The 2023 MDPI Annual Report has
been released!
 
19 pages, 9475 KiB  
Article
Performance Analysis of Vermiculite–Potassium Carbonate Composite Materials for Efficient Thermochemical Energy Storage
by Jianquan Lin, Qian Zhao and Haotian Huang
Energies 2024, 17(12), 2847; https://doi.org/10.3390/en17122847 (registering DOI) - 9 Jun 2024
Abstract
In this study, the preparation of the composite material consisting of expanded vermiculite (EV) and potassium carbonate (K2CO3) was conducted using a solution impregnation method. Sorption and desorption experiments were undertaken to investigate the dynamic and thermodynamic properties of [...] Read more.
In this study, the preparation of the composite material consisting of expanded vermiculite (EV) and potassium carbonate (K2CO3) was conducted using a solution impregnation method. Sorption and desorption experiments were undertaken to investigate the dynamic and thermodynamic properties of the EV/K2CO3 composites with varying salt contents. The findings suggest that the EV/K2CO3 composites effectively address the issues of solution leakage resulting from the deliquescence and excessive hydration of pure K2CO3 salt, thereby substantially improving the water sorption capacity and overall stability of the composite materials. The salt content plays a vital role in the sorption and desorption processes of EV/K2CO3 composites. As the salt content rises, the resistance to sorption mass transfer increases, resulting in a decline in the average sorption rate. Concurrently, as the salt content increases, there is a corresponding increase in the average desorption rate, water uptake, and heat storage density. Specifically, at a temperature of 30 °C and a relative humidity of 60%, the EVPC40 composite with a salt content of 67.4% demonstrates water uptake, mass energy density, and volumetric energy density values of 0.68 g/g, 1633.6 kJ/kg, and 160 kWh/m3, respectively. In comparison to pure K2CO3 salt, the utilization of EV/K2CO3 composites under identical heat demand conditions results in a 57% reduction in the required reaction material. This study offers essential empirical evidence and theoretical backing for the utilization and development of EV/K2CO3 composites within thermochemical energy storage systems. Full article
(This article belongs to the Topic Thermal Energy Transfer and Storage)
17 pages, 560 KiB  
Article
The Usefulness of Cleaner Production Projects as an Element of the Initial Assessment of the Circularity of SMEs in the Context of Obtaining Funds Supporting the Implementation of the Circular Economy
by Anna Stasiuk-Piekarska, Małgorzata Hordyńska and Monika Michalska
Sustainability 2024, 16(12), 4951; https://doi.org/10.3390/su16124951 (registering DOI) - 9 Jun 2024
Abstract
The authors of the article decided to verify the requirements for companies looking for sources of financing for projects that will enable them to transform the circular economy. Clarifying the requirements will allow companies to initially verify their ideas. For this purpose, an [...] Read more.
The authors of the article decided to verify the requirements for companies looking for sources of financing for projects that will enable them to transform the circular economy. Clarifying the requirements will allow companies to initially verify their ideas. For this purpose, an analysis was carried out of the requirements set for enterprises by committees assessing circular economy projects and allocating funds for their implementation. The analysis allowed us to identify several features that indicate whether a given project fits into the circular economy model. The article proposes a system model that can be used to prepare the company for changes towards the Green Deal (GD) by implementing the Cleaner Production (CP) strategy in the company. The implementation of a Cleaner Production strategy initiates further changes, gradually developing the company’s potential towards implementing the circular economy assumptions. This solution is much cheaper than the expensive services of consulting companies and much simpler than trying to prepare a competition application on your own, the authors asked themselves a research question: can the implementation of a Cleaner Production project be an initial action supporting SMEs in obtaining external funds (domestic and foreign) intended for the implementation of circular economy solutions? Full article
15 pages, 2224 KiB  
Article
The Lifting Performance and Experimental Study of a Variable Spiral Spike-Toothed Crop Divider
by Jing Bai, Shaochun Ma and Chao Cheng
Agriculture 2024, 14(6), 916; https://doi.org/10.3390/agriculture14060916 (registering DOI) - 9 Jun 2024
Abstract
The contact between a traditional crop divider and sugarcane is unstable, and the sugarcane easily slides off of its surface. By analyzing the movement process of sugarcane, the influence of traditional spiral flightings on lifting performance was studied, and shortcomings were also found. [...] Read more.
The contact between a traditional crop divider and sugarcane is unstable, and the sugarcane easily slides off of its surface. By analyzing the movement process of sugarcane, the influence of traditional spiral flightings on lifting performance was studied, and shortcomings were also found. Based on previous research and analysis, the variable spiral spike-toothed crop divider was designed by research groups. For sugarcane with different lodging states, the contact separation rule between the sugarcane and the spike tooth was studied, and the action time and angle of the spike tooth on sugarcane were obtained. At the same time, the interaction mechanism between sugarcane and the spike tooth was analyzed, and the conditions for lodged canes to be lifted were obtained. The influence of the spike tooth on the lifting performance was explored, and the working advantages were found for the spike-toothed crop divider. Then, a simulation test was conducted to obtain the contact force between the sugarcane and the crop divider. Finally, the crop divider was optimized and integrated into the harvester, and a field harvesting test was carried out to verify the working performance of the crop divider. This study was expected to provide a reference for the design of crop dividers and a theoretical basis for the analysis of the lifting process. Full article
(This article belongs to the Section Agricultural Technology)
23 pages, 3038 KiB  
Review
Non-Linear Phenomena in Voltage and Frequency Converters Supplying Non-Thermal Plasma Reactors
by Grzegorz Karol Komarzyniec, Henryka Danuta Stryczewska and Oleksandr Boiko
Energies 2024, 17(12), 2846; https://doi.org/10.3390/en17122846 (registering DOI) - 9 Jun 2024
Abstract
Atmospheric pressure cold plasmas have recently been the subject of intense research and applications for solving problems in the fields of energy, environmental engineering, and biomedicine. Non-thermal atmospheric pressure plasma sources, with dielectric barrier discharges, plasma jets, and arc discharges, are non-linear power [...] Read more.
