Abstract
For the first time the adducts of 2-amino-I-methylbenzimidazole (L) with cobalt, copper, and zinc chelates based on 2-tosylamino-N-salicylideneaniline were electrochemically synthesized, and the properties and structures of these adducts were studied. According to the IR and1H NMR spectral data on the adducts obtained and X-ray structural analysis of the copper complex, the adducts of composition mL · ML' · nH2O (m = 1 or 2; n = 0, 1, or 2) contain the L moiety bonded to the metal atom through the pyridine-type N atom of the imidazole ring.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 2093–2097, August, 1996.
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Garnovskii, D.A., Sousa, A., Antsyskkina, A.S. et al. Electrosynthesis and studies of adducts of 2-amino-1-methylbenzimidazole with metal chelates based on 2-tosylamino-N-salicylideneaniline. Russ Chem Bull 45, 1988–1992 (1996). https://doi.org/10.1007/BF01457793
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DOI: https://doi.org/10.1007/BF01457793