Abstract
It is shown that the so-called hypervirial theorems found byHirschfelder and coworkers (Sect. 1) are satisfied for a large class of variational trial functions (Sect. 2). The results are applied to several variational approximations to the eigenfunctions of the H +2 molecule (Sect. 3).
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Herrn Professor Dr. S.Flügge und Fräulein U.Eichmann danke ich für wertvolle Diskussionen.
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Schröder, U. Zur Gültigkeit von Hypervirialsätzen bei Variationsfunktionen. Z. Physik 172, 219–223 (1963). https://doi.org/10.1007/BF01377741
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DOI: https://doi.org/10.1007/BF01377741