Atmospheric pressure cold plasmas have recently been the subject of intense research and applications for solving problems in the fields of energy, environmental engineering, and biomedicine. Non-thermal atmospheric pressure plasma sources, with dielectric barrier discharges, plasma jets, and arc discharges, are non-linear power loads. They require special power systems, which are usually designed separately for each type of plasma reactor, depending on the requirements of the plasma-chemical process, the power of the receiver, the type of process gas, the current, voltage and frequency requirements, and the efficiency of the power source. This paper presents non-linear phenomena accompanying plasma generation in the power supply plasma reactor system, such as harmonic generation, resonance, and ferroresonance of currents and voltages, and the switching of overvoltages and pulse generation. When properly applied, this can support the operation of the above-mentioned reactors by providing improved discharge ignition depending on the working gas, thus increasing the efficiency of the plasma process and improving the cooperation of the plasma-generation system with the power supply. Full article
(This article belongs to the Special Issue Energy, Electrical and Power Engineering 2024)
14 pages, 602 KiB  
Article
Preparative Fractionation of Brazilian Red Propolis Extract Using Step-Gradient Counter-Current Chromatography
by Begoña Gimenez-Cassina Lopez, Maria Cristina Marcucci, Silvana Aparecida Rocco, Maurício Luís Sforça, Marcos Nogueira Eberlin, Peter Hewitson, Svetlana Ignatova and Alexandra Christine Helena Frankland Sawaya
Molecules 2024, 29(12), 2757; https://doi.org/10.3390/molecules29122757 (registering DOI) - 9 Jun 2024
Abstract
Propolis is a resinous bee product with a very complex composition, which is dependent upon the plant sources that bees visit. Due to the promising antimicrobial activities of red Brazilian propolis, it is paramount to identify the compounds responsible for it, which, in [...] Read more.
Propolis is a resinous bee product with a very complex composition, which is dependent upon the plant sources that bees visit. Due to the promising antimicrobial activities of red Brazilian propolis, it is paramount to identify the compounds responsible for it, which, in most of the cases, are not commercially available. The aim of this study was to develop a quick and clean preparative-scale methodology for preparing fractions of red propolis directly from a complex crude ethanol extract by combining the extractive capacity of counter-current chromatography (CCC) with preparative HPLC. The CCC method development included step gradient elution for the removal of waxes (which can bind to and block HPLC columns), sample injection in a single solvent to improve stationary phase stability, and a change in the mobile phase flow pattern, resulting in the loading of 2.5 g of the Brazilian red propolis crude extract on a 912.5 mL Midi CCC column. Three compounds were subsequently isolated from the concentrated fractions by preparative HPLC and identified by NMR and high-resolution MS: red pigment, retusapurpurin A; the isoflavan 3(R)-7-O-methylvestitol; and the prenylated benzophenone isomers xanthochymol/isoxanthochymol. These compounds are markers of red propolis that contribute to its therapeutic properties, and the amount isolated allows for further biological activities testing and for their use as chromatographic standards. Full article
16 pages, 1178 KiB  
Technical Note
Examining the Capability of the VLF Technique for Nowcasting Solar Flares Based on Ground Measurements in Antarctica
by Shiwei Wang, Ruoxian Zhou, Xudong Gu, Wei Xu, Zejun Hu, Binbin Ni, Wen Cheng, Jingyuan Feng, Wenchen Ma, Haotian Xu, Yudi Pan, Bin Li, Fang He, Xiangcai Chen and Hongqiao Hu
Remote Sens. 2024, 16(12), 2092; https://doi.org/10.3390/rs16122092 (registering DOI) - 9 Jun 2024
Abstract
Measurements of Very-Low-Frequency (VLF) transmitter signals have been widely used to investigate the effects of various space weather events on the D-region ionosphere, including nowcasting solar flares. Previous studies have established a method to nowcast solar flares using VLF measurements, but only using [...] Read more.
Measurements of Very-Low-Frequency (VLF) transmitter signals have been widely used to investigate the effects of various space weather events on the D-region ionosphere, including nowcasting solar flares. Previous studies have established a method to nowcast solar flares using VLF measurements, but only using measurements from dayside propagation paths, and there remains limited focus on day–night mixed paths, which are important for method applicability. Between March and May of 2022, the Sun erupted a total of 56 M-class and 6 X-class solar flares, all of which were well captured by our VLF receiver in Antarctica. Using these VLF measurements, we reexamine the capability of the VLF technique to nowcast solar flares by including day–night mixed propagation paths and expanding the path coverage in longitude compared to that in previous studies. The amplitude and phase maximum changes are generally positively correlated with X-ray fluxes, whereas the time delay is negatively correlated. The curve-fitting parameters that we obtain for the X-ray fluxes and VLF signal maximum changes are consistent with those in previous studies for dayside paths, even though different instruments are used, supporting the flare-nowcasting method. Moreover, the present results show that, for day–night mixed paths, the amplitude and phase maximum changes also scale linearly with the logarithm of the flare X-ray fluxes, but the level of change is notably different from that for dayside paths. The coefficients used in the flare-nowcasting method need to be updated for mixed propagation paths. Full article
25 pages, 579 KiB  
Article
An Integrated Approach to Cyber Risk Management with Cyber Threat Intelligence Framework to Secure Critical Infrastructure
by Habib El Amin, Abed Ellatif Samhat, Maroun Chamoun, Lina Oueidat and Antoine Feghali
J. Cybersecur. Priv. 2024, 4(2), 357-381; https://doi.org/10.3390/jcp4020018 (registering DOI) - 9 Jun 2024
Abstract
Emerging cyber threats’ sophistication, impact, and complexity rapidly evolve, confronting organizations with demanding challenges. This severe escalation requires a deeper understanding of adversary dynamics to develop enhanced defensive strategies and capabilities. Cyber threat actors’ advanced techniques necessitate a proactive approach to managing organizations’ [...] Read more.
