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  • Articles  (28)
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  • Articles  (28)
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  • 1
    Publication Date: 2021-10-27
    Description: The effect of N fertilization on residue decomposition has been studied extensively; however, contrasting results reflect differences in residue quality, the form of N applied, and the type of soil studied. A 60 d laboratory incubation experiment was conducted to ascertain the effect of synthetic N addition on the decomposition of two corn (Zea mays L.) stover mixtures differing in C:N ratio by continuous monitoring of CO2 emissions and periodic measurement of microbial biomass and enzyme activities involved in C and N cycling. Cumulative CO2 production was greater for the high than low N residue treatment, and was significantly increased by the addition of exogenous N. The latter effect was prominent during the first month of incubation, whereas N-treated soils produced less CO2 in the second month, as would be expected due to more rapid substrate depletion from microbial C utilization previously enhanced by greater N availability. The stimulatory effect of exogenous N was verified with respect to active biomass, microbial biomass C and N, and cellulase and protease activities, all of which were significantly correlated with cumulative CO2 production. Intensive N fertilization in modern corn production increases the input of residues but is not conducive to soil C sequestration.
    Electronic ISSN: 2504-3129
    Topics: Chemistry and Pharmacology
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  • 2
    Publication Date: 2021-09-02
    Description: Economic use of organic and inorganic fertilizers following their availability is necessary for livestock-based Nepalese farming systems. However, how best to integrate these fertilizers in an appropriate manner is not yet clear. Thus, this study was conducted in the horticulture farm of the Agriculture and Forestry University (AFU), Rampur, Chitwan, Nepal from November 2018 to February 2019 to evaluate the effect of organic and inorganic sources of nitrogen (N) on growth, yield, and quality of beetroot (Beta vulgaris L.) varieties. The experiment was laid out in a two factorial randomized complete block design with four replications consisting of two beetroot varieties, i.e., Madhur and Ruby Red, and five N source combinations, i.e., N1: 100% poultry manure (PM), N2: 50% PM + 50% urea, N3: 100% farmyard manure (FYM), N4: 50% FYM + 50% urea, and N5: 100% urea (120:80:40 kg NPK ha−1). Results of this study indicated a significant impact of N sources and varieties on the assessed parameters. During harvest, a significantly higher plant height (41.84 cm), number of leaves per plant (14.68), leaf length (34.56 cm), leaf width (11.38 cm), and beetroot diameter (72.15 mm) were observed in the N2 treatment. Likewise, higher economic (49.78 t ha−1) and biological yields (78.69 t ha−1) were also recorded in the N2 compared to other N sources. Out of the two varieties, the Madhur variety was significantly better in most growth and yield parameters. Similarly, the Madhur variety showed a significantly higher economic (44.49 t ha−1) and biological yields (69.79 t ha−1) compared to the Ruby Red variety. However, the physiological weight loss was higher in the Ruby Red variety. Therefore, the current study suggests that an integration of poultry manure along with the combination of N fertilizer and the Madhur variety is the best combination for quality beetroot production in the Terai region of Nepal.
    Electronic ISSN: 2504-3129
    Topics: Chemistry and Pharmacology
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  • 3
    Publication Date: 2021-09-01
    Description: The optimum dose of fertilizers for crops varies with soil, agro-ecology, and crop management practices. Optimizing application dose is critical to reduce nutrient loss to the environment and increase nitrogen use efficiency (NUE), crop yields, and economic return to farmers. An experiment was conducted to determine the optimum N dose for increasing maize (Zea mays L. cv, Manakamana-3) yield, NUE, and farm profits under rainfed conditions. Five levels of N (0, 60, 120, 180, and 240 kg ha−1), and a non-fertilized treatment were tested in a randomized complete block design with three replications. Effects of each treatment on yield and yield attributing traits, plant lodging and Sterility (plants with no cob or grain formation), NUE, and stay green trait of maize were recorded. Application of N above 120 kg ha−1 (N120) did not have any significant effects on yield and yield components. Nitrogen, at N120 and above, produced highly fertile plants (though sterility slightly increased at N180 and N240), higher N uptake, and lower dead leaf area (18–27%). N120 produced the highest agronomic; yield increase per unit of N application (AEN—26.89 kg grain kg−1 N) and physiological efficiency of N (PEN—42.67 kg grain kg−1 N uptake), and net benefit (USD 500.43). Considering agronomic, economic, and NUE factors, an N dose of 120 kg ha−1 was found optimum for the cultivation of rainfed maize (Manakamana-3) under sandy loam soil.
