-environmental behaviors (PEBs) (i.e., conservation, environmental citizenship, food, transportation). Given the results obtained, we can say that the scale we constructed can infer the individual’s propensity to enact PEBs, and consequently it can give input to the implementation of interventions aimed at stimulating RtC and, therefore, sustainable behaviors. In conclusion, the scale appears valid and usable for assessing the activation potential of both individuals but also at the group and community levels—the latter factor being an important contribution to scientific research, since most of the instruments used to date fail to estimate this aspect. Full article
22 pages, 987 KiB  
Review
Dietary Patterns, Gut Microbiota and Sports Performance in Athletes: A Narrative Review
by Yonglin Chen, Keer Yang, Mingxin Xu, Yishuo Zhang, Xiquan Weng, Jiaji Luo, Yanshuo Li and Yu-Heng Mao
Nutrients 2024, 16(11), 1634; https://doi.org/10.3390/nu16111634 (registering DOI) - 26 May 2024
Abstract
The intestinal tract of humans harbors a dynamic and complex bacterial community known as the gut microbiota, which plays a crucial role in regulating functions such as metabolism and immunity in the human body. Numerous studies conducted in recent decades have also highlighted [...] Read more.
The intestinal tract of humans harbors a dynamic and complex bacterial community known as the gut microbiota, which plays a crucial role in regulating functions such as metabolism and immunity in the human body. Numerous studies conducted in recent decades have also highlighted the significant potential of the gut microbiota in promoting human health. It is widely recognized that training and nutrition strategies are pivotal factors that allow athletes to achieve optimal performance. Consequently, there has been an increasing focus on whether training and dietary patterns influence sports performance through their impact on the gut microbiota. In this review, we aim to present the concept and primary functions of the gut microbiota, explore the relationship between exercise and the gut microbiota, and specifically examine the popular dietary patterns associated with athletes’ sports performance while considering their interaction with the gut microbiota. Finally, we discuss the potential mechanisms by which dietary patterns affect sports performance from a nutritional perspective, aiming to elucidate the intricate interplay among dietary patterns, the gut microbiota, and sports performance. We have found that the precise application of specific dietary patterns (ketogenic diet, plant-based diet, high-protein diet, Mediterranean diet, and high intake of carbohydrate) can improve vascular function and reduce the risk of illness in health promotion, etc., as well as promoting recovery and controlling weight with regard to improving sports performance, etc. In conclusion, although it can be inferred that certain aspects of an athlete’s ability may benefit from specific dietary patterns mediated by the gut microbiota to some extent, further high-quality clinical studies are warranted to substantiate these claims and elucidate the underlying mechanisms. Full article
(This article belongs to the Special Issue Dietary Habit, Gut Microbiome and Human Health)
15 pages, 4316 KiB  
Article
Simulation of Orbital Fractures Using Experimental and Mathematical Approaches: A Pilot Study
by Patrik Eiba, Karel Frydrysek, Behrad Zanganeh, Daniel Cepica, Pavel Marsalek, Petr Handlos, Juraj Timkovic, Jan Stembirek, Jakub Cienciala, Arnost Onderka, Michal Brezik and Ondrej Mizera
J. Funct. Biomater. 2024, 15(6), 143; https://doi.org/10.3390/jfb15060143 (registering DOI) - 26 May 2024
Abstract
This contribution gives basic information about the mechanical behavior of the facial part of the human skull cranium, i.e., the splanchnocranium, associated with external loads and injuries caused mainly by brachial violence. The main areas suffering from such violence include the orbit, frontal, [...] Read more.
This contribution gives basic information about the mechanical behavior of the facial part of the human skull cranium, i.e., the splanchnocranium, associated with external loads and injuries caused mainly by brachial violence. The main areas suffering from such violence include the orbit, frontal, and zygomatic bones. In this paper, as a first approach, brachial violence was simulated via quasi-static compression laboratory tests, in which cadaveric skulls were subjected to a load in a testing machine, increasing till fractures occurred. The test skulls were also used for research into the dynamic behavior, in which experimental and numerical analyses were performed. A relatively high variability in forces inducing the fractures has been observed (143–1403 N). The results lay the basis for applications mainly in forensic science, surgery, and ophthalmology. Full article
20 pages, 543 KiB  
Article
Green Business Model and Green Media Coverage for a Successful Initial Public Offering: Evidence from the Korean Firms
by Jungha Kim, Kyung Ryang Ko and Wonyong Choi
Sustainability 2024, 16(11), 4520; https://doi.org/10.3390/su16114520 (registering DOI) - 26 May 2024
Abstract
With mounting concerns about sustainability, significant attention has been directed toward research within the green industry domain. However, existing literature on initial public offerings (IPOs) has overlooked a crucial distinction: investors do not perceive all firms operating in green industries equally. Firms with [...] Read more.