Emerging cyber threats’ sophistication, impact, and complexity rapidly evolve, confronting organizations with demanding challenges. This severe escalation requires a deeper understanding of adversary dynamics to develop enhanced defensive strategies and capabilities. Cyber threat actors’ advanced techniques necessitate a proactive approach to managing organizations’ risks and safeguarding cyberspace. Cyber risk management is one of the most efficient measures to anticipate cyber threats. However, it often relies on organizations’ contexts and overlooks adversaries, their motives, capabilities, and tactics. A new cyber risk management framework incorporating emergent information about the dynamic threat landscape is needed to overcome these limitations and bridge the knowledge gap between adversaries and security practitioners. Such information is the product of a cyber threat intelligence process that proactively delivers knowledge about cyber threats to inform decision-making and strengthen defenses. In this paper, we overview risk management and threat intelligence frameworks. Then, we highlight the necessity of integrating cyber threat intelligence and assessment in cyber risk management. After that, we propose a novel risk management framework with integrated threat intelligence on top of EBIOS Risk Manager. Finally, we apply the proposed framework in the scope of a national telecommunications organization. Full article
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12 pages, 527 KiB  
Article
Reverse Shoulder Arthroplasty for Proximal Humeral Fractures: Is the Bigliani-Flatow Stem Suitable for Tuberosity Fixation and Healing?
by Enrico Bellato, Valeria Fava, Andrea Arpaia, Michel Calò, Antonio Marmotti and Filippo Castoldi
J. Clin. Med. 2024, 13(12), 3388; https://doi.org/10.3390/jcm13123388 (registering DOI) - 9 Jun 2024
Abstract
Background/Objectives: The aim of the study was to investigate the clinical, functional, and radiographic results of patients affected by three- or four-part proximal humeral fractures treated with reverse total shoulder arthroplasty, to investigate whether a prosthetic stem nonspecifically designed for fractures (i.e., [...] Read more.
Background/Objectives: The aim of the study was to investigate the clinical, functional, and radiographic results of patients affected by three- or four-part proximal humeral fractures treated with reverse total shoulder arthroplasty, to investigate whether a prosthetic stem nonspecifically designed for fractures (i.e., the Bigliani-Flatow stem) promotes tuberosities’ healing, and to evaluate the impact of tuberosity fixation and healing on the outcomes. Methods: Patients’ data such as gender, age, side and dominancy, comorbidities, complications during or after surgery, and time lapse between trauma and surgery were prospectively collected. The type of fixation of the stem, the thickness and type of liner, and whether the tuberosities were fixed or not were also recorded. The Constant score weighted on the contralateral limb, QuickDASH, Oxford Shoulder Score, and Subjective Shoulder Value were collected. Tuberosities’ healing was assessed with X-rays (anteroposterior, Grashey, and axillary views). Results: Overall, 34 patients were included, with an average follow-up of 42 months. Tuberosities were reinserted in 24 cases and their healing rate was 83%. The mean values were the following: a Constant score of 64, Oxford Shoulder Score of 39, Subjective Shoulder Value of 71, and QuickDASH score of 27. There were no significant differences in the scores or range of motion between patients with tuberosities healed, reabsorbed, or not reattached. There was a better external rotation in the group with healed tuberosities and a longer duration of surgery to reattach tuberosities. Conclusions: The treatment of proximal humerus fractures with the Bigliani-Flatow stem is associated with good clinical and functional results. The healing rate of the tuberosities was high and comparable, if not even better, than the mean rates reported for the stems dedicated to fractures of the proximal humerus and was, therefore, also appropriate for this indication. Full article
(This article belongs to the Special Issue Shoulder and Elbow Disease: Current Treatment and Future Options)
23 pages, 9646 KiB  
Article
Detecting Melt Pond Onset on Landfast Arctic Sea Ice Using a Dual C-Band Satellite Approach
by Syeda Shahida Maknun, Torsten Geldsetzer, Vishnu Nandan, John Yackel and Mallik Mahmud
Remote Sens. 2024, 16(12), 2091; https://doi.org/10.3390/rs16122091 (registering DOI) - 9 Jun 2024
Abstract
The presence of melt ponds on the surface of Arctic Sea ice affects its albedo, thermal properties, and overall melting rate; thus, the detection of melt pond onset is of significant importance for understanding the Arctic’s changing climate. This study investigates the utility [...] Read more.
