ALBERT

Description: This work focused on the recycling of WEEE plastic waste as a partial substitute for aggregate in light mortars. The plastic mix, provided by the IREN group, was used as a replacement of aggregate in 15, 30, 45, 60, 75, and 90%vol in mortars. Worsening of the mechanical performance of around 50% was detected already at only 15%vol of mineral aggregate substituted with plastic waste. The explanation of this phenomenon was found in both the scarce mechanical properties of the used plastic and in the poor adhesion between matrix and plastics that resulted in extra-porosity formation, as also demonstrated by comparing the results with several models in the literature. However, the use of plastic waste as a partial replacement of natural aggregate contributes to the preservation of natural resources and, in any case, does not limit the application of these materials in non-structural applications.

Description: Approximately 300 million tons of plastic waste is generated per year. The major portion of this plastic waste is landfilled, while part of it leaks into the environment. When plastic waste enters the terrestrial or aqueous environment, it can have negative impacts on ecosystems, human health, and wildlife. Increasing the amount of plastic waste that is recycled will correspondingly reduce the amount of plastic waste that enters the environment. By educating the public and industry on plastic recycling, current recycling programs can be used more efficiently, and new programs can be created. Education material on plastic recycling is available through professional and industry associations, foundations with an environmental focus, university courses, and short courses offered with private companies. This review assembles and analyzes the current education material on plastic recycling that is available from these providers. The material compiled here can be used to gain insight into specific plastic recycling-related topics, to identify areas of recycling education that can be improved, and as a resource to help build university level courses. There is currently a dearth of plastic recycling courses offered at the university level. Educating more students on plastic recycling will equip them with the knowledge and skills to make informed decisions as consumers, and to implement plastic recycling systems at the professional level.

Description: The treatment of used vegetable oils (UVOs) with clays represents a pivotal step in their industrial recycling process as well as one of the most challenging topics for researchers. In particular, cheap, effective, and sustainable powders need to be explored in order to develop new processes which produce beneficial results in relation to economic and environmental aspects. In this context, five samples within commercial and waste vegetable oils were treated with two sodium- and calcium-based bentonites employing a low oil/bentonite ratio (0.15 wt%). The outcomes of the processes were monitored by FT-IR spectroscopy and compared with the data relative to the parent commercial edible oil. In particular, treatment of FT-IR data by multivariate statistical analysis allowed us to determine a chemical fingerprint characteristic of each sample. Important relationships between the overall chemical composition and the specific clay employed and the treatment time (2 or 4 h) were highlighted. Finally, N2 physisorption, TEM microscopy, and FT-IR analyses of the more efficient Na bentonite allowed us to characterize the material and thus to furnish all the information needed to set-up a general protocol for the partial regeneration of waste vegetable oil destined for further processing.

Description: High-shear melt conditioning (HSMC) technology was used for degassing and de-ironing of an aluminum alloy recovered from the Zorba cast fraction of the non-ferrous scrap from shredded end-of-life vehicles. The results showed that the recovery of aluminum alloys from the Zorba cast fraction was more than 80%. High-shear melt conditioning improved the degassing process during melt treatment in comparison with the adding of degassing tablets. The efficiency of the de-ironing process using HSMC increased by up to 24% after, increasing the Mn content to 0.8% in the melt. Adding Mn to Zorba melt enhanced the de-ironing process and eliminated the formation of β-AlFeSi intermetallic particles, which have a detrimental effect on both the mechanical and corrosion properties of the alloy.

Description: Construction waste (CW) is a prime contributor to the stream of total waste worldwide. One of the biggest challenges of the construction industry is to minimise CW and to develop practices of a more sustainable nature for its management and recycling in order to promote its transition towards a more effective circular economy. The implementation of these practices contributes towards mitigating the scarcity of natural resources and the environmental impact of CW. Thus, a preceding and essential step is the estimation of CW during building design, which will allow the adoption of measures for its early reduction and optimisation. For this purpose, Building Information Modelling (BIM) has become a useful methodology to predict waste during the early stages of design. There remains, however, a lack of instrumental development. Therefore, this study proposes a BIM-based method to estimate CW during building design by integrating a consolidated construction waste quantification model in three different BIM platforms. For its validation, the method is applied to the structural system of a Spanish residential building. The results provide evidence that the proposed method is vendor-neutral and enables the automatic identification and quantification of the waste generated by each building element during the design stage in multiple BIM platforms.

Description: The recycling of plastic waste is undergoing fast growth due to environmental, health and economic issues, and several blends of post-consumer and post-industrial polymeric materials have been characterized in recent years. However, most of these researches have focused on plastic containers and packaging, neglecting hard plastic waste. This study provides the first experimental characterization of different blends of hard plastic waste and virgin polypropylene in terms of melt index, differential scan calorimetry (DSC), thermogravimetric analysis (TGA), mechanical properties (tensile, impact and Shore hardness) and Vicat softening test. Compared to blends based on packaging plastic waste, significant differences were observed in terms of melt flow index (about 10 points higher for hard plastic waste). Mechanical properties, in particular yield strain, were instead quite similar (between 5 and 9%), despite a higher standard deviation being observed, up to 10%, probably due to incomplete homogenization. Results demonstrate that these worse performances could be mainly attributed to the presence of different additives, as well as to the presence of impurities or traces of other polymers, other than incomplete homogenization. On the other hand, acceptable results were obtained for selected blends; the optimal blending ratio was identified as 78% post-consumer waste and 22% post-industrial waste, meeting the requirement for injection molding and thermoforming.

