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CD4, SF6 and CF4 have Raman transitions in near coincidence with the 9P(36) pump line and hence could possibly have resonantly de-excited CH3OH.
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Mansfield, D.K., Horlbeck, E., Bennett, C.L. et al. Enhanced, high power operation of the 119μm line of optically pumped CH3OH. Int J Infrared Milli Waves 6, 867–876 (1985). https://doi.org/10.1007/BF01013294
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DOI: https://doi.org/10.1007/BF01013294