With mounting concerns about sustainability, significant attention has been directed toward research within the green industry domain. However, existing literature on initial public offerings (IPOs) has overlooked a crucial distinction: investors do not perceive all firms operating in green industries equally. Firms with green business models (GBMs) are more attractive to investors by providing positive signals of future growth potential and sustainability. To reveal this, the study investigates the relationship between GBMs and IPO success by Ordinary Least Squares (OLS) regression analysis. As the Asia-Pacific IPO market accounts for about 60% of IPO volume and value, with Korea actively participating in this global surge, the study used a sample of 150 firms that underwent IPOs between 2016 and 2019 on the Korea Securities Dealers Automated Quotations (KOSDAQ) market. We find evidence that firms with GBMs are more likely to achieve successful IPO outcomes, and GMC also plays a positive moderating role, enhancing the positive link between GBMs and IPO success. However, GMC alone had no significant effect. These findings imply that green signals positively contribute to a successful IPO and that each green signal can have different signaling effects, ultimately contributing to the field of sustainability through signaling theory. Full article
(This article belongs to the Special Issue Digital Transformation and Innovation for a Sustainable Future)
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30 pages, 10649 KiB  
Article
An In Silico Analysis of Genetic Variants and Structural Modeling of the Human Frataxin Protein in Friedreich’s Ataxia
by Loiane Mendonça Abrantes Da Conceição, Lucio Mendes Cabral, Gabriel Rodrigues Coutinho Pereira and Joelma Freire De Mesquita
Int. J. Mol. Sci. 2024, 25(11), 5796; https://doi.org/10.3390/ijms25115796 (registering DOI) - 26 May 2024
Abstract
Friedreich’s Ataxia (FRDA) stands out as the most prevalent form of hereditary ataxias, marked by progressive movement ataxia, loss of vibratory sensitivity, and skeletal deformities, severely affecting daily functioning. To date, the only medication available for treating FRDA is Omaveloxolone (Skyclarys®), [...] Read more.
Friedreich’s Ataxia (FRDA) stands out as the most prevalent form of hereditary ataxias, marked by progressive movement ataxia, loss of vibratory sensitivity, and skeletal deformities, severely affecting daily functioning. To date, the only medication available for treating FRDA is Omaveloxolone (Skyclarys®), recently approved by the FDA. Missense mutations within the human frataxin (FXN) gene, responsible for intracellular iron homeostasis regulation, are linked to FRDA development. These mutations induce FXN dysfunction, fostering mitochondrial iron accumulation and heightened oxidative stress, ultimately triggering neuronal cell death pathways. This study amalgamated 226 FXN genetic variants from the literature and database searches, with only 18 previously characterized. Predictive analyses revealed a notable prevalence of detrimental and destabilizing predictions for FXN mutations, predominantly impacting conserved residues crucial for protein function. Additionally, an accurate, comprehensive three-dimensional model of human FXN was constructed, serving as the basis for generating genetic variants I154F and W155R. These variants, selected for their severe clinical implications, underwent molecular dynamics (MD) simulations, unveiling flexibility and essential dynamic alterations in their N-terminal segments, encompassing FXN42, FXN56, and FXN78 domains pivotal for protein maturation. Thus, our findings indicate potential interaction profile disturbances in the FXN42, FXN56, and FXN78 domains induced by I154F and W155R mutations, aligning with the existing literature. Full article
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18 pages, 6756 KiB  
Article
Exploring the Differences in Tree Species Classification between Typical Forest Regions in Northern and Southern China
by Jia Zhang, Hao Li, Jia Wang, Yuying Liang, Rui Li and Xiaoting Sun
Forests 2024, 15(6), 929; https://doi.org/10.3390/f15060929 (registering DOI) - 26 May 2024
Abstract
Focusing on the trend of continuously seeking high-precision tree species classification results in small areas from the perspectives of sensors and classification algorithms. This study aimed to explore the effects of data sources, classifiers, and seasons on classification accuracy in regions with significant [...] Read more.
