Summary
The reaction of previously reported RhI and IrI cationic complexes towards carbon monoxide and triphenylphosphine has been studied. Carbonyl rhodium(I) mixed complexes of the formulae [Rh(CO)L2(PPh3)]ClO4, (L=tetrahydrothiophene(tht), trimethylene sulfide(tms), SMe2, or SEt2), [(CO)(PPh3)Rh{μ-(L-L)}2Rh(PPh3)(CO)](ClO4)2 (L-L= 2,2,7,7-tetramethyl-3,6-dithiaoctane (tmdto), (MeS)2(CH2)3 (dth), or 1,4-dithiacyclohexane (dt), [Rh(CO)L(PPh3)2]ClO4 (L= tht, tms, SMe2, or SEt2), and carbonyl iridium(I) complexes of the formulae [Ir(CO)2(COD)(PPh3)]ClO4, [Ir(CO)(COD)(PPh3)2]ClO4, [(CO)(COD)(PPh3) Ir{μ-(L-L)} Ir(PPh3)(COD)(CO)](ClO4)2 (L-L = tmdto or dt), [(CO)2 (PPh3)Ir(μ-tmdto)Ir(PPh3)(CO)2](ClO4)2, [(CO)2(PPh3) Ir(μ-dt)2Ir(PPh3)(CO)2](ClO4)2, were prepared by different synthetic methods.
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References
M. A. Garralda and L. A. Oro,Transition Met. Chem., 5, 65 (1980).
J. V. Heras, E. Pinilla and L. A. Oro,Transition Met. Chem., 6, 45 (1981).
C. Claver, E. Marco, L. A. Oro, M. Royo and E. Pastor,Transition Met. Chem., 7, 246 (1982).
R. Uson, L. A. Oro, M. A. Ciriano, F. Lahoz and M. C. Bello,J. Organometal. Chem., 234, 205 (1982).
R. Uson, L. A. Oro, M. A. Ciriano, F. Lahoz,J. Organometal. Chem., 240, 429 (1982).
C. Claver, J. C. Rodriguez and A. Ruiz,Transition Met. Chem., (in press).
A. Ruiz, C. Claver and J. C. Rodriguez,J. Chem. Soc., Dalton Trans., submitted for publication.
A. Tiripicchio, M. Tiripicchio Camellini, C. Claver, A. Ruiz and L. A. Oro,J. Organometal. Chem., 251, 369 (1983).
C. Claver, J. C. Rodriguez and A. Ruiz,J. Organometal. Chem., 251, 369 (1983).
D. F. Steele, T. A. Stephenson,J. Chem. Soc., Dalton Trans., 2161 (1972).
A. J. Deeming and I. P. Rothwell,J. Chem. Soc., Dalton Trans., 1259 (1980).
R. D. Feltham and R. G. Hayter,J. Chem. Soc., 4587 (1964).
J. A. Davies, F. R. Hartley and S. G. Murray,Inorg. Chim. Acta, 43, 69 (1980).
P. S. Pregrosin and R. W. Kunz,NMR Basic Principles and Progress, Springer Verlag Berlin,16, 110 (1979).
D. W. Meek, and T. J. Mazanec,Acc. Chem. Res., 14, 266 (1981).
R. Uson, J. Gimeno, J. Fornies and F. Martinez,Inorg. Chim. Acta, 50, 173 (1981).
D. Montauzon, R. Poilblanc,Inorg. Synth., 20, 137 (1980).
P. Kalck and R. Poilblanc,Inorg. Chem., 14, 2779 (1975).
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Rodriguez, J.C., Ruiz, A. & Claver, C. Carbonyl cationic rhodium(I) and iridium(I) complexes with sulphur donor and triphenylphosphine ligands. Transition Met Chem 9, 237–241 (1984). https://doi.org/10.1007/BF01227127
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DOI: https://doi.org/10.1007/BF01227127