Adenaya, Adenike; Rios Quintero, Ruben; Brinkhoff, Thorsten; Lara-Martín, Pablo A; Wurl, Oliver; Ribas-Ribas, Mariana (2023): Distribution of pharmaceutical compounds in coastal waters of the North Sea in March 2023 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.963943
Always quote citation above when using data! You can download the citation in several formats below.
Abstract:
We investigated the occurrence, spatial, and vertical distributions of 63 pharmaceutical compounds and six artificial sweeteners from the sea surface microlayer (SML) to five different depths (0 cm, 20 cm, 50 cm, 100 cm, and 150 cm) of the corresponding underlying waters in four stations of the North Sea. One station is a coastal area (Jade Bay), one station is an estuary (Bremerhaven), and the other two stations (NS_7 and NS_8) are open coastal waters. We will refer to each environment with the name in brackets throughout this publication. We collected seawater samples vertically from these stations and analyzed them using ultra-performance liquid chromatography - triple quadrupole mass spectrometry in tandem with ionization spray (UPLC-QqQMS/MS) (Bruker EVOQ Elite system Bruker, USA) at the Department of Physical Chemistry, University of Cádiz.
Keyword(s):
Supplement to:
Adenaya, Adenike; Rios Quintero, Ruben; Brinkhoff, Thorsten; Lara-Martín, Pablo A; Wurl, Oliver; Ribas-Ribas, Mariana (2023): Vertical Distribution of Pharmaceutical Contaminants in North Sea Coastal Waters and Risk Assessments. Preprint, SSRN, https://doi.org/10.2139/ssrn.4623663
Further details:
Adenaya, Adenike (2023): Supplementary information for distribution of pharmaceutical compounds in coastal waters of the North Sea. Supplementary_data_Vertical_Distribution_of_Pharmaceutical_Compounds.pdf
Coverage:
Median Latitude: 53.907693 * Median Longitude: 7.940682 * South-bound Latitude: 53.523002 * West-bound Longitude: 7.245698 * North-bound Latitude: 54.868190 * East-bound Longitude: 8.580609
Date/Time Start: 2023-03-12T07:12:00 * Date/Time End: 2023-03-19T08:16:00
Minimum DEPTH, water: 0.0 m * Maximum DEPTH, water: 1.5 m
Event(s):
HE614_20-2 * Latitude Start: 53.533743 * Longitude Start: 8.183051 * Latitude End: 53.599136 * Longitude End: 8.162742 * Date/Time Start: 2023-03-12T07:03:50 * Date/Time End: 2023-03-12T08:00:01 * Elevation Start: -26.0 m * Elevation End: -17.0 m * Location: North Sea * Campaign: HE614 (SCANS) * Basis: Heincke * Method/Device: Rubber boat, Zodiac (ZODIAC)
HE614_21-1 * Latitude Start: 53.523010 * Longitude Start: 8.580611 * Latitude End: 53.523003 * Longitude End: 8.580611 * Date/Time Start: 2023-03-13T07:00:01 * Date/Time End: 2023-03-13T13:30:59 * Location: North Sea * Campaign: HE614 (SCANS) * Basis: Heincke * Method/Device: CATAMARAN (CATM)
HE614_28-6 * Latitude Start: 53.853523 * Longitude Start: 7.565429 * Latitude End: 53.865614 * Longitude End: 7.631295 * Date/Time Start: 2023-03-17T12:59:35 * Date/Time End: 2023-03-17T15:24:31 * Elevation Start: -18.0 m * Elevation End: -19.0 m * Location: North Sea * Campaign: HE614 (SCANS) * Basis: Heincke * Method/Device: Rubber boat, Zodiac (ZODIAC)
Comment:
The value <0.001 in the data table refers to 'below the detection limit'. The specific limit of quantification for each pharmaceutical compound can be found in the supplementary information.
