Abstract
Precise ab initio calculations of the rovibrational structures of the and electronic states of prompt a new vibrational assignment of the transition and provide the basis for the rotational analysis of the vibrational band by means of high-resolution optical-optical double resonance. The calculations, which use the single-surface adiabatic approach, reproduce our experimental data only if, as required by theory, a geometric phase of under pseudorotation around the equilateral configuration is imposed. We consider this the first verification of Berry's phase in high-resolution molecular spectroscopy.
- Received 29 June 1998
DOI:https://doi.org/10.1103/PhysRevLett.81.4584
©1998 American Physical Society