Abstract
The air oxidation of three Fe-Cu alloyscontaining 25, 50, and 75 wt.% Cu has been studied at600-800°C. The oxidation followed the parabolic lawonly approximately with rates lower than those of thepure constituent metals. The scales were alwayscomposed of an inner layer containing a mixture ofcopper metal and iron oxide and of an outer oxide layerwhose composition depended on the copper content of the alloy. For the two alloys richer in ironthe external layer was composed mostly of iron oxideswith some copper-rich particles which oxidized only inthe external-scale zone. For the alloy richest in copper the external layer contained a complexmixture of iron oxides, copper particles and doubleFe-Cu oxides surmounted by an outermost copper-oxidelayer. No significant iron depletion was observed in the alloys beneath the region of internaloxidation. The peculiar scale microstructure observedfor these alloys is considered mainly as a consequenceof their two-phase microstructure and of the limited solubilities of the two components in oneanother.
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REFERENCES
N. S. Stoloff, in Superalloys II, C. T. Sims, N. S. Stoloff, and W. C. Hagel, eds. (Wiley, New York, 1987), Ch. 3, p. 61.
D. N. Duhl, in Superalloys II, C. T. Sims, N. S. Stoloff, and W. C. Hagel, eds. (Wiley, New York, 1987), Ch. 7, p. 189.
N. S. Stoloff and C. T. Sims, in Superalloys II, C. T. Sims, N. S. Stoloff, and W. C. Hagel, eds. (Wiley, New York, 1987), Ch. 19, p. 519.
J. H. Wood and E. Goldman, in Superalloys II, C. T. Sims, N. S. Stoloff, and W. C. Hagel, eds. (Wiley, New York, 1987), Ch. 13, p. 359.
M. E. El Dahshan, D. P. Whittle, and J. Stringer, Cobalt 4, 86 (1974).
M. E. El Dahshan, D. P. Whittle, and J. Stringer, Oxid. Met. 9, 45 (1975).
M. E. El Dahshan, D. P. Whittle, and J. Stringer, Corros. Sci. 16, 77 (1978).
F. H. Stott, G. C. Wood, and J. G. Fountain, Oxid. Met. 14, 31 (1980).
S. Espevik, R. A. Rapp, P. L. Daniel, and J. P. Hirth, Oxid. Met. 14, 85 (1980).
F. H. Stott, G. C. Wood, and J. G. Fountain, Oxid. Met. 14, 135 (1980).
T. Hodgkiess, G. C. Wood, D. P. Whittle, and B. D. Bastow, Oxid. Met. 14, 263 (1980).
S. Espevik, R. A. Rapp, P. L. Daniel, and J. P. Hirth, Oxid. Met. 20, 37 (1983).
F. Gesmundo, P. Nanni, and D. P. Whittle, J. Electrochem. Soc. 127, 1773 (1980).
F. Viani, P. Nanni, and F. Gesmundo, Oxid. Met. 19, 53 (1983).
F. Gesmundo, P. Nanni, and F. Viani, Reactivity of Solids, P. Barret and L. C. Dufour, eds. (Materials Science Monographs, Elsevier, Amsterdam, 1985), Vol. 28 A, p. 175.
D. L. Douglass, in Corrosion & Particle Erosion at High Temperatures, V. Srivanasan and K. Vedula, eds. (TMS, Warrendale, 1989), p. 3.