Parameter(s):
| # | Name | Short Name | Unit | Principal Investigator | Method/Device | Comment |
|---|---|---|---|---|---|---|
| 1 | Event label | Event | Adenaya, Adenike | |||
| 2 | LATITUDE | Latitude | Adenaya, Adenike | Geocode | ||
| 3 | LONGITUDE | Longitude | Adenaya, Adenike | Geocode | ||
| 4 | DATE/TIME | Date/Time | Adenaya, Adenike | Geocode | ||
| 5 | Salinity | Sal | Adenaya, Adenike | Thermosalinograph (TSG) | ||
| 6 | Temperature, water | Temp | °C | Adenaya, Adenike | Thermosalinograph (TSG) | |
| 7 | Wind speed | ff | m/s | Adenaya, Adenike | Ship Weather Station (SWEAS) | |
| 8 | DEPTH, water | Depth water | m | Adenaya, Adenike | Geocode | |
| 9 | Station label | Station | Adenaya, Adenike | |||
| 10 | Device type | Device | Adenaya, Adenike | |||
| 11 | Sample type | Samp type | Adenaya, Adenike | |||
| 12 | Acetaminophen | Acetaminophen | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Anti-inflammatory |
| 13 | Diclofenac | Diclofenac | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Anti-inflammatory |
| 14 | Fenoprofen | Fenoprofen | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Anti-inflammatory |
| 15 | Ibuprofen | Ibuprofen | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Anti-inflammatory |
| 16 | Indometacin | Indometacin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Anti-inflammatory |
| 17 | Ketoprofen | Ketoprofen | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Anti-inflammatory |
| 18 | Mefenamic acid | Mefenamic acid | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Anti-inflammatory |
| 19 | Naproxen | Naproxen | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Anti-inflammatory |
| 20 | Phenylbutazone | Phenylbutazone | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Anti-inflammatory |
| 21 | Acetylsalicylic acid | Acetylsalicylic acid | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Anti-inflammatory |
| 22 | Atenolol | Atenolol | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Beta-blocker |
| 23 | Pindolol | Pindolol | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Beta-blocker |
| 24 | Nadolol | Nadolol | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Beta-blocker |
| 25 | Metoprolol | Metoprolol | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Beta-blocker |
| 26 | Timolol | Timolol | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Beta-blocker |
| 27 | Propanolol | Propanolol | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Beta-blocker |
| 28 | Bezafibrate | Bezafibrate | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Lipid-regulator |
| 29 | Clofibric Acid | Clofibric Acid | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Lipid-regulator |
| 30 | Fenofibrate | Fenofibrate | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Lipid-regulator |
| 31 | Gemfibrozil | Gemfibrozil | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Lipid-regulator |
| 32 | Pravastatin | Pravastatin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Lipid-regulator |
| 33 | Furosemide | Furosemide | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Diuretic |
| 34 | Hydrochlorothiazide | Hydrochlorothiazide | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Diuretic |
| 35 | Caffeine | Caffeine | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Stimulant |
| 36 | Carbamazepine | Carbamazepine | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Stimulant |
| 37 | Fluoxetine | Fluoxetine | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Stimulant |
| 38 | Amitriptyline | Amitriptyline | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Anti-depressant |
| 39 | Ranitidine | Ranitidine | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Histamine-receptor antagonist |
| 40 | Famotidine | Famotidine | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Histamine-receptor antagonist |
| 41 | Lincomycin | Lincomycin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Lincosamide |
| 42 | Clindamycin | Clindamycin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Lincosamide |
| 43 | Spiramycin | Spiramycin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Macrolide |
| 44 | Azithromycin | Azithromycin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Macrolide |
| 45 | Clarithromycin | Clarithromycin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Macrolide |
| 46 | Tylosin | Tylosin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Macrolide |
| 47 | Erythromycin | Erythromycin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Macrolide |
| 48 | Roxithromycin | Roxithromycin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Macrolide |
| 49 | Azithromycin | Azithromycin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Macrolide |
| 50 | Ofloxacin | Ofloxacin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Quinolone |
| 51 | Enrofloxacin | Enrofloxacin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Quinolone |
| 52 | Danofloxacin | Danofloxacin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Quinolone |
| 53 | Sparfloxacin | Sparfloxacin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Quinolone |
| 54 | Flumequine | Flumequine | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Quinolone |
| 55 | Metronidazole | Metronidazole | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Nitroimidazol |
| 56 | Ornidazole | Ornidazole | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Nitroimidazol |
| 57 | Chloramphenicol | Chloramphenicol | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Phenicol |
| 58 | Sulfaguanidine | Sulfaguanidine | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Sulfonamide |
| 59 | Sulfadiazine | Sulfadiazine | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Sulfonamide |
| 60 | Sulfamethizole | Sulfamethizole | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Sulfonamide |
| 61 | Sulfamethazine | Sulfamethazine | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Sulfonamide |
| 62 | Sulfamethoxazole | Sulfamethoxazole | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Sulfonamide |
| 63 | Sulfathiazole | Sulfathiazole | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Sulfonamide |
| 64 | Sulfisoxazole | Sulfisoxazole | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Sulfonamide |
| 65 | Sulfadimethoxine | Sulfadimethoxine | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Sulfonamide |
| 66 | Novobiocin | Novobiocin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Aminocoumarin |
| 67 | Doxycycline | Doxycycline | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Tetracycline |
| 68 | Chlortetracycline | Chlortetracycline | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Tetracycline |
| 69 | Oxytetracycline | Oxytetracycline | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Tetracycline |
| 70 | Trimethoprim | Trimethoprim | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Diaminopyrimidines |
| 71 | Rifampicin | Rifampicin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Rifampicin |
| 72 | Methotrexate | Methotrexate | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Other pharmaceuticals |
| 73 | Glibenclamide | Glibenclamide | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Other pharmaceuticals |
| 74 | Benzophenone-4 | Benzophenone-4 | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | UV-filter |
| 75 | Acesulfame | Acesulfame | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Artificial sweeteners |
| 76 | Saccharin | Saccharin | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Artificial sweeteners |
| 77 | Cyclamate | Cyclamate | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Artificial sweeteners |
| 78 | Aspartame | Aspartame | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Artificial sweeteners |
| 79 | Sucralose | Sucralose | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Artificial sweeteners |
| 80 | Neohesperidin dihydrochalcone | Neohesperidin dihydrochalcone | ng/l | Adenaya, Adenike | Ultra-performance liquid chromatography - triple quadrupole mass spectrometry, (UPLC-QqQMS/MS), Bruker, EVOQ Elite system | Artificial sweeteners |
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0)
Size:
1800 data points