The presence of melt ponds on the surface of Arctic Sea ice affects its albedo, thermal properties, and overall melting rate; thus, the detection of melt pond onset is of significant importance for understanding the Arctic’s changing climate. This study investigates the utility of a novel method for detecting the onset of melt ponds on sea ice using a satellite-based, dual-sensor C-band approach, whereby Sentinel-1 provides horizontally polarized (HH) data and Advanced SCATterometer (ASCAT) provides vertically polarized (VV) data. The co-polarized ratio (VV/HH) is used to detect the presence of melt ponds on landfast sea ice in the Canadian Arctic Archipelago in 2017 and 2018. ERA-5 air temperature and wind speed re-analysis datasets are used to establish the VV/HH threshold for pond onset detection, which have been further validated by Landsat-8 reflectance. The co-polarized ratio threshold of three standard deviations from the late winter season (April) mean co-pol ratio values are used for assessing pond onset detection associated with the air temperature and wind speed data, along with visual observations from Sentinel-1 and cloud-free Sentinel-2 imagery. In 2017, the pond onset detection rates were 70.59% for FYI and 92.3% for MYI. Results suggest that this method, because of its dual-platform application, has potential for providing large-area coverage estimation of the timing of sea ice melt pond onset using different earth observation satellites. Full article
17 pages, 364 KiB  
Article
A Long-Term Study on the Effect of a Professional Development Program on Science Teachers’ Inquiry
by Christina Tsaliki, Penelope Papadopoulou, Georgios Malandrakis and Petros Kariotoglou
Educ. Sci. 2024, 14(6), 621; https://doi.org/10.3390/educsci14060621 (registering DOI) - 9 Jun 2024
Abstract
In this study we explore the effect of a professional development (PD) program on four science teachers’ views and practices nearly a year after its completion, regarding inquiry implementation in everyday school practice. The PD program aimed to familiarize participants with current trends [...] Read more.
In this study we explore the effect of a professional development (PD) program on four science teachers’ views and practices nearly a year after its completion, regarding inquiry implementation in everyday school practice. The PD program aimed to familiarize participants with current trends in science education (SE), putting emphasis on the inquiry approach. The basic research question guiding this study is whether science teachers’ inquiry practices and views changed, and to which extent, long after their participation in the PD program. Teachers’ practices were recorded, both during and after the PD, through non-participatory observation and were analysed through a semi-quantitative method. Teachers’ views were also recorded both during and after PD through structured questionnaires and reflective interviews, producing qualitative data that were analysed. Findings are encouraging concerning the preservation of guided inquiry practices obtained during the program, while more open inquiry practices proved to be limited. Teachers’ views concerning inquiry remained positive, also maintaining their innovative character. Full article
20 pages, 5253 KiB  
Article
A Multi-Party Privacy-Preserving Record Linkage Method Based on Secondary Encoding
by Shumin Han, Yizi Wang, Derong Shen and Chuang Wang
Mathematics 2024, 12(12), 1800; https://doi.org/10.3390/math12121800 (registering DOI) - 9 Jun 2024
Abstract
With the advent of the big data era, data security and sharing have become the core elements of new-era data processing. Privacy-preserving record linkage (PPRL), as a method capable of accurately and securely matching and sharing the same entity across multiple data sources, [...] Read more.
With the advent of the big data era, data security and sharing have become the core elements of new-era data processing. Privacy-preserving record linkage (PPRL), as a method capable of accurately and securely matching and sharing the same entity across multiple data sources, is receiving increasing attention. Among the existing research methods, although PPRL methods based on Bloom Filter encoding excel in computational efficiency, they are susceptible to privacy attacks, and the security risks they face cannot be ignored. To balance the contradiction between security and computational efficiency, we propose a multi-party PPRL method based on secondary encoding. This method, based on Bloom Filter encoding, generates secondary encoding according to well-designed encoding rules and utilizes the proposed linking rules for secure matching. Owing to its excellent encoding and linking rules, this method successfully addresses the balance between security and computational efficiency. The experimental results clearly show that, in comparison to the original Bloom Filter encoding, this method has nearly equivalent computational efficiency and linkage quality. The proposed rules can effectively prevent the re-identification problem in Bloom Filter encoding (proven). Compared to existing privacy-preserving record linkage methods, this method shows higher security, making it more suitable for various practical application scenarios. The introduction of this method is of great significance for promoting the widespread application of privacy-preserving record linkage technology. Full article
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15 pages, 7199 KiB  
Article
Plasma Surface Treatment and Application of Polyvinyl Alcohol/Polylactic Acid Electrospun Fibrous Hemostatic Membrane
by Xiaotian Ge, Li Zhang, Xuanhe Wei, Xi Long and Yingchao Han
Polymers 2024, 16(12), 1635; https://doi.org/10.3390/polym16121635 (registering DOI) - 9 Jun 2024
Abstract
Abstract: In this study, an improved PVA/PLA fibrous hemostatic membrane was prepared by electrospinning technology combined with air plasma modification. The plasma treatment was used to modify PLA to enhance the interlayer bonding between the PVA and PLA fibrous membranes first, then [...] Read more.