Focusing on the trend of continuously seeking high-precision tree species classification results in small areas from the perspectives of sensors and classification algorithms. This study aimed to explore the effects of data sources, classifiers, and seasons on classification accuracy in regions with significant environmental variation, examining patterns of tree species classification to enhance the transferability of classification. Considering two typical forest distribution regions in the north and south of China, this study utilized the revisitation cycle and open-source advantages of Sentinel-2 and Landsat-8. Leveraging the Google Earth Engine (GEE) platform, this study captured spectral features, vegetation indices, and texture features for single seasonal and seasonal combination images. With the assistance of Sentinel-1A and SRTM (Shuttle Radar Topography Mission) DEM (Digital Elevation Model), backscattering coefficient features and topographical features were extracted and input with features captured from Sentinel-2 and Landsat-8 into three types of classifiers: random forest (RF), support vector machine (SVM), and gradient tree boosting (GTB) for major tree species classification. In this research, we discovered that the best classification for single season in the northern study area was spring, whereas, for the southern study area, it was winter. Seasonal combination images effectively improved the classification accuracy of single seasonal images, with Sentinel-2 imagery displaying better classification performance compared to Landsat-8, and the optimal classifier differing between the north and the south. The inclusion of topographical or backscattering coefficient features in the four-season combination imagery contributed to improvements in classification accuracy, with topographical features significantly enhancing the classification performance in the topographically varied southern study area. The evaluation of feature importance indicated that elevation was the most critical feature for classification, while spectral features and vegetation indices were also significant. In the southern study area with large topographical discrepancies, subdividing into different terrain units led to improved tree species classification accuracy in medium-altitude, gentle slope areas. These findings provide insights into the regularity of enhancing tree species classification accuracy in environmentally diverse areas through the use of multi-source remote sensing data and multi-seasonal imagery. Consequently, the results offer a reference for the identification of tree species across large areas and the creation of spatial distribution maps. Full article
34 pages, 5617 KiB  
Review
Trends in Hybrid Renewable Energy System (HRES) Applications: A Review
by Daniel Alejandro Pérez Uc, Susana Estefany de León Aldaco and Jesús Aguayo Alquicira
Energies 2024, 17(11), 2578; https://doi.org/10.3390/en17112578 (registering DOI) - 26 May 2024
Abstract
Microgrids and hybrid renewable energy systems play a crucial role in today’s energy transition. They enable local power generation and distribution, reducing dependence on large centralized infrastructures, can operate independently or connected to a grid, and can provide backup power, thus increasing system [...] Read more.
Microgrids and hybrid renewable energy systems play a crucial role in today’s energy transition. They enable local power generation and distribution, reducing dependence on large centralized infrastructures, can operate independently or connected to a grid, and can provide backup power, thus increasing system resilience. In addition, they combine multiple renewable energy sources, such as solar, wind, hydro, and biomass, to maximize the efficiency and reliability of the supply, and are also adaptable to location-specific conditions, taking advantage of locally available energy resources and reducing the need for energy imports. Moreover, they contribute to decarbonization goals by offering a cleaner and more sustainable alternative. In this article, a documentary review is presented on the interaction of Homer Pro software 3.16.2 (July 2023), used for the design of hybrid renewable energy systems (HRES), with other methods of optimization or sizing. Allusion is made to the type of architecture in the most prominent clean and fossil source configurations, the levelized cost, net annual cost, and maintenance and capital investment cost. A comparison is made among the works reported in the last five years regarding the use of this software tool, based on load demand, geographical area, renewable energy sources, fossil sources, and objective functions, applied to the educational, rural, and industrial sectors. It is shown that India is one of the countries that has reported the most number of HRES techno-economic environmental analysis works, and that the case studies have focused approximately 47% on rural areas, 20% on educational agencies, 14% on commerce and industry, and 29% on urban buildings. Full article
(This article belongs to the Special Issue Energy Consumption in the EU Countries: 3rd Edition)
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20 pages, 2156 KiB  
Article
Valorization of Cherry By-Products as Coagulant/Flocculants Combined with Bentonite Clay for Olive Mill Wastewater Treatment
by Ana R. Teixeira, Sílvia Afonso, Nuno Jorge, Ivo V. Oliveira, Berta Gonçalves, José A. Peres and Marco S. Lucas
Water 2024, 16(11), 1530; https://doi.org/10.3390/w16111530 (registering DOI) - 26 May 2024
Abstract
In this study, two by-products resulting from the processing of cherry (stems and pits) were used as natural coagulants to promote the valorization of these wastes and treat olive mill wastewater (OMW). The efficacy of the plant-based coagulants (PBCs) in the coagulation–flocculation–decantation process [...] Read more.