Description: Toner waste is one of the major electronic waste materials posing serious environmental threat and health hazards. Globally, only about 20–30% of toner waste is recycled, while the remaining percentage is dumped in landfills. Recycling options are limited due to the desirably engineered durability of toners, ascribed to a complicated composition of chemicals, carbon black, and plastic particles, which in turn creates critical challenges in recycling. The World Health Organization has classified toner waste as class 2B carcinogen due to its potential health hazard. In this review, the existing challenges in toner waste recycling are discussed from the perspective of environmental, health, and feasibility aspects. In parallel, the challenges have been opening up alternative strategies to recycle toner wastes. Emerging trends in toner waste recycling include transformation of toner waste into value-added products, utilization as raw material for nanomaterial synthesis, generation of composite electrodes for power generation/storage devices, integration into construction materials, and development of microwave absorbing composites. Considering the enormous volume of toner waste generated globally every year, better recycling and transformation strategies are needed immediately. A circular economy could be established in the future by transforming the enormous toner waste into a resource for other applications. For an effective management of toner waste in the future, an integrated approach involving policies and legislations, infrastructure for collection and treatment, and financial planning among the stakeholders is needed in addition to technological innovations.

Description: Following the Fukushima Daiichi Nuclear Power Plant (FDNPP) accident caused by the 2011 Tōhoku earthquake and tsunami, radioactive caesium (r-Cs) was detected in the ash generated by municipal solid waste (MSW) incineration facilities in Fukushima Prefecture. This has led to concerns of r-Cs leaching and subsequent environmental contamination during recycling or landfill disposal. Therefore, it is crucial that the relevant authorities have a thorough understanding of r-Cs leaching behavior to establish suitable prevention methods. In this study, we collected r-Cs-contaminated fly and bottom ash (FA and BA) samples from five MSW incineration facilities in Fukushima Prefecture and conducted tests to clarify their basic physical properties and r-Cs leaching properties. We also examined the possibility of preventing r-Cs leaching by adding 5 wt% acid clay to the FA. FA had greater chloride content and r-Cs leaching rate than BA and was found to absorb moisture and deliquesce when stored under high-humidity conditions. However, the addition of acid clay effectively prevented r-Cs leaching upon contact with moisture. From the results, we propose some specific recommendations to counter the leaching of r-Cs from FA at MSW incineration facilities, which will limit r-Cs leaching during recycling or landfill processes.

Description: The depletion of natural resources and global warming have increased in severity globally. In the industrial field, assembly products, such as electronic products, should be disassembled for recycling and reuse to deal with these problems. Reuse and recycling can contribute to reducing GreenHouse Gas (GHG) emissions and less depletion of natural resources since GHG emissions for virgin material production can be saved using reused components and recycled materials. However, each component of selling revenue and material-based GHG emissions depends on the country because of the different energy mixes of electrical power. Moreover, each collected component embedded in End-of-Life (EOL) products needs to be selected as a life cycle option based on its remaining life. The purpose of this study is to decide life cycle options such as reuse, recycling, and disposal of each component environmentally-friendly and economically in Korea and Japanese cases for computers. Firstly, selecting the life cycle option for each component was formulated by 0–1 integer programming with ε constraints. Next, GHG emissions, profits, and costs in Korea and Japan were estimated and analyzed for each component. Finally, Korean and Japanese cases were analyzed to obtain an economic value in the same material-based GHG saving rate with each component’s life cycle option selection by comparing each EOL product data. In the experiments, GHG recovery efficiency was higher in Japan 43 [g/Yen] than one in Korea 28 [g/Yen]. Therefore, it was better to retrieve and reutilize the components in Korea. However, if the maximum GHG recovery efficiency is desired, Japan is a better option.

Description: In this work, the application of Short-Wave Infrared (SWIR: 1000–2500 nm) spectroscopy was evaluated to identify plastic waste containing brominated flame retardants (BFRs) using two different technologies: a portable spectroradiometer, providing spectra of single spots, and a hyperspectral imaging (HSI) platform, acquiring spectral images. X-ray Fluorescence (XRF) analysis was preliminarily performed on plastic scraps to analyze their bromine content. Chemometric methods were then applied to identify brominated plastics and polymer types. Principal Component Analysis (PCA) was carried out to explore collected data and define the best preprocessing strategies, followed by Partial Least Squares—Discriminant Analysis (PLS-DA), used as a classification method. Plastic fragments were classified into “High Br content” (Br 〉 2000 mg/kg) and “Low Br content” (Br 〈 2000 mg/kg). The identified polymers were acrylonitrile butadiene styrene (ABS) and polystyrene (PS). Correct recognition of 89–90%, independently from the applied technique, was achieved for brominated plastics, whereas a correct recognition ranging from 81 to 89% for polymer type was reached. The study demonstrated as a systematic utilization of both the approaches at the industrial level and/or at laboratory scale for quality control can be envisaged especially considering their ease of use and the short detection response.