    Electronic ISSN: 2504-3129
    Topics: Chemistry and Pharmacology
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  • 4
    Publication Date: 2021-08-26
    Description: Manure is a common source of nitrogen (N) in organic farming. However, manure is not always easily available, while the maximum N amount added as animal manure in organic agriculture is restricted by EU regulations. The present study was designed to test whether green manuring with a warm-season legume and intercropping with a cold-season legume can substitute farm-yard manure or compost as N sources in organic greenhouse tomato crops. To test this hypothesis, a winter-spring (WS) tomato crop was installed in February following the incorporation of crop residues of an autumn-winter (AW) tomato crop intercropped with faba bean, which had been fertilized with cowpea residues as green manure. This treatment, henceforth termed legume treatment (LT), was compared with the use of compost or manure as an N fertilization source in both tomato crops. In addition, a combination of compost and LT was also used as a fourth treatment. The results showed that green manuring with legumes and particularly cowpea can contribute a significant amount of N to the following organic tomato crop, through the biological fixation process. Nevertheless, legumes as green manure, or compost, or their combination cannot efficiently replace farmyard manure as an N fertilization source. Compost exhibited a slow mineralization course.
    Electronic ISSN: 2504-3129
    Topics: Chemistry and Pharmacology
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  • 5
    Publication Date: 2021-04-13
    Description: Temporal variability of NO2 concentrations measured by 28 Envirowatch E-MOTEs, 13 AQMesh pods, and eight reference sensors (five run by Sheffield City Council and three run by the Department for Environment, Food and Rural Affairs (DEFRA)) was analysed at different time scales (e.g., annual, weekly and diurnal cycles). Density plots and time variation plots were used to compare the distributions and temporal variability of NO2 concentrations. Long-term trends, both adjusted and non-adjusted, showed significant reductions in NO2 concentrations. At the Tinsley site, the non-adjusted trend was −0.94 (−1.12, −0.78) µgm−3/year, whereas the adjusted trend was −0.95 (−1.04, −0.86) µgm−3/year. At Devonshire Green, the non-adjusted trend was −1.21 (−1.91, −0.41) µgm−3/year and the adjusted trend was −1.26 (−1.57, −0.83) µgm−3/year. Furthermore, NO2 concentrations were analysed employing univariate linear and nonlinear time series models and their performance was compared with a more advanced time series model using two exogenous variables (NO and O3). For this purpose, time series data of NO, O3 and NO2 were obtained from a reference site in Sheffield, which were more accurate than the measurements from low-cost sensors and, therefore, more suitable for training and testing the model. In this article, the three main steps used for model development are discussed: (i) model specification for choosing appropriate values for p, d and q, (ii) model fitting (parameters estimation), and (iii) model diagnostic (testing the goodness of fit). The linear auto-regressive integrated moving average (ARIMA) performed better than the nonlinear counterpart; however, its performance in predicting NO2 concentration was inferior to ARIMA with exogenous variables (ARIMAX). Using cross-validation ARIMAX demonstrated strong association with the measured concentrations, with a correlation coefficient of 0.84 and RMSE of 9.90. ARIMAX can be used as an early warning tool for predicting potential pollution episodes in order to be proactive in adopting precautionary measures.
    Electronic ISSN: 2504-3129
    Topics: Chemistry and Pharmacology
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  • 6
    Publication Date: 2021-04-13
    Description: Nitrification inhibitors (NIs) can be used to reduce both NO3−-N leaching and N2O-N emissions. However, the comparative efficacies of NIs can be strongly affected by soil type. Therefore, the efficacies of four nitrification inhibitors (dicyandiamide (DCD), 3, 4-dimethylpyrazole phosphate (DMPP), nitrogenous mineral fertilizers containing the DMPP ammonium stabilizer (ENTEC) and active ingredients: 3.00–3.25% 1, 2, 4-triazole and 1.50–1.65% 3-methylpyrazole (PIADIN)) were investigated in three different textured N-fertilized (0.5 g NH4+-N kg−1 soil) soils of Schleswig-Holstein, namely, Marsch (clayey), Östliches Hügelland (loamy) and Geest (sandy) under a controlled environment. Total CO2-C and N2O-N emissions were significantly higher from Marsch than Östliches Hügelland and Geest. In Marsch, DMPP showed the highest inhibitory effect on CO2-C emission (50%), followed by PIADIN (32%) and ENTEC (16%). In Östliches Hügelland, DCD and PIADIN showed the highest and equal inhibitory effect on CO2-C emission (73%), followed by DMPP (64%) and ENTEC (36%). In Marsch and Östliches Hügelland, DCD showed the stronger inhibitory effect on N2O-N emission (86% and 47%) than DMPP (56% and 30%) and PIADIN (54% and 16%). In Geest, DMPP was more effective in reducing N2O-N emission (88%) than PIADIN (70%) and DCD (33%). Thus, it can be concluded that DCD is a better NI for clay and loamy soils, while DMPP and PIADIN are better for sandy soils to inhibit soil nitrification and gaseous emissions.
