Publication Date:
2015-01-27
Description:
3α,5α-Cyclocholestan-6β-yl alkyl and aryl ethers were proved to be efficient cholesteryl donors in the electrochemical synthesis of glycoconjugates. 3α,5α-Cyclocholestan-6β-ol (i-cholesterol) and its tert -butyldimethylsilyl ether can also be used for this purpose. The i-cholesterol derivatives show similar reactivities to those of previously studied 3α,5α-cyclocholestan-6β-thioethers. Beilstein J. Org. Chem. 2015, 11, 162–168. doi:10.3762/bjoc.11.16
Keywords:
cholesterolelectrochemical oxidationglycosylationi-cholesteryl ethersi-steroids
Electronic ISSN:
1860-5397
Topics:
Chemistry and Pharmacology
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