Abstract: In this study, an improved PVA/PLA fibrous hemostatic membrane was prepared by electrospinning technology combined with air plasma modification. The plasma treatment was used to modify PLA to enhance the interlayer bonding between the PVA and PLA fibrous membranes first, then modify the PVA to improve the hemostatic capacity. The surfaces of the PLA and PVA were oxidized after air plasma treatment, the fibrous diameter was reduced, and roughness was increased. Plasma treatment enhanced the interfacial bond strength of PLA/PVA composite fibrous membrane, and PLA acted as a good mechanical support. Plasma-treated PVA/PLA composite membranes showed an increasing liquid-enrichment capacity of 350% and shortened the coagulation time to 258 s. The hemostatic model of the liver showed that the hemostatic ability of plasma-treated PVA/PLA composite membranes was enhanced by 79% compared to untreated PVA membranes, with a slight improvement over commercially available collagen. The results showed that the plasma-treated PVA/PLA fibers were able to achieve more effective hemostasis, which provides a new strategy for improving the hemostatic performance of hemostatic materials. Full article
26 pages, 3211 KiB  
Article
A Comprehensive Architecture for Federated Learning-Based Smart Advertising
by Rasool Seyghaly, Jordi Garcia and Xavi Masip-Bruin
Sensors 2024, 24(12), 3765; https://doi.org/10.3390/s24123765 (registering DOI) - 9 Jun 2024
Abstract
This paper introduces a cutting-edge data architecture designed for a smart advertising context, prioritizing efficient data flow and performance, robust security, while guaranteeing data privacy and integrity. At the core of this study lies the application of federated learning (FL) as the primary [...] Read more.
This paper introduces a cutting-edge data architecture designed for a smart advertising context, prioritizing efficient data flow and performance, robust security, while guaranteeing data privacy and integrity. At the core of this study lies the application of federated learning (FL) as the primary methodology, which emphasizes the authenticity and privacy of data while promptly discarding irrelevant or fraudulent information. Our innovative data model employs a semi-random role assignment strategy based on a variety of criteria to efficiently collect and amalgamate data. The architecture is composed of model nodes, data nodes, and validator nodes, where the role of each node is determined by factors such as computational capability, interconnection quality, and historical performance records. A key feature of our proposed system is the selective engagement of a subset of nodes for modeling and validation, optimizing resource use and minimizing data loss. The AROUND social network platform serves as a real-world case study, illustrating the efficacy of our data architecture in a practical setting. Both simulated and real implementations of our architecture showcase its potential to dramatically curtail network traffic and average CPU usage, while preserving the accuracy of the FL model. Remarkably, the system is capable of achieving over a 50% reduction in both network traffic and average CPU usage even when the user count escalates by twenty-fold. The click rate, user engagement, and other parameters have also been evaluated, proving that the proposed architecture’s advantages do not affect the smart advertising accuracy. These findings highlight the proposed architecture’s capacity to scale efficiently and maintain high performance in smart advertising environments, making it a valuable contribution to the evolving landscape of digital marketing and FL. Full article
(This article belongs to the Section Sensor Networks)
20 pages, 5732 KiB  
Article
The Experimental Characterization of Iron Ore Tailings from a Geotechnical Perspective
by Paulo Coelho and David Camacho
Appl. Sci. 2024, 14(12), 5033; https://doi.org/10.3390/app14125033 (registering DOI) - 9 Jun 2024
Abstract
The mining industry produces large amounts of tailings which are disposed of in deposits, which neglects their potential value and represents important economic, social and environmental risks. Consequently, implementing circular economy principles using these unconventional geomaterials may decrease the wide-ranging impacts of raw [...] Read more.
The mining industry produces large amounts of tailings which are disposed of in deposits, which neglects their potential value and represents important economic, social and environmental risks. Consequently, implementing circular economy principles using these unconventional geomaterials may decrease the wide-ranging impacts of raw material extraction. This paper presents an experimental characterization of iron ore tailings, which are the most abundant type of mining waste. The characterization includes various aspects of behavior that are relevant to different types of use as a building material, including physical and identification properties, compaction behavior and stress–strain properties under undrained monotonic and cyclic triaxial loading. The tailings tested can be described as low-plasticity silty sand materials with an average solids density of 4.7, a maximum dry unit weight close to 3 g/cm3 and a higher angle of friction and liquefaction resistance than common granular materials. The experimental results highlight the particular features of the behavior of iron ore tailings and emphasize the potentially promising combination of high shear resistance and high density that favors particular geotechnical applications. Overall, the conclusions provide the basis for promoting the use of mining wastes in the construction of sustainable geotechnical works and underpin the advanced analysis of tailings storage facilities’ safety founded on an open-minded geotechnical approach. Full article
(This article belongs to the Special Issue Sustainability in Geotechnics)
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16 pages, 2972 KiB  
Article
Carboxymethyl β-Cyclodextrin Assistance for the 4-Nitrophenol Reduction Using Cobalt-Based Layered Double Hydroxides
by Alexia Demeester, Fatima Douma, Renaud Cousin, Stéphane Siffert, Gwladys Pourceau, Anne Wadouachi, Anne Ponchel, Eric Monflier and Sébastien Noël
Int. J. Mol. Sci. 2024, 25(12), 6390; https://doi.org/10.3390/ijms25126390 (registering DOI) - 9 Jun 2024
Abstract
Cobalt-aluminum-layered double hydroxides containing carboxymethyl β-cyclodextrin (CMβCD) were synthesized by coprecipitation and evaluated as a cobalt source for the 4-nitrophenol reduction in an aqueous medium. Several physicochemical techniques (XRD, FTIR, TGA) indicated the intercalation of the anionic cyclodextrin without damages to the hydrotalcite-type [...] Read more.
