Skip to main content
SpringerLink
Log in

Reversed phase behaviour of high molecular mass polystyrenes in ethyl acetate solvent mixtures

  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

The reversed phase behaviour of high molecular mass polystyrenes was investigated on C18 bonded phase columns with ethyl acetate-methanol and ethyl acetateacetonitrile mobile phases. The results are compared with the corresponding dichloromethane mobile phases. The ethyl acetate-methanol mobile phase showed anomalous elution behaviour, similar to other previously investigated solvent combinations with methanol. The ethyl acetate-acetonitrile mobile phase showed no anomalous behaviour, increased retention and, elution over a wider composition range compared with the dichloromethane-acetonitrile system. However, resolution between adjacent molecular masses was considerably worse.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. Schultz, H. Engelhardt, Chromatographia29, 205 (1990).

    Google Scholar 

  2. C. H. Lochmuller, M. B. McGranaghan, Anal. Chem.61, 2449 (1989).

    Google Scholar 

  3. R. A. Shalliker, P. E. Kavanagh, I. M. Russell, J. Chromatogr.543, 157 (1991).

    Google Scholar 

  4. G. Glöckner, Chromatographia25, 854 (1988).

    Google Scholar 

  5. R. A. Shalliker, P. E. Kavanagh, I. M. Russell, J. Chromatogr.558, 440 (1991).

    Google Scholar 

  6. D. M. Northrup, D. E. Martire, R. P. W. Scott, Anal. Chem.64, 16 (1992).

    Google Scholar 

  7. J. J. Lewis, L. B. Rogers, R. E. Pauls, J. Chromatogr.264, 339 (1983).

    Google Scholar 

  8. C. M. Hansen, Ind. Eng. Chem. Prod. Res. Dev.8, 2 (1969).

    Google Scholar 

  9. D. W. Armstrong, K. H. Bui, Anal. Chem.54, 706 (1982).

    Google Scholar 

  10. D. W. Armstrong, K. N. Bui, R. E. Boehm, J. Liq. Chromatogr.6, 1 (1983).

    Google Scholar 

  11. K. H. Bui, D. W. Armstrong, J. Liq. Chromatogr.7, 29 (1984).

    Google Scholar 

  12. K. H. Bui, D. W. Armstrong, J. Liq. Chromatogr.7, 45 (1984).

    Google Scholar 

  13. K. H. Bui, D. W. Armstrong, R. E. Boehm, J. Chromatogr.288, 15 (1984).

    Google Scholar 

  14. D. W. Armstrong, R. E. Boehm, J. Chromatogr. Sci.22, 378 (1984).

    Google Scholar 

  15. A. Alhedai, R. E. Boehm, D. E. Martire, Chromatographia29, 313 (1990).

    Google Scholar 

  16. G. Glöckner, S. Schmutzler, H. Engelhardt, R. Schultz, Chromatographia25, 983 (1988).

    Google Scholar 

  17. M. A. Quarry, M. A. Stadalius, T. H. Mourey, L. R. Snyder, J. Chromatogr.358, 1 (1986).

    Google Scholar 

  18. G. Glöckner, H. G. Barth, J. Chromatogr.499, 145 (1990).

    Google Scholar 

  19. H. Engelhardt, M. Czok, R. Schultz, E. Schweinheim, J. Chromatogr.458, 79 (1988).

    Google Scholar 

  20. J. P. Larman, J. J. DeStefano, A. P. Goldberg, R. W. Stout, L. R. Snyder, M. A. Stadalius, J. Chromatogr.255, 165 (1983).

    Google Scholar 

  21. R. A. Shalliker, P. E. Kavanagh, I. M. Russell, J. Chromatogr.A664, 221, (1994).

    Google Scholar 

  22. R. A. Shalliker, PhD Thesis, Deakin University, (1992).

  23. L. R. Snyder, in “High Performance Liquid Chromatography”, Horvath, C. S., Ed., Academic Press, New York,Vol. 1, p. 207, 1980.

    Google Scholar 

  24. R. A. Shalliker, P. E. Kavanagh, I. M. Russell, J. Chromatogr.,679, 105 (1994).

    Google Scholar 

  25. G. Glöckner, “Gradient HPLC of Copolymers and Chromatographic Crossfractionation”, Springer Verlag, New York/Berlin/Heidelberg, (1991), figure 5.9.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Biological and Chemical Sciences, Deakin University, 3217, Victoria, Australia

    R. A. Shalliker & P. E. Kavanagh

  2. Division of Wool Technology, CSIRO, 3216, Belmont, Victoria, Australia

    I. M. Russell

Authors
  1. R. A. Shalliker
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. E. Kavanagh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. M. Russell
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shalliker, R.A., Kavanagh, P.E. & Russell, I.M. Reversed phase behaviour of high molecular mass polystyrenes in ethyl acetate solvent mixtures. Chromatographia 39, 663–667 (1994). https://doi.org/10.1007/BF02274580

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02274580

Key words

Search

Navigation