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  • 1
    Unknown
    London : The Geological Society
    Keywords: Europa ; Kohle ; Kohlengeologie ; Technologie ; Coal ; Coal mines and mining ; Coal trade ; Europe ; Geology
    Description / Table of Contents: Dr Rod Gayer and Professor Jiri Pesek: Preface / Geological Society, London, Special Publications, 125:vii-viii, doi:10.1144/GSL.SP.1997.125.01.01 --- Regional Coal Reserves, Coal Basin Tectonics and Stratigraphy --- Josef Doruška: The Czech Republic energy policy: conception and implementation in a market economy / Geological Society, London, Special Publications, 125:1-2, doi:10.1144/GSL.SP.1997.125.01.02 --- J. Pešek and M. Dopita: Coal production and usage in the Czech Republic / Geological Society, London, Special Publications, 125:3-12, doi:10.1144/GSL.SP.1997.125.01.03 --- O. Kumpera: Controls on the evolution of the Namurian paralic basin, Bohemian Massif, Czech Republic / Geological Society, London, Special Publications, 125:13-27, doi:10.1144/GSL.SP.1997.125.01.04 --- Miroslav Krs, Jiří Pešek, Petr Pruner, Vladimír Skoček, and Jana Slepičková: The origin of magnetic remanence components of Westphalian C to Stephanian C sediments, West Bohemia: a record of waning Variscan tectonism / Geological Society, London, Special Publications, 125:29-47, doi:10.1144/GSL.SP.1997.125.01.05 --- Roland Dreesen, Dominique Bossiroy, Rudy Swennen, Jacques Thorez, Aurelio Fadda, Luciano Ottelli, and Eddy Keppens: A depositional and diagenetic model for the Eocene Sulcis coal basin of SW Sardinia / Geological Society, London, Special Publications, 125:49-75, doi:10.1144/GSL.SP.1997.125.01.06 --- H. İnaner and E. Nakoman: Turkish lignite deposits / Geological Society, London, Special Publications, 125:77-99, doi:10.1144/GSL.SP.1997.125.01.07 --- A. I. Karayigit and M. K. G. Whateley: The origin and properties of a coal seam associated with continental thin micritic limestones, Selimoglu-Divrigi, Turkey / Geological Society, London, Special Publications, 125:101-114, doi:10.1144/GSL.SP.1997.125.01.08 --- A. I. Karayigit and M. K. G. Whateley: Chemical characteristics, mineralogical composition and rank of high sulphur coking coals of Middle Miocene age in the Gökler coal field, Gediz, Turkey / Geological Society, London, Special Publications, 125:115-130, doi:10.1144/GSL.SP.1997.125.01.09 --- Nicolae Ţicleanu and Dorina Diaconiţǎ: The main coal facies and lithotypes of the Pliocene coal basin, Oltenia, Romania / Geological Society, London, Special Publications, 125:131-139, doi:10.1144/GSL.SP.1997.125.01.10 --- George D. Šiškov: Bulgarian low rank coals: geology and petrology / Geological Society, London, Special Publications, 125:141-148, doi:10.1144/GSL.SP.1997.125.01.11 --- I. E. Stukalova: Coal petrology and facies associations of the South Yakutian Coal Basin, Siberia / Geological Society, London, Special Publications, 125:149-160, doi:10.1144/GSL.SP.1997.125.01.12 --- Coal Petrology and Palaeontology --- Rod Gayer, Richard Fowler, and Gareth Davies: Coal rank variations with depth related to major thrust detachments in the South Wales coalfield: implications for fluid flow and mineralization / Geological Society, London, Special Publications, 125:161-178, doi:10.1144/GSL.SP.1997.125.01.13 --- J. Dvořák, J. Honěk, J. Pešek, and P. Valterová: Deep borehole evidence for a southward extension of the Early Namurian deposits near Němčičky, S. Moravia, Czech Republic: implication for rapid coalification / Geological Society, London, Special Publications, 125:179-193, doi:10.1144/GSL.SP.1997.125.01.14 --- Irena Kostova, Kalinka Markova, and Krasimir Kuntchev: Mössbauer spectroscopic investigation of low rank coal lithotypes / Geological Society, London, Special Publications, 125:195-199, doi:10.1144/GSL.SP.1997.125.01.15 --- P. I. Premović, R. S. Nikolić, and M. P. Premović: Comparison of solid state 13C NMR of algal coals/anthracite and charcoal-like fusinites: further evidence for graphitic domains / Geological Society, London, Special Publications, 125:201-205, doi:10.1144/GSL.SP.1997.125.01.16 --- Ivana Sýkorová, Jaroslav Černý, Helena Pavlíková, and Zuzana Weishauptová: Composition and properties of North Bohemian coals / Geological Society, London, Special Publications, 125:207-217, doi:10.1144/GSL.SP.1997.125.01.17 --- Maya Stefanova and Caroline Magnier: Aliphatic biological markers in Miocene Maritza-Iztok lignite, Bulgaria / Geological Society, London, Special Publications, 