Cobalt-aluminum-layered double hydroxides containing carboxymethyl β-cyclodextrin (CMβCD) were synthesized by coprecipitation and evaluated as a cobalt source for the 4-nitrophenol reduction in an aqueous medium. Several physicochemical techniques (XRD, FTIR, TGA) indicated the intercalation of the anionic cyclodextrin without damages to the hydrotalcite-type structure. These lamellar cobalt-aluminum hybrid materials (CoAl_CMβCD) were evaluated in the 4-nitrophenol reduction and showed higher activities in comparison with the CMβCD-free standard material (CoAl_CO3). To rationalize these results, a set of experimental controls going from physical mixtures of CoAl_CO3 with different cyclodextrins to other cobalt-based materials were investigated, highlighting the beneficial effects of both the layered double hydroxide and CMβCD-based hybrid structures. CMβCD also showed a beneficial effect as an additive during the 4-nitrophenol reduction. CoAl_CO3, dispersed in a fresh CMβCD solution could be re-used for five successive cycles without the loss of activity. Full article
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26 pages, 4156 KiB  
Article
Enhanced Berth Mapping and Clothoid Trajectory Prediction Aided Intelligent Underground Localization
by Fei Li, Jialiang Chen, Yuelin Yuan, Zhaozheng Hu and Xiaohui Liu
Appl. Sci. 2024, 14(12), 5032; https://doi.org/10.3390/app14125032 (registering DOI) - 9 Jun 2024
Abstract
In response to the widespread absence of global navigation satellite system (GNSS) signals in underground parking scenes, we propose a multimodal localization method that integrates enhanced berth mapping with Clothoid trajectory prediction, enabling high-precision localization for intelligent vehicles in underground parking environments. This [...] Read more.
In response to the widespread absence of global navigation satellite system (GNSS) signals in underground parking scenes, we propose a multimodal localization method that integrates enhanced berth mapping with Clothoid trajectory prediction, enabling high-precision localization for intelligent vehicles in underground parking environments. This method began by constructing a lightweight map based on the key berths. The map consisted of a series of discrete nodes, each encompassing three elements: holistic and local scene features extracted from an around-view image, and the global pose of the mapping vehicle calculated using the positions of the key berth’s corner points. An adaptive localization strategy was employed during the localization phase based on the trajectory prediction result. A progressive localization strategy, relying on multi-scale feature matching, was applied to the nodes within the map coverage range. Additionally, a compensation localization strategy that combined odometry with the prior pose was utilized for the nodes outside the map coverage range. The experiments conducted in two typical underground parking scenes demonstrated that the proposed method achieved a trajectory prediction accuracy of 40 cm, a nearest map search accuracy exceeding 92%, and a metric localization accuracy meeting the 30 cm standard. These results indicate that the proposed approach satisfies the high-precision, robust, real-time localization requirements for intelligent vehicles in underground parking scenes, while effectively reducing the map memory requirements. Full article
(This article belongs to the Special Issue Mobile Robotics and Autonomous Intelligent Systems)
14 pages, 3852 KiB  
Article
Study on Discharge Characteristic Performance of New Energy Electric Vehicle Batteries in Teaching Experiments of Safety Simulation under Different Operating Conditions
by Meilin Gong, Jiatao Chen, Jianming Chen and Xiaohuan Zhao
Energies 2024, 17(12), 2845; https://doi.org/10.3390/en17122845 (registering DOI) - 9 Jun 2024
Abstract
High-voltage heat release from batteries can cause safety issues for electric vehicles. Relevant scientific research work is carried out in the laboratory. The battery safety of laboratory experiments should not be underestimated. In order to evaluate the safety performance of batteries in the [...] Read more.
High-voltage heat release from batteries can cause safety issues for electric vehicles. Relevant scientific research work is carried out in the laboratory. The battery safety of laboratory experiments should not be underestimated. In order to evaluate the safety performance of batteries in the laboratory testing of driving conditions of electric vehicles, this paper simulated and compared the discharge characteristics of two common batteries (lithium iron phosphate (LFP) battery and nickel–cobalt–manganese (NCM) ternary lithium battery) in three different operating conditions. The operating conditions are the NEDC (New European Driving Cycle), WLTP (World Light Vehicle Test Procedure) and CLTC-P (China light vehicle test cycle) for normal driving of electric vehicles. LFP batteries have a higher maximum voltage and lower minimum voltage under the same initial voltage conditions, with a maximum voltage difference variation of 11 V. The maximum current of WLTP is significantly higher than NEDC and CLTC-P operating conditions (>20 A). Low current discharge conditions should be emulated in teaching simulation and experiments for safety reasons. The simulation data showed that the LFP battery had good performance in maintaining the voltage plateau and discharge voltage stability, while the NCM battery had excellent energy density and long-term endurance. Full article
(This article belongs to the Special Issue Advances in Hybrid Vehicles: Volume II)
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14 pages, 2681 KiB  
Article
A Comprehensive Analysis of Unclamped-Inductive-Switching-Induced Electrical Parameter Degradations and Optimizations for 4H-SiC Trench Metal-Oxide-Semiconductor Field-Effect Transistor Structures
by Li Liu, Jingqi Guo, Yiheng Shi, Kai Zeng and Gangpeng Li
Micromachines 2024, 15(6), 772; https://doi.org/10.3390/mi15060772 (registering DOI) - 9 Jun 2024
Abstract
This paper presents a comprehensive study on single- and repetitive-frequency UIS characteristics of 1200 V asymmetric (AT) and double trench silicon carbide (DT-SiC) metal-oxide-semiconductor field-effect transistors (MOSFETs) and their electrical degradation under electrical–thermal working conditions, investigated through experiment and simulation verification. Because their [...] Read more.
