Summary
The reaction of S2Cl2 with alcohols yields products, the reversed-phase liquid chromatograms of which are similar to those of dialkyl-polysulphides RSnR, i.e., they represent homologous series. Four of the products were identified via GC-MS as 1,ω-di(alkoxy)-polysulphides having the general structure ROSnOR. Retention contributions of alkyl groups R and sulphur atoms in the −Sn — chain are not much different from values observed with polysulphides. The effect of oxygen, however, is only about −100 index units per O atom, while in dialkyl ethers values of −500 units have been reported.
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Singer, E., Möckel, H.J. RPLC retention of 1,ω-di(alkoxy)-polysulphides. Chromatographia 27, 27–30 (1989). https://doi.org/10.1007/BF02290400
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DOI: https://doi.org/10.1007/BF02290400