Abstract
The choice of a sampling design forassessing soil contamination is a key issue. The leveland spatial pattern of contaminants needs to be takeninto account by those buying, selling or developingsuch land. This paper evaluates sampling design andsize in order to provide satisfactory and efficientestimates of contamination levels. Geostatisticalmethods are used to quantify the spatial dependence ofheavy metals. Semivariance is calculated forlog-transformed data to minimise the effects ofextreme outliers. Several models at different samplingstages are presented for characterising spatialpattern of heavy metals at the investigated site.Variogram models are calculated for a range of samplesizes. The results are assessed by a jack-knifingtechnique and then used for block kriging. The overallconclusion is that a sample size of 50 to 60 isoptimal for characterising variability incontamination levels at an old industrial site of 6.25 ha.
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References
Alloway, B. J.: 1995, Heavy Metals in Soils, London Glasgow, Blackie Academic and Professional, 368 pp.
Burgess, T. M. and Webster, R.: 1984, Journal of Soil Science 35, 641.
Burrough, P. A.: 1986, Principles of Geographical Information Systems for Land Resources Assessment, Oxford University Press, 194 pp.
Burrough, P. A.: 1993, Soils and Fertilisers 56, 529.
Burrough, P. A., Bouma, J. and Yates, S. R.: 1994, Geoderma 62, 311.
Campardella, C. A. and Moorman, T. B.: 1994, Soil Science Society of America Journal 58, 1501.
Cairney, T. and Hobson, D. M. (eds): 1998, Contaminated Land: Problems and Solutions, E. and F. N. Spon, London.
D'Agostino, R. B., Belander, A. and D'Agostino Jr., R. B.: 1990, The American Statistician 44, 316.
Davidson, D. A. and Watson, A. I.: 1995, Earth Surface Processes and Landforms 20, 219.
De Gruijter, J. J. and Ter Braak, C. J. F.: 1990, Mathematical Geology 22, 407.
Domburg, P. and De Gruijter, J. J.: 1992,‘A Framework of Concepts for Soil Survey Using Probability Sampling’ The Winand Staring Centre Report 55, Wageningen, 32 pp.
Domburg, P., De Gruijter, J. J. and Brus, D. J.: 1994, Geoderma 62, 151.
Domburg, P., De Gruijter, J. J. and Van Beek, P.: 1997, Geoderma 75, 183.
Efron, B. and Gong, G.: 1983, The American Statistician 37, 36.
GAMMA DESIGN SOFTWARE: 1992, GS+ Professional Geostatistics for the PC, Plainwell, Michigan, 42 pp.
Gaston, L., Nkeidi-Kizza, P., Sawka, G. and Rao, P. S. C.: 1990, Soil Science Society America Journal 54, 527.
Haan, C. T.: 1977, Statistical Methods in Hydrology, Iowa State University Press. Ames, Iowa, 305 pp.
ICRL: 1987, Interdepartmental Committee on the Development of Contaminated Land. Guidance on the Assessment and Redevelopment of Contaminated Land, Scotland, 18 pp.
McBratney, A. B. and Webster, R.: 1986, Journal of Soil Science 37, 617.
Nortcliff, S.: 1978, Journal of Soil Science 29, 403.
Oliver, M. A. and Webster, R.: 1991, Soil Use and Management 7, 206.
Parkin, T. B., Starr, J. L. and Meisinger, J. L.: 1987, Soil Science Society America Journal 51, 1492.
Parkin, T. B.: 1993, Journal of Environmental Quality 22, 409.
Stein, A.: 1994, Geoderma 62, 202.
Trangmar, B. B., Yost, R. S. and Uehara, G.: 1985, Advances in Agronomy 38, 45–93.
Van Meirvenne, M. and Hofman, G.: 1991, Pedologie 51, 263.
Van Meirvenne, M., Pannier, J., Hofman, G. and Louwagie, G.: 1996, Soil Use and Management 12, 86.
Wade, S. D., Foster, I. D. L. and Baban, S. M. J.: 1996, Soil Use and Management 12, 95.
Webster, R.: 1985, Advances in Soil Science 3, 1.
Webster, R. and Oliver, M. A.: 1990, Statistical Methods in Soil and Land Resource Survey, Oxford University Press, Oxford, 316 pp.
Wilken, R. D., Forstner, U. and Knochel, A. (eds): 1995,‘Heavy Metals in the Environment’ in Proceedings of the International Conference, Vol. 2, pp. 38–46.
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Andronikov, S.V., Davidson, D.A. & Spiers, R.B. Variability in Contamination by Heavy Metals: Sampling Implications. Water, Air, & Soil Pollution 120, 29–45 (2000). https://doi.org/10.1023/A:1005261522465
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DOI: https://doi.org/10.1023/A:1005261522465