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Extraction inductively coupled plasma-optical emission spectrometry (ICP-OES) determination of traces of phosphorus in tungsten

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Abstract

A method for the separation and preconcentration of traces of phosphorus from tungsten was developed. Solid phase extraction of the phosphovanadomolybdate complex performed on a micro-column was applied. Phosphorus was determined by optical emission spectroscopy (OES) with inductively coupled plasma (ICP) excitation. A limit of detection of 0.4 μg/g P with respect to the solid phase is obtained. By directly coupling the extraction/elution step to the ICP instrument a detection limit of 0.06 μg/g P in W was achieved. Besides, the complexity of spectral evaluation in ICP-OES determinations of traces in spectralline-rich matrices is discussed.

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Authors and Affiliations

  1. Institute of Analytical Chemistry, Micro- and Radiochemistry, Graz University of Technology, Technikerstrasse 4, A-8010, Graz, Austria

    Gottfried Bauer, Wolfhard Wegscheider & Kurt Müller

  2. Metallwerk Plansee GmbH, A-6600, Reutte, Tyrol, Austria

    Hugo M. Ortner

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  1. Gottfried Bauer
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  2. Wolfhard Wegscheider
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  3. Kurt Müller
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  4. Hugo M. Ortner
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Bauer, G., Wegscheider, W., Müller, K. et al. Extraction inductively coupled plasma-optical emission spectrometry (ICP-OES) determination of traces of phosphorus in tungsten. Mikrochim Acta 99, 399–412 (1989). https://doi.org/10.1007/BF01244696

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  • DOI: https://doi.org/10.1007/BF01244696

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