125:219-228, doi:10.1144/GSL.SP.1997.125.01.18 --- Svetilana Syabryaj: Floristic characters of the upper coal-bearing formation in the Transcarpathians / Geological Society, London, Special Publications, 125:229-236, doi:10.1144/GSL.SP.1997.125.01.19 --- Mineral Matter in Coal and the Environment --- S. R. H. Baqri: The distribution of sulphur in the Palaeocene coals of the Sindh Province of Pakistan / Geological Society, London, Special Publications, 125:237-243, doi:10.1144/GSL.SP.1997.125.01.20 --- Paul F. Cavender and D. Alan Spears: Sulphur distribution in a multi-bed seam / Geological Society, London, Special Publications, 125:245-260, doi:10.1144/GSL.SP.1997.125.01.21 --- Vladimír Bouška, Jiří Pešek, and Karel Žák: Values of δ34S in iron disulphides of the North Bohemian Lignite Basin, Czech Republic / Geological Society, London, Special Publications, 125:261-267, doi:10.1144/GSL.SP.1997.125.01.22 --- G. Jankes, O. Cvetković, and T. Glumičić: Determination of different forms of sulphur in Yugoslav soft brown coals / Geological Society, London, Special Publications, 125:269-272, doi:10.1144/GSL.SP.1997.125.01.23 --- P. I. Premović, N. D. Nikolić, M. S. Pavlović, LJ. S. Jovanović, and M. P. Premović: Origin of vanadium in coals: parts of the Western Kentucky (USA) No. 9 coal rich in vanadium / Geological Society, London, Special Publications, 125:273-286, doi:10.1144/GSL.SP.1997.125.01.24 --- D. A. Spears: Environmental impact of minerals in UK coals / Geological Society, London, Special Publications, 125:287-295, doi:10.1144/GSL.SP.1997.125.01.25 --- Mining Geophysics --- Vít Gregor and Antonín Těžký: A well logging method for the determination of the sulphur content of coal seams by means of deep gammaspectrometry / Geological Society, London, Special Publications, 125:297-307, doi:10.1144/GSL.SP.1997.125.01.26 --- Karel Mach: A logging correlation scheme for the Main coal seam of the North Bohemian brown coal basin, and the implications for the palaeogeographical development of the basin / Geological Society, London, Special Publications, 125:309-320, doi:10.1144/GSL.SP.1997.125.01.27 --- Karel Holub: Seismic monitoring for rockburst prevention in the Ostrava-Karviná Coalfield, Czech Republic / Geological Society, London, Special Publications, 125:321-328, doi:10.1144/GSL.SP.1997.125.01.28 --- Zdeněk Kaláb: An analysis of mining induced seismicity and its relationship to fault zones / Geological Society, London, Special Publications, 125:329-335, doi:10.1144/GSL.SP.1997.125.01.29 --- Stanislav Opluštil, Jiří Pešek, and Jiří Skopec: Comparison of structures derived from mine workings and those interpreted in seismic profiles: an example from the Kačice deposit, Kladno Mine, Bohemia / Geological Society, London, Special Publications, 125:337-347, doi:10.1144/GSL.SP.1997.125.01.30 --- Coal Technology and Coalbed Methane --- J. Barraza, M. Cloke, and A. Belghazi: Improvements in direct coal liquefaction using beneficiated coal fractions / Geological Society, London, Special Publications, 125:349-356, doi:10.1144/GSL.SP.1997.125.01.31 --- B. R. Aleksić, M. D. Ercegovac, O. G. Cvetković, B. Ž. Marković, T. L. Glumičić, B. D. Aleksić, and D. K. Vitorvić: Conversion of low rank coal into liquid fuels by direct hydrogenation / Geological Society, London, Special Publications, 125:357-363, doi:10.1144/GSL.SP.1997.125.01.32 --- R. Asmatulu, N. Acarkan, G. Onal, and M. S. Celik: Desulphurization of low-rank coals by low-temperature carbonization / Geological Society, London, Special Publications, 125:365-369, doi:10.1144/GSL.SP.1997.125.01.33 --- Michael K. G. Whateley, Zafer Gencer, and Ertem Tuncali: Amelioration of high organic sulphur coal for combustion in domestic stoves / Geological Society, London, Special Publications, 125:371-377, doi:10.1144/GSL.SP.1997.125.01.34 --- M. Stanojević, G. Jankes, M. Kuburović, M. Stanojević, and P. Blagojević: The use of pulverized lignite/natural gas mixed fuels in the high-temperature process of a cement rotary kiln / Geological Society, London, Special Publications, 125:379-383, doi:10.1144/GSL.SP.1997.125.01.35 --- Douchko Douchanov and Venecia Minkova: The possibility of underground gasification of Bulgarian Dobrudja’s coal / Geological Society, London, Special Publications, 125:385-390, doi:10.1144/GSL.SP.1997.125.01.36 --- E. L. Boardman and J. H. Rippon: Coalbed methane migration in and around fault zones / Geological Society, London, Special Publications, 125:391-408, doi:10.1144/GSL.SP.1997.125.01.37 --- V. Holub, M. Eliáš, P. Hrazdíra, and