Y. Niu, F. Gesmundo, and F. Viani, Corros. Sci. 36, 423 (1994).
Y. Niu, F. Gesmundo, and F. Viani, Corros. Sci. 36, 853 (1994).
Y. Niu, F. Gesmundo, and F. Viani, Corros. Sci. 36, 883 (1994).
Y. Niu, F. Gesmundo, and F. Viani, Corros. Sci. 36, 1885 (1994).
Y. Niu, F. Gesmundo, and F. Viani, Corros. Sci. 36, 1973 (1994).
Y. Niu, F. Gesmundo, and F. Viani, Corros. Sci. 37, 169 (1995).
Y. Niu, F. Gesmundo, F. Viani, F. C. Rizzo, and J. F. Oliveira, Corros. Sci. 37, 2043 (1995).
M. J. Monteiro, Y. Niu, F. C. Rizzo, and F. Gesmundo, Oxid. Met. 43, 527 (1995).
M. Castro Rebello, Y. Niu, F. C. Rizzo, and F. Gesmundo, Oxid. Met, 43, 561 (1995).
J. F. Oliveira, Y. Niu, F. C. Rizzo, and F. Gesmundo, Oxid. Met. 44, 399 (1995).
Y. Niu, F. C. Rizzo, F. Gesmundo, M. Castro Rebello, and F. Viani, Werkst. Korros. 46, 223 (1995).
Y. Niu, F. Gesmundo, F. Viani, F. C. Rizzo, and M. J. Monteiro, Corros. Sci. 38, 193 (1996).
J. Stringer, P. S. Corkish, and D. P. Whittle, in Stress Effects on the Oxidation of Metals, J. V. Catchard, ed. (The Met. Soc. of AIME, New York, 1975), p. 75.
G. Wang, B. Gleeson, and D. L. Douglass, Oxid. Met.35, 343 (1991).
F. Gesmundo, F. Viani, Y. Niu, and D. L. Douglass, Oxid. Met. 39, 197 (1993).
F. Gesmundo, Y. Niu, F. Viani, and D. L. Douglass, Oxid. Met. 40, 373 (1993).
F. Gesmundo, F. Viani, and Y. Niu, Oxid. Met. 42, 409 (1994)
F. Gesmundo, F. Viani, Y. Niu, and D. L. Douglass, Oxid. Met. 42, 465 (1994).
F. Gesmundo, Y. Niu, and F. Viani, Oxid. Met. 43, 379 (1995).
F. Gesmundo and B. Gleeson, Oxid. Met. 44, 211 (1995).
F. Gesmundo, F. Viani, and Y. Niu, Oxid. Met. 45, 51 (1996).
T. B. Massalski, Binary Alloys Phase Diagrams (ASM International, Materials Park, Ohio, 1990), Vol. II.
P. Nanni and F. Gesmundo, Corrosion 36, 119 (1980).
J. Paidassi, in L'Oxydation des Métaux, J. Bénard, ed. (Gauthiers-Villars, Paris, 1964), Vol. II, p. 13.
F. Gesmundo, C. De Asmundis, and S. Merlo, Werkst. u. Korros. 30, 114 (1979).
R. A. Swalin, Thermodynamic s of Solids, J. Wiley & Sons, New York (1972).
E. M. Levin, C. R. Robbins, and H. F. McMurdie, Phase Diagrams for Ceramists, 1969 Supplement, The American Ceramic Soc., Columbus (1969), pp. 30–31.
C. Wagner, J. Electrochem. Soc. 99, 369 (1952).
C. Wagner, Z. Elektrochem. 63, 772 (1959).
R. A. Rapp, Corrosion 21, 382 (1965).
F. Gesmundo, F. Viani, and Y. Niu, Oxid. Met. 45, 51 (1996).
F. Gesmundo and F. Viani, Oxid. Met. 25, 269 (1986).
M. L. Narula, V. B. Tare, and W. L. Worrell, Met. Trans. B 14B, 673 (1983).
Diffusion and Defect Data, N. 1, p. 278 (1971).
R. A. Rapp, Acta Met. 9, 730 (1961).
C. Wagner, Corros. Sci. 8, 889 (1968).
W. W. Smeltzer and D. P. Whittle, J. Electrochem. Soc. 125, 1116 (1978).
F. Gesmundo, P. Castello, and F. Viani, Oxid. Met. 46, 381 (1966).
C. Wagner, J. Electrochem. Soc. 103, 571 (1956).
P. Kofstad, Nonstoichiome try, Diffusion and Electrical Conductivity in Binary Metal Oxides (Wiley-Interscience, New York, 1972).
D. L. Douglass, Oxid. Met. 44, 81 (1995).
F. Viani and F. Gesmundo, Corros. Sci. 20, 541 (1980).
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Gesmundo, F., Niu, Y., Oquab, D. et al. The Air Oxidation of Two-Phase Fe-Cu Alloys at 600-800°C. Oxidation of Metals 49, 115–146 (1998). https://doi.org/10.1023/A:1018861804007
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DOI: https://doi.org/10.1023/A:1018861804007