In this study, two by-products resulting from the processing of cherry (stems and pits) were used as natural coagulants to promote the valorization of these wastes and treat olive mill wastewater (OMW). The efficacy of the plant-based coagulants (PBCs) in the coagulation–flocculation–decantation process (CFD) was evaluated through the removal of turbidity, total suspended solids (TSS), total polyphenols (TPh), and dissolved organic carbon (DOC). The CFD process was demonstrated to be effective in turbidity and TSS reduction in OMW. Using cherry stems (CSs), these reductions were 65.2% of turbidity and 58.0% of TSS, while cherry pits (CPs) achieved higher reductions, 78.6% of turbidity and 68.2% of TSS. To improve the effectiveness of OMW treatment, mainly regarding the removal of TPh and DOC, the CFD process was complemented with the adsorption process (using bentonite clay). The adsorption capacity of bentonite was higher in acidic conditions (pH 3.0) and, with a dosage of 3.0 g L−1, reached 17.3 mg of DOC and 13.8 mg of TPh per gram of bentonite. Several adsorption isothermal models were assessed, and the Langmuir (r2 = 0.985), SIPS (r2 = 0.992), and Jovanovic models (r2 = 0.994) provided the best fittings. According to the optimal operational conditions defined throughout the present work, the combination of CFD and adsorption removals were as follows: (1) 98.0 and 91.3% of turbidity, (2) 80.8 and 81.2% of TSS, (3) 98.1 and 97.6% of TPh and (4) 57.9 and 62.2% of DOC, for CSs and CPs, correspondingly. Overall, the results suggest that cherry by-products can be used as low-cost natural coagulants and, when combined with another natural, abundant, and cheap material, such as bentonite clay, can be a sustainable alternative for treating OMW. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
18 pages, 976 KiB  
Article
Optimization of Chitosan Synthesis Process Parameters to Enhance PES/Chitosan Membrane Performance for the Treatment of Acid Mine Drainage (AMD)
by Ndiwanga F. Rasifudi, Lukhanyo Mekuto and Machodi J. Mathaba
Materials 2024, 17(11), 2562; https://doi.org/10.3390/ma17112562 (registering DOI) - 26 May 2024
Abstract
Acid mine drainage (AMD) is an environmental issue linked with mining activities, causing the release of toxic water from mining areas. Polyethersulphone (PES) membranes are explored for AMD treatment, but their limited hydrophilicity hinders their performance. Chitosan enhances hydrophilicity, addressing this issue. However, [...] Read more.