    Electronic ISSN: 2504-3129
    Topics: Chemistry and Pharmacology
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  • 7
    Publication Date: 2021-04-10
    Description: External nitrogen (N) inputs originating from human activities act as essential nutrients accumulation in aquatic ecosystems or it is exported elsewhere, where the assimilation capacity is surpassed. This research presents a multi-annual case study of the dissolved inorganic nitrogen (DIN) in an urban river in Ontario (Canada), assessed changes in N downstream of the largest wastewater treatment plant (WTP) in the watershed. Changes in the DIN effluent discharge, in-river concentrations and loads were observed comparing the intra- and inter-annual variability (2010–2013) before, during and after WTP upgrades. These upgrades reduced the ammonium concentration in the river from 0.44 to 0.11 mg N-NH4+/L (year average), but the N load in the effluent increased. In the river, nitrate and ammonium concentrations responded to seasonal variability, being higher during the low temperature (〉10 °C) and high flow seasons (spring and spring melt). Among years, changes in the DIN concentration are likely controlled by the effluent to river dilution ratio, which variability resides on the differences in river discharge between years. This suggest that the increasing trend in the DIN concentration and loads are the result of agricultural and urban additions, together with reduced N assimilation, in addition to N loads responding to variable river discharge. Finally, we propose monitoring both concentrations and loads, as they provide answers to different questions for regulatory agencies and water managers, allowing tailored strategies for different purposes, objectives and users.
    Electronic ISSN: 2504-3129
    Topics: Chemistry and Pharmacology
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  • 8
    Publication Date: 2021-04-01
    Description: Catch crops are an effective method for reducing nitrogen (N) leaching in agriculture, but the mineralization of incorporated catch crop residue N is difficult to predict and model. We conducted a five-month incubation experiment using fresh residue from three catch crops (hairy vetch, fodder radish and ryegrass) with three temperature treatments (2 °C, 15 °C and 2–15 °C variable temperature) and two termination methods (glyphosate and untreated). Mineral N (ammonium and nitrate) in soil was quantified at 0, 1, 2, 4, 8 and 20 weeks of incubation. Ammonium accumulation from residue decomposition showed a lag at low and variable temperature, but subsequent nitrification of the ammonium did not. Mineral N accumulation over time changed from exponential to sigmoidal mode at low and variable temperature. Incubation temperature significantly affected mineralization rates in a first-order kinetics (FOK) model, while plant type and termination method did not. Plant type alone had a significant effect on the final mineralized fraction of added catch crop N. FOK models modified to accommodate an initial lag were fitted to the incubation results and produced better goodness-of-fit statistics than simple FOK. We suggest that initial lags in residue decomposition should be investigated for the benefit of mineralization predictions in cropping models.
    Electronic ISSN: 2504-3129
    Topics: Chemistry and Pharmacology
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  • 9
    Publication Date: 2021-04-01
    Description: Soybean is one of the most traded products. Naturally, soy fixes nitrogen through biological symbiosis. Its cultivation transforms natural inert atomic nitrogen into its reactive forms. The advancement of soybean can have environmental impacts, both locally and globally. This study estimated nitrogen flows and their use efficiency in the Brazilian soybean production chain applying material flow analysis. We innovate proposing a new indicator to estimate the “cascade effect of nitrogen” in a framework of 12 years (2007 to 2019). We hypothesized that it is capable to show accumulated nitrogen emissions through the chain. Besides, the method can show the main sources of nitrogen to the environment. The biological fixation was the largest entry. The efficiency in the use of nitrogen was 81% for grain production, and the nitrogen cascade indicator, which represents the ratio of the nitrogen emission in the environment to the total nitrogen available in the product, was only 5.2% in the soybean meal production chain for the year of 2019, with a clear trend of increasing during the period. Thus, Brazil contributes significantly to global nitrogen emissions in the environment since the country is an important producer and player in the world market.
    Electronic ISSN: 2504-3129
    Topics: Chemistry and Pharmacology
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  • 10
    Publication Date: 2021-03-18
    Description: Nitrous oxide (N2O) is one of the main greenhouse gases and its emissions from vegetable production systems have brought a sustainability challenge. The objective of this study was to evaluate the potential of reducing N2O emissions from silt loam soil by mixing nitrogen (N)-rich broccoli (Brassica oleracea var. italica) residue with wheat straw or water-washed wheat straw. An experiment was conducted in randomized complete block design with five treatments; unamended or control (BS), wheat straw (+S), broccoli residue (+CR), broccoli residue and wheat straw (+CR+S) and broccoli residue and washed wheat straw (+CR+Sw) and was replicated four times. The +CR and +S were added at the rate of 3.5 kg and 2.0 kg fresh matter m−2 and their mixtures, +CR+S and +CR+Sw, were incorporated in 3.5 kg of silt loam soil at 60% water-filled pore space (WFPS) and packed in soil microcosms. Nitrous oxide emissions were measured once a day during the 14-day of study period. Daily fluxes of N2O were found to be reduced on +CR+W and +CR+Sw when compared to single-amended +CR treatment. Similarly, N2O fluxes on +CR+Sw (2772 µg N m−2 h−1) were significantly lower than +CR+S (3606 µg N m−2 h−1) soon after the amendment but did not vary significantly thereafter. Moreover, the amendment mixture, +CR+S and +Cr+Sw, resulted in lower net N2O emissions by 73.3% and 74.2%, respectively, relative to +CR treatment. While the results clearly suggest that the +CR+S or +CR+Sw reduced N2O emissions, it necessitated further studies, possibly by increasing the frequency of sampling to clarify if washed wheat straw would further mitigate N2O emissions from the vegetable production system.
    Electronic ISSN: 2504-3129
    Topics: Chemistry and Pharmacology
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