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Synthesis and structure determination of a 2D open-framework zincophosphate templated by cyclohexylamine molecules

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Abstract

The synthesis and crystal structure of a new bidimensional zincophosphate (ZnPO) are reported. Zn2(HPO4)2Cl2·2NC6H14 crystallizes in the monoclinic space group P21/a (n°14) with a = 8.830(3) Å, b = 9.278(3) Å, c = 26.950(9) Å, β = 90.74(3)°, V = 2207.7(1) Å3 and Z = 4. This new material consists of a 2D open-framework of corner sharing ZnO3Cl and PO3OH tetrahedra alternating with planes of protonated cyclohexylamine molecules (NC6H14)+. The organic molecules are interconnected to the framework through hydrogen bonds.

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Authors and Affiliations

  1. Département de Chimie, Faculté des Sciences de Tunis, 1060, Campus Universitaire, Tunis—Tunisie

    Basma Trojette, Amen Allah Hajem, Ahmed Driss & Tahar Jouini

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  1. Basma Trojette
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  2. Amen Allah Hajem
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  3. Ahmed Driss
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  4. Tahar Jouini
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Trojette, B., Hajem, A.A., Driss, A. et al. Synthesis and structure determination of a 2D open-framework zincophosphate templated by cyclohexylamine molecules. Journal of Chemical Crystallography 28, 339–342 (1998). https://doi.org/10.1023/A:1022403907037

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