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  • 1
    Description / Table of Contents: Orogenic andesites have long intrigued scientists because of their remarkable compositional similarities to the continental crust. The significance of orogenic andesites as proxies to continental crust formation has been recognized for over 30 years, but no consensus model of andesite genesis exists. Much of the controversy revolves around whether orogenic andesites are primary melts of slab and mantle materials, or instead evolve from basaltic mantle melts at shallower crustal levels. In three sections, this book provides an overview of andesite genesis at convergent margins that focuses on the slab–mantle interaction, crustal processing and andesite evolution through the life of volcanic arcs. Without favouring a particular view, the books aims to engender cross-fertilization and discussion that will smooth the pathway towards a holistic communal model of andesite petrogenesis and its role within the broader geochemical cycles of the Earth.
    Pages: Online-Ressource (IX, 414 Seiten)
    ISBN: 9781862393691
    Language: English
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  • 2
    Description / Table of Contents: The subduction zone volatile cycle is key to understanding the petrogenesis, transport, storage and eruption of arc magmas. Volatiles control the flux of slab components into the mantle wedge, are responsible for melt generation through lowering the solidi of mantle materials and influence the crystallizing phase assemblages in the overriding crust. Further, the rates and extents of degassing during magma storage and decompression affect magma rheology, ultimately control eruption style and have consequences for the environmental impact of explosive arc volcanism. This book highlights recent progress in constraining the role of volatiles in magmatic processes. Individual book sections are devoted to tracing volatiles from the subducting slab to the overriding crust, their role in subvolcanic processes and eruption triggering, as well as magmatic-hydrothermal systems and volcanic degassing. For the first time, all aspects of the overarching theme of volatile cycling are covered in detail within a single volume.
    Pages: Online-Ressource (292 Seiten)
    ISBN: 9781862396890
    Language: English
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  • 3
    Publication Date: 2013-09-14
    Description: A fundamental question in the formation of orogenic andesites is whether their high melt SiO 2 reflects the recycling of silicic melts from the subducted slab or the processing of basaltic mantle melts in the overlying crust. The latter model is widely favoured, because most arc magmas lack the ‘garnet’ signature of partial slab melts. Here we present new trace element data from Holocene high-Mg# 〉64–72 calc-alkaline basalts to andesites (50–62 wt% SiO 2 ) from the central Mexican Volcanic Belt that crystallize high-Ni olivines with the high 3 He/ 4 He = 7–8 of the upper mantle. These magmas have been proposed to be partial melts from ‘reaction pyroxenites’, which formed by hybridization of mantle peridotite ( c. 82–85%) and heavy rare earth element-depleted silicic slab melt (〉15–18%). Forward and inverse models suggest that the absence of a garnet signature in these melts reflects the efficient buffering of the heavy rare earth elements (Ho to Lu) in the subarc mantle. In contrast, all elements more incompatible than Ho – excepting TiO 2 – are more or less strongly controlled by the silicic slab flux that also directly contributes to the silicic arc magma formation. Our study emphasizes the strong link between slab recycling and the genesis of orogenic andesites. Supplementary material: Methods, additional data and modelling parameters are available at http://www.geolsoc.org.uk/SUP18686
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
    Topics: Geosciences
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  • 4
    Publication Date: 2015-05-16
    Description: U–Th–Ra isotope analyses of whole rocks and mineral separates were conducted in order to perform isochron dating of three morphologically young lavas from Tatun volcano, northern Taiwan (from Mt Cising, the Shamao dome and the Huangzuei volcano). The data do not yield tight U–Th isochrons, indicating open-system magmatic processes. However, crystallization ages of two samples can be constrained: namely, less than about 1370 years for the Shamao dome, based on 226 Ra– 230 Th disequilibrium in magnetite, and less than approximately 70 ka (but potentially Holocene) for a Huangzuei flow, based on 238 U– 230 Th disequilibrium in plagioclase. Discordant Ar–Ar, 238 U– 230 Th and 226 Ra– 230 Th ages are best explained by young lavas having inherited some crystals from older lithologies (crystal mushes or rocks), and indicate that the above ages represent maxima. Our study provides the first evidence of effusive volcanism at the Tatun Volcano Group in Late Holocene times. All separates from the Shamao dome and Huangzuei volcano are in 234 U– 238 U equilibrium. Minerals in the Mt Cising sample are in 234 U– 238 U disequilibrium, despite the 234 U– 238 U equilibrium of the whole rock. We interpret this as uptake of a hydrothermally altered, old crystal cargo into fresh melt prior to eruption. A different dating approach will thus be required to constrain the eruption age of Mt Cising. Supplementary material: Ar–Ar plateaus from Mt Cising and the Shamao dome, reproduced from Lee (1996), are available at www.geolsoc.org.uk/SUP18817
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
    Topics: Geosciences
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  • 5
    Publication Date: 2013-10-10
    Description: This chapter provides an overview of the current state of research on orogenic andesites. While their importance as proxies to the evolution of the continental crust has long been recognized, andesite genesis has remained highly controversial with a broader consensus yet to be reached. The controversy is fuelled by the question of whether orogenic andesites are primary melts of slab and mantle materials, or instead derivative products of basaltic mantle melts that differentiate in the overlying crust. These hypotheses are addressed in three sections of the book devoted to slab–mantle processes, the complexities of melt differentiation at crustal levels, and models pertaining to arc crustal growth. We believe that cross-fertilization and discussion among seemingly opposite and irreconcilable hypotheses will smooth the pathway towards a holistic communal model of andesite petrogenesis.