J. Franců: Geological research into gas sorbed in the coal seams of the Carboniferous in the Mšeno-Roudnice Basin, Czech Republic / Geological Society, London, Special Publications, 125:409-423, doi:10.1144/GSL.SP.1997.125.01.38 --- Ireneusz Grzybek, Lidia Gawlik, Wojciech Suwała, and Ryszard Kuzak: Method for estimating methane emissions from Polish coal mining / Geological Society, London, Special Publications, 125:425-434, doi:10.1144/GSL.SP.1997.125.01.39 --- G. Takla and Z. Vavrušák: Methane emission and its utilization from Ostrava-Karviná Collieries in the Upper Silesian coal basin, Czech Republic / Geological Society, London, Special Publications, 125:435-440, doi:10.1144/GSL.SP.1997.125.01.40
    Pages: Online-Ressource (VIII, 448 Seiten) , Illustrationen, Diagramme, Karten
    ISBN: 1897799861
    Language: English
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 89 (1985), S. 4338-4342 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Low-molecular-weight hydrocarbons ; Extraterrestrial atmospheres ; Chemically bonded squalene(ane) phase ; 13C and29Si CP-MAS NMR
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Chemically bonded squalene(ene) phases have been synthesized via a hydride modified silanization process using dimethylchlorosilane, triethoxysilane and trichlorosilane. The surface structure of the bonded phases were characterized with DRIFT and solid state NMR studies. The results of the latter indicate successful bonding of a non-terminal olefin to the silica surface and that bonding of individual squalene molecules appeared not to occur at the same site(s) presumably due to steric hindrance. Among the phases examined, the trichlorosilane-based material exhibits better chromatographic properties probably due to greater surface coverage and hence effective non-polar interaction between the solutes and the bonded ligands. Under isothermal conditions, the present packings produced fast and efficient separation of C1–C4 saturated hydrocarbons on shorter columns than similar columns containing alkyl- or bidentate alkyl-modified silica packings at low column head pressure and are thermally stable at temperatures up to 250°C or higher.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; New bonded phases ; 13C and29Si CP-MAS NMR ; DRIFT ; ESCA
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A variety of olefins were bonded to silaceous supports through a hydride modified substrate. The products were then examined by13C and29Si solid state-NMR with cross-polarization (CP) and magic angle spinning (MAS). Information about the surface was also obtained by diffuse reflectance infrared Fourier transform spectroscopy (DRIFT) and the related photoelectron spectroscopic technique (ESCA). Carbon analysis on bonded silicas was carried out and surface coverage was calculated. Confirmation of the organic groups bound to the silica support was possible. The hydride intermediate is shown to be a versatile material for bonding a wide variety of organic moieties to silica surfaces.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Synthesis of new liquid phases ; Evaluation of new phases
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Three columns, mono-ol, butylphenyl and perfluorinated synthesized through the reaction of an olefin with a silica hydride intermediate, are evaluated for the separation of various model compounds. Two of the columns, mono-ol and perfluorinated, can operate in both the normal phase and reversed phase modes. Some effects of the hydride surface are detected, particularly for the perfluorinated phase. A four-component steroid mixture is tested on both the mono-ol and perfluorinated phases in the normal mode.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Bonded liquid crystals ; Polymeric stationary phases ; Variable temperature studies
