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Preparation and conductivity of dithiolene complex Langmuir–Blodgett films

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Abstract

The d.c. electrical property of the dithiolene complex, or bis(4-diethyannodithiobenzil)nickel (BDN) and stearyl alcohol (SA) mixed Langmuir–Blodgett films was investigated. The conductivity of the LB films as a function of the thickness of the films and the ratio of BDN:SA as well as the current versus voltage (I–V) characteristics have been measured. The conductivity of the LB films is about 3.5 x 10-10 S cm-1 which is less than the bulk conductivity of BDN, and the conductivity of the LB films is strongly influenced by BDN concentration. The I–V property of Al-LB films is governed by the thickness of oxide layers at the LB films with Al electrodes after Auger depth profiling analysis.

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Yang, DQ., Wang, RF., Guo, Y. et al. Preparation and conductivity of dithiolene complex Langmuir–Blodgett films. Journal of Materials Science: Materials in Electronics 10, 557–561 (1999). https://doi.org/10.1023/A:1008904924688

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