Microstructural evolution of potassium titanate whiskers during the synthesis by the calcination and slow-cooling method

Abstract

K₂Ti₆O₁₃ whisker was synthesized by the calcination and slow-cooling method, and the microstructural evolution of whiskers, and the relations between the phase and the layer structure, were investigated. The amount of K₂O in the starting powder mixture played a key role in forming a layer structure, which can be obtained by addition of excess K₂O. During calcination, rod-like K₂Ti₆O₁₃ particles with a layer structure were formed by reactions between K₂O and TiO₂. During slow-cooling, the K₂O-rich liquid phase reacted with K₂Ti₆O₁₃ layers near the boundary and k₂Ti₄O₉ whiskers were produced by the splitting of layers within rod-like k₂T₆O₁₃ particles. k₂Ti₄O₉ whiskers were reformed into k₂T₆O₁₃ whiskers by treatment in boiling water and reheating. The synthesized k₂T₆O₁₃ whiskers had a clean surface and a length exceeding 100 μm.