This paper presents a comprehensive study on single- and repetitive-frequency UIS characteristics of 1200 V asymmetric (AT) and double trench silicon carbide (DT-SiC) metal-oxide-semiconductor field-effect transistors (MOSFETs) and their electrical degradation under electrical–thermal working conditions, investigated through experiment and simulation verification. Because their structure is different, the failure mechanisms are different. Comparatively, the gate oxide of a DT-MOSFET is more easily damaged than an AT-MOSFET because the hot carriers are injected into the oxide. The parameters’ degradation under repetitive UIS stress also requires analysis. The variations in the measured parameters are recorded to evaluate typical electrical features of device failure. Furthermore, TCAD simulation is used to reveal the electrothermal stress inside the device during avalanche. Additionally, failed devices are decapsulated to verify the location of the failure point. Finally, a new type of stepped-oxide vertical power DT MOSFET with P-type shielding and current spread layers, along with its feasible process flow, is proposed for the improvement of gate dielectric reliability. Full article
23 pages, 2401 KiB  
Article
Study on the Effect of Cracking Parameters on the Migration Characteristics of Chloride Ions in Cracked Concrete
by Tao Huang, Shuang Feng, Mengge Wang and Zhongqi Peng
Buildings 2024, 14(6), 1738; https://doi.org/10.3390/buildings14061738 (registering DOI) - 9 Jun 2024
Abstract
In engineering, concrete often develops cracks due to various reasons, which accelerate the erosion rate of chloride ions in concrete and consequently expedite the degradation of the mechanical properties of concrete structures. This study simplifies the four-phase model into a two-phase model using [...] Read more.
In engineering, concrete often develops cracks due to various reasons, which accelerate the erosion rate of chloride ions in concrete and consequently expedite the degradation of the mechanical properties of concrete structures. This study simplifies the four-phase model into a two-phase model using homogenization methods. Based on this, numerical simulations are employed to investigate the influences of dimensionless structural parameters and material parameters of cracks on the equivalent diffusion coefficient of cracked concrete, and a theoretical model for the equivalent diffusion coefficient of cracked concrete is established according to Fick’s diffusion law. The research findings indicate that when cracks are positioned in the middle of the boundary through which chloride ions enter and exit the concrete, and the direction of the cracks is parallel to the diffusion direction of chloride ions; this scenario is the most detrimental to the durability of concrete. For n cracks (n ≥ 2), when they are parallel to the x-axis and symmetrical about the x-axis, and the spacing between cracks equals 1/n times the width of the concrete, this scenario is the most detrimental to the durability of concrete containing multiple cracks. Whether for a single crack or multiple cracks, when they are in the most unfavorable condition, the “parallel-then-series” theoretical model can accurately predict the equivalent diffusion coefficient of cracked concrete. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
18 pages, 5301 KiB  
Review
A Comprehensive Review and Insights into the New Entity of Differentiated High-Grade Thyroid Carcinoma
by Agnes Stephanie Harahap, Regina Stefani Roren and Shofiyya Imtiyaz
Curr. Oncol. 2024, 31(6), 3311-3328; https://doi.org/10.3390/curroncol31060252 (registering DOI) - 9 Jun 2024
Abstract
Differentiated high-grade thyroid carcinoma (DHGTC) is a new subset within the spectrum of thyroid malignancies. This review aims to provide a comprehensive overview of DHGTC, focusing on its historical perspective, diagnosis, clinical characteristics, molecular profiles, management, and prognosis. DHGTC demonstrates an intermediate prognosis [...] Read more.
Differentiated high-grade thyroid carcinoma (DHGTC) is a new subset within the spectrum of thyroid malignancies. This review aims to provide a comprehensive overview of DHGTC, focusing on its historical perspective, diagnosis, clinical characteristics, molecular profiles, management, and prognosis. DHGTC demonstrates an intermediate prognosis that falls between well-differentiated thyroid carcinoma and anaplastic thyroid carcinoma. Previously unenumerated, this entity is now recognized for its significant impact. Patients with DHGTC often present at an older age with advanced disease and exhibit aggressive clinical behavior. Molecularly, DHGTC shares similarities with other thyroid malignancies, harboring driver mutations such as BRAFV600E and RAS, along with additional late mutations. The unique behavior and histologic features of DHGTC underscore the necessity of precise classification for prognostication and treatment selection. This highlights the critical importance of accurate diagnosis and recognition by pathologists to enrich future research on this entity further. Full article
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24 pages, 21619 KiB  
Article
A Vehicle Velocity Prediction Method with Kinematic Segment Recognition
by Benxiang Lin, Chao Wei and Fuyong Feng
Appl. Sci. 2024, 14(12), 5030; https://doi.org/10.3390/app14125030 (registering DOI) - 9 Jun 2024
Abstract
Accurate vehicle velocity prediction is of great significance in vehicle energy distribution and road traffic management. In light of the high time variability of vehicle velocity itself and the limitation of single model prediction, a velocity prediction method based on K-means-QPSO-LSTM with kinematic [...] Read more.