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Using two polycyclyic aromatic hydrocarbons as solutes, a comparison is made between a bonded liquid crystal stationary phase and a conventional polymeric C-18 phase. The bonded nematic liquid crystal phase was the silanized form of 4-[4-(allyloxy)benzoyl-oxy]biphenyl and the polymeric phase was Vydac 201TP. Both phases display shape and planarity selectivity as indicated by the results of the variable temperature and mobile phase composition studies. The slot theory of retention can be used to explain these results. However, the liquid crystal phase is more sensitive to molecular geometry, probably due to its more ordered structure on the surface. Variable temperature experiments which compare retention during both heating and cooling provides additional support for this conclusion. With the polymeric bonded C-18 phase, each solute had identical retention at the same temperature during both the heating and cooling cycles. On the bonded liquid crystal phase, measurable differences in retention were observed at identical temperatures depending on whether the column was heated or cooled. This effect is attributed to a degree of partially reversible disordering which occurs as the column temperature was increased. However, conditioning with the appropriate mobile phase can restore the original retention characteristics of the bonded liquid crystal phase.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Chemically bonded phases ; Non-silica based supports ; Hydrosilation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A process for bonding a monolayer of silane to the surface of alumina, zirconia, thoria and titania by reaction with the hydrolysis product of triethoxysilane is described. The hydride containing material is then further reacted with a terminal olefin in the presence of a platinum catalyst to produce a chemically modified oxide surface which could be used as a chromatographic stationary phase. The success of this reaction is monitored by diffuse reflectance infrared Fourier transform and cross-polarization magic-angle spinning nuclear magnetic resonance spectroscopy as well as by differential scanning calorimetry. On all four oxides both the hydride intermediate and the alkyl bonded product are successfully formed via the silanization/hydrosilation reaction sequence.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Fullerences ; Alkyl bonded silica phases ; Retention vs. column temperature ; CP-MAS NMR
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The temperature-dependency of the separation of fullerenes in liquid chromatography (LC) has been examined using various alkyl bonded stationary phases. It has been found that a maximum retention temperature exists with long alkyl bonded stationary phases, whereas there is no similar effect with the newly synthesized alkyl bonded phases which have two phenyl groups at the base of the bonded phase. The interpretation of the retention behavior of fullerenes in the low temperature region on alkyl bonded stationary phases is discussed using information obtained by CP-MAS solid-state NMR spectroscopy and LC.
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  • 9
    ISSN: 1572-8943
    Keywords: catalytic hydrosilylation ; functional olefins ; immobilization ; silica surface
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract By means of hydrosilylation reactions between functional olefins and triethoxysilane in the presence of Speier's catalyst and sol-gel transformations of the reaction products, a number of optically active and complexing alkenes (quinine, quinidine, cinchonine, cinchonidine, alprenolol, N-allylrhodanine and hemin) were immobilized on the surface of silica. The structures of the compounds formed and the nature of their bonding with the surface were studied by DRIFT and NMR spectroscopies. The concentrations of olefins anchored to the surface layer of the silica matrix were estimated by UV spectroscopy.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Synthesis of polyfunctional stationary phases ; Quantitative structure-retention relationships, QSRR ; Separation of steroids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Preparation of a chemically-bonded-silica stationary phase (SG-MIX), with different polar and nonpolar functional groups such as hydroxyl (-OH), amino (-NH2), cyano (-CN), phenyl (-Ph), octyl (-C8) and octadecyl (-C18), is described. The characteristics of the prepared packing was done by physicochemical methods such as elemental analysis, FTIR spectroscopy, solid-state nuclear magnetic resonance (NMR), chromatography (GC and HPLC) as well as by analysis of quantitative structure-retention relationships (QSRR). The polyfunctional SG-MIX phase possesses properties of a reversed-phase material modified by specific inputs to retention due to interactions of analytes with polar functionalities on the surface of adsorbent. The new type of packing was successfully used for both analytical and preparative separation of finasteride from its metabolite, N-methylfinasteride.
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