Acid mine drainage (AMD) is an environmental issue linked with mining activities, causing the release of toxic water from mining areas. Polyethersulphone (PES) membranes are explored for AMD treatment, but their limited hydrophilicity hinders their performance. Chitosan enhances hydrophilicity, addressing this issue. However, the effectiveness depends on chitosan’s degree of deacetylation (DD), determined during the deacetylation process for chitosan production. This study optimized the chitin deacetylation temperature, alkaline (NaOH) concentration, and reaction time, yielding the highest chitosan degree of deacetylation (DD) for PES/chitosan membrane applications. Prior research has shown that high DD chitosan enhances membrane antifouling and hydrophilicity, increasing contaminant rejection and permeate flux. Evaluation of the best deacetylation conditions in terms of temperature (80, 100, 120 °C), NaOH concentration (20, 40, 60 wt.%), and time (2, 4, 6 h) was performed. The highest chitosan DD obtained was 87.11% at 80 °C, 40 wt. %NaOH at 4 h of chitin deacetylation. The PES/0.75 chitosan membrane (87.11%DD) showed an increase in surface hydrophilicity (63.62° contact angle) as compared to the pristine PES membrane (72.83° contact angle). This was an indicated improvement in membrane performance. Thus, presumably leading to high contaminant rejection and permeate flux in the AMD treatment context, postulate to literature. Full article
21 pages, 11715 KiB  
Article
Tolerance Mitigates Gall Effects When Susceptible Plants Fail to Elicit Induced Defense
by Janete Ferreira Andrade, Eduardo Soares Calixto, Guilherme Ramos Demetrio, Henrique Venâncio, Marcos Vinicius Meiado, Denise Garcia de Santana, Pablo Cuevas-Reyes, Wanessa Rejane de Almeida and Jean Carlos Santos
Plants 2024, 13(11), 1472; https://doi.org/10.3390/plants13111472 (registering DOI) - 26 May 2024
Abstract
Variations in plant genotypes and phenotypes are expressed in ways that lead to the development of defensive abilities against herbivory. Induced defenses are mechanisms that affect herbivore insect preferences and performance. We evaluated the performance of resistant and susceptible phenotypes of Bauhinia brevipes [...] Read more.
Variations in plant genotypes and phenotypes are expressed in ways that lead to the development of defensive abilities against herbivory. Induced defenses are mechanisms that affect herbivore insect preferences and performance. We evaluated the performance of resistant and susceptible phenotypes of Bauhinia brevipes (Fabaceae) against attacks by the gall-inducing insect Schizomyia macrocapillata (Diptera). We hypothesized that there is a positive relationship between resistance to S. macrocapillata and host plant performance because resistance can have a high adaptive value. We evaluated plant architecture, nutritional leaf quality, leaf fluctuating asymmetry, and reproductive capacity between phenotypes. Plant performance was evaluated at three ontogenetic stages: seed, seedling, and juvenile. Overall, there were no differences in vegetative and reproductive performance or asymmetry between the resistant and susceptible mature plants. We found no relationship between leaf nutritional quality and resistance to S. macrocapillata. Plant performance was consistent across ontogeny for both phenotypes, except for five variables. Contrary to our expectations, the susceptible plants performed equally well or better than the resistant plants, suggesting that tolerance and overcompensation to herbivory in B. brevipes may be mediated by induced defense. Our study highlights the importance of multiple layers of plant defense against herbivory, where plant tolerance acts as a secondary barrier in plants susceptible to gall-inducing insects. Full article
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12 pages, 1134 KiB  
Article
Green Innovation Practices: A Case Study in a Foundry
by Gianluca Fratta, Ivan Stefani, Sara Tapola and Stefano Saetta
J. Manuf. Mater. Process. 2024, 8(3), 111; https://doi.org/10.3390/jmmp8030111 (registering DOI) - 26 May 2024
Abstract
The foundry industry is responsible for the production of several potentially polluting and hazardous compounds. One of the major sources of pollution is the use of organic binders for the manufacturing of sand cores and sand moulds. To address this problem, in recent [...] Read more.
The foundry industry is responsible for the production of several potentially polluting and hazardous compounds. One of the major sources of pollution is the use of organic binders for the manufacturing of sand cores and sand moulds. To address this problem, in recent years, the use of low-emission products, known as inorganic binders, has been proposed. Their use in ferrous foundries, otherwise, is limited due to some problematic features that complicate their introduction in the manufacturing process, as often happens when a breakthrough innovation is introduced. In light of this, the aim of this work is to provide a Green Innovation Practice (GIP) to manage the introduction of green breakthrough innovations, as previously described, within an existing productive context. This practice was applied to better manage the experimental phase of the Green Casting Life Project, which aims to evaluate the possibility of using inorganic binders for the production of ferrous castings. After describing the state of the art of GIPs and their application in manufacturing contexts, the paper described the proposed GIP and its application to a real case consisting of testing inorganic binders in a ferrous foundry. Full article
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