Accurate vehicle velocity prediction is of great significance in vehicle energy distribution and road traffic management. In light of the high time variability of vehicle velocity itself and the limitation of single model prediction, a velocity prediction method based on K-means-QPSO-LSTM with kinematic segment recognition is proposed in this paper. Firstly, the K-means algorithm was used to cluster samples with similar characteristics together, extract kinematic fragment samples in typical driving conditions, calculate their feature parameters, and carry out principal component analysis on the feature parameters to achieve dimensionality reduction transformation of information. Then, the vehicle velocity prediction sub-neural network models based on long short-term memory (LSTM) with the QPSO algorithm optimized were trained under different driving condition datasets. Furthermore, the kinematic segment recognition and traditional vehicle velocity prediction were integrated to form an adaptive vehicle velocity prediction method based on driving condition identification. Finally, the current driving condition type was identified and updated in real-time during vehicle velocity prediction, and then the corresponding sub-LSTM model was used for vehicle velocity prediction. The simulation experiment demonstrated a significant enhancement in both the velocity and accuracy of prediction through the proposed method. The proposed hybrid method has the potential to improve the accuracy and reliability of vehicle velocity prediction, making it applicable in various fields such as autonomous driving, traffic management, and energy management strategies for hybrid electric vehicles. Full article
(This article belongs to the Topic Artificial Intelligence Models, Tools and Applications)
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15 pages, 6547 KiB  
Article
Effect of Calcination Atmosphere on the Performance of Cu/Al2O3 Catalyst for the Selective Hydrogenation of Furfural to Furfuryl Alcohol
by Yongzhen Gao, Wenjing Yi, Jingyi Yang, Kai Jiang, Tao Yang, Zhihan Li, Meng Zhang, Zhongyi Liu and Benlai Wu
Molecules 2024, 29(12), 2753; https://doi.org/10.3390/molecules29122753 (registering DOI) - 9 Jun 2024
Abstract
The selective hydrogenation of the biomass platform molecule furfural (FAL) to produce furfuryl alcohol (FA) is of great significance to alleviate the energy crisis. Cu-based catalysts are the most commonly used catalysts, and their catalytic performance can be optimized by changing the preparation [...] Read more.
The selective hydrogenation of the biomass platform molecule furfural (FAL) to produce furfuryl alcohol (FA) is of great significance to alleviate the energy crisis. Cu-based catalysts are the most commonly used catalysts, and their catalytic performance can be optimized by changing the preparation method. This paper emphasized the effect of calcination atmosphere on the performance of a Cu/Al2O3 catalyst for the selective hydrogenation of FAL. The precursor of the Cu/Al2O3 catalyst prepared by the ammonia evaporation method was treated with different calcination atmospheres (N2 and air). On the basis of the combined results from the characterizations using in situ XRD, TEM, N2O titration, H2-TPR and XPS, the Cu/Al2O3 catalyst calcined in the N2 atmosphere was more favorable for the dispersion and reduction of Cu species and the reduction process could produce more Cu+ and Cu0 species, which facilitated the selective hydrogenation of FAL to FA. The experimental results showed that the N2 calcination atmosphere improved the FAL conversion and FA selectivity, and the FAL conversion was further increased after reduction. Cu/Al2O3-N2-R exhibited the outstanding performance, with a high yield of 99.9% of FA after 2 h at 120 °C and an H2 pressure of 1 MPa. This work provides a simple, efficient and economic method to improve the C=O hydrogenation performance of Cu-based catalysts. Full article
(This article belongs to the Special Issue New Strategies for Metal Catalysis in Heterogeneous System)
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25 pages, 25566 KiB  
Review
Preparation of Fibrous Three-Dimensional Porous Materials and Their Research Progress in the Field of Stealth Protection
by Peng Zhang, Shuang Zhao, Guobing Chen, Kunfeng Li, Jun Chen, Zhen Zhang, Feiyue Yang and Zichun Yang
Nanomaterials 2024, 14(12), 1003; https://doi.org/10.3390/nano14121003 (registering DOI) - 9 Jun 2024
Abstract
Intelligent and diversified development of modern detection technology greatly affects the battlefield survivability of military targets, especially infrared, acoustic wave, and radar detection expose targets by capturing their unavoidable infrared radiation, acoustic wave, and electromagnetic wave information, greatly affecting their battlefield survival and [...] Read more.
Intelligent and diversified development of modern detection technology greatly affects the battlefield survivability of military targets, especially infrared, acoustic wave, and radar detection expose targets by capturing their unavoidable infrared radiation, acoustic wave, and electromagnetic wave information, greatly affecting their battlefield survival and penetration capabilities. Therefore, there is an urgent need to develop stealth-protective materials that can suppress infrared radiation, reduce acoustic characteristics, and weaken electromagnetic signals. Fibrous three-dimensional porous materials, with their high porosity, excellent structural adjustability, and superior mechanical properties, possess strong potential for development in the field of stealth protection. This article introduced and reviewed the characteristics and development process of fibrous three-dimensional porous materials at both the micrometer and nanometer scales. Then, the process and characteristics of preparing fibrous three-dimensional porous materials through vacuum forming, gel solidification, freeze-casting, and impregnation stacking methods were analyzed and discussed. Meanwhile, their current application status in infrared, acoustic wave, and radar stealth fields was summarized and their existing problems and development trends in these areas from the perspectives of preparation processes and applicability were analyzed. Finally, several prospects for the current challenges faced by fibrous three-dimensional porous materials were proposed as follows: functionally modifying fibers to enhance their applicability through self-cross-linking; establishing theoretical models for the transmission of thermal energy, acoustic waves, and electromagnetic waves within fibrous porous materials; constructing fibrous porous materials resistant to impact, shear, and fracture to meet the needs of practical applications; developing multifunctional stealth fibrous porous materials to confer full-spectrum broadband stealth capability; and exploring the relationship between material size and mechanical properties as a basis for preparing large-scale samples that meet the application’s requirement. This review is very timely and aims to focus researchers’ attention on the importance and research progress of fibrous porous materials in the field of stealth protection, so as to solve the problems and challenges of fibrous porous materials in the field of stealth protection and to promote the further innovation of fibrous porous materials in terms of structure and function. Full article
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