Abstract
The synthesis of individual Ni-, Mn-, and Na-containing cage-like organometallosiloxanes has been performed. A possible mechanism of the formation of stable metallosiloxane frameworksvia a transition complex and coordinately bound ion pairs has been proposed. Both monometallic and bimetallic organometallosiloxanes containing only atoms of a transition metal or two different (transition and non-transition) metals, respectively, have been prepared.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 957–961, May, 1993.
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Zhdanov, A.A., Shchegolikhina, O.I. & Molodtsova, Y.A. Peculiarities of the synthesis of cage-like metallosiloxanes. Russ Chem Bull 42, 917–922 (1993). https://doi.org/10.1007/BF00698961
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DOI: https://doi.org/10.1007/BF00698961