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
    Topics: Geosciences
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  • 6
    Publication Date: 2014-11-15
    Description: The volatile cycle at subduction zones is key to the petrogenesis, transport, storage and eruption of arc magmas. Volatiles control the flux of slab components into the mantle wedge, are responsible for melt generation through lowering the solidi of mantle materials, and influence the crystallizing phase assemblages in the overriding crust. Globally, magma ponding depths may be partially controlled by melt volatile contents. Volatiles also affect the rate and extent of degassing during magma storage and decompression, influence magma rheology and therefore control eruption style. The style of eruptions in turn determines the injection height of environmentally sensitive gases into the atmosphere and the impact of explosive arc volcanism. In this overview we summarize recent advances regarding the role of volatiles during slab dehydration, melt generation in the mantle wedge, magmatic evolution in the overriding crust, eruption triggering, and the release of some magmatic volatiles from volcanic edifices into the Earth's atmosphere.
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
    Topics: Geosciences
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  • 7
    Publication Date: 2014-07-20
    Description: Pleistocene basalts from Daisen and Mengameyama in the SW Japan volcanic arc of western Honshu are characterized by an abundance of olivine crystals with Fe-rich rims. At Daisen, these have previously been interpreted to have formed from their host melt by equilibrium crystal fractionation and by disequilibrium fractionation during supercooling. Here we use combined electron probe microanalysis, isotopography, transmission electron microscopy and selected area electron diffraction to show that crystal rims are significantly enriched in aluminium (up to c . 1 wt%) and hydrogen (up to c . 10 000 ppm) hosted in oriented low-density amorphous domains. These domains are interpreted to have formed by melting of deuteric and/or post-deuteric metasomatic alteration minerals upon uptake of older olivine crystals into fresh, initially aphyric host melts up to a few hours prior to eruption. It is argued that uptake of variably altered crystals into initially aphyric or sparsely phyric melts may be a common process at subduction zones, and can account for typical disequilibrium textures displayed by arc magmas erupted in SW Japan and elsewhere. Analyses of the altered crystal cargo in arc volcanic rocks therefore provides an important tool for understanding subvolcanic hydrothermal systems and the interaction of ascending melts with such systems. Supplementary material: Olivine mineral chemistry data from two typical Daisen basalts and one typical Mengameyama basalt, and a figure showing the locations of all focussed ion beam (FIB) sections studied here, are available at http://www.geolsoc.org.uk/SUP18760 .
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
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  • 8
    Publication Date: 2013-07-20
    Description: Uranium–thorium (U–Th) isotope compositions of whole rocks, groundmasses and minerals from mafic to intermediate Andean arc magmas were determined to assess the influence of crustal stress on rates of pre-eruptive crystallization and the significance of crystal uptake. Volcanoes investigated include Lascar in the central Andes, situated in a compressional regime, and Callaqui and Lonquimay in the southern Andes, situated in a transtensional regime. In the southern Andes, Calbuco volcano, which experienced variations in the local stress field due to volcano unloading triggered by large debris avalanches, was also targeted. In U–Th equiline space, whole rock and groundmass coincide in each studied sample, and are close to secular equilibrium or in slight U-excess. No isochronal relationships are displayed by the mineral separates, although many are out of secular equilibrium. Further, ( 234 U/ 238 U) activity ratios of some mineral separates from the southern Andes are in disequilibrium and vary significantly between different phases of individual rock samples. The combined data indicate that many crystals are foreign to the melts they are carried in, and that some mineral phases have experienced incipient weathering before their incorporation into the melt. Using Calbuco as an example, we speculate that volcano loading may affect secondary alteration processes at depth.
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
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  • 9
  • 10
    Publication Date: 2016-11-02
    Description: The Trans-Mexican Volcanic Belt (TMVB) is known for the chemical diversity in its erupted products. We have analyzed the olivine, pyroxene, and plagioclase mineral chemistry of 30 geochemically well-characterized mafic eruptives from Isla Maria at the western end of the arc to Palma Sola in the east. The mineral major oxide data indicate the dominance of open system processes such as antecryst uptake, and the scarcity of mineral-mineral and mineral-melt equilibria suggests that apart from forming microlites, erupted melts do not significantly crystallize during ascent. A combination of plagioclase antecryst chemistry and MELTS thermodynamic modeling of H 2 O-saturated isobaric fractional crystallization was employed to develop a pressure sensor aimed at determining the ponding depths of the co-genetic magmas from which the erupted plagioclase crystal assemblage originates. We show that the depth of magma-mush reservoirs increase eastward along the TMVB. We suggest that magma ponding is triggered by degassing-induced crystallization during magma ascent, and that the pressure sensor can also be regarded as a degassing sensor, with more hydrous melts beginning to degas at greater depths. Modeled initial magma H 2 O contents at the Moho range from ~4 to ~9 wt%. Magma-mush ponding depth variations fully explain the observed westward increase of average surface heat flux along the TMVB, supporting a new model of mafic arc magma ascent, where rapidly rising, initially aphyric melts pick up their antecrystic crystal cargo from a restricted crustal depth range, in which small unerupted batches of previously risen co-genetic magmas typically stall and solidify. This implies that, globally, mafic arc magmas may be used to constrain the depths of degassing and mush zone formation, as well as the amount of H 2 O in the primary melts.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
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