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  • 1
    Publication Date: 2017-09-27
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 92 (1988), S. 3024-3028 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 7823-7830 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report optical waveguiding in single-crystal, epitaxial (101) oriented rutile (TiO2) thin films grown on (112¯0) sapphire (α-Al2O3) substrates using the metal-organic chemical vapor deposition technique. The electromagnetic field distributions and propagation constants for asymmetric planar waveguides composed of an anisotropic dielectric media applicable to these films are derived. Modifications to the prism-film coupling theory for this anisotropic case are also discussed. By application of this model to (101) oriented rutile thin films, we directly obtain values of the ordinary and extraordinary refractive indexes, n0 and ne, of the rutile thin films as well as film thicknesses. We obtain typical values of the refractive indexes (n0=2.5701±0.0005; ne=2.934±0.001) near to those for bulk rutile single crystals indicating the exceptional quality of these films.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 2995-3003 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Photoion–photoelectron coincidence (PIPECO) spectra for Ar+n (n=2–4) in the wavelength region of 750–875 A(ring) have been measured at different nozzle stagnation pressures. The ionization energies (IE) for the ground Ar+2[I(1/2)u] and Ar+3[I(1/2)u] states are determined to be 14.518±0.017 eV (854±1 A(ring)) and 14.350±0.033 eV (864±2 A(ring)), in agreement with the findings of previous photoionization experiments. The IE for Ar+2[II(1/2)u] is found to be (approximately-less-than)15.83 eV (783 A(ring)). The observation of the Ar+2[II(1/2)u] PIPECO band supports the interpretation that Ar+2[II(1/2)u] is metastable with a lifetime longer than 47 μs, a value in accord with the calculated radiative lifetime of 90.9 μs for the II(1/2)u →I(1/2)g transition. The PIPECO spectrum for Ar+2 is dominated by autoionization structure similar to that resolved in the photoionization efficiency spectrum for Ar+2, indicating that a significant fraction of electrons produced by these autoionizing states are slow electrons with near-zero kinetic energies. Evidence is found that metastable Ar+3 and Ar+4 ions formed by photoionization of Ar3 and Ar4 at energies above the Ar+2[I(1/2)u]+Ar(1S0) and Ar+3[I(1/2)u]+Ar(1S0) dissociation limits may live longer than 58 and 66 μs, respectively. We suggest that the formation of Ar+3 in metastable electronic states may be responsible for the long dissociation lifetimes of Ar+3 observed in this experiment.
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 6026-6033 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The photoion–photoelectron coincidence (PIPECO) spectra for (CO)+2 in the wavelength region of 620–990 A(ring) have been obtained at different nozzle stagnation pressures (P0). The ionization energy for (CO)2 to CO+(X˜)⋅CO is determined to be (approximately-less-than)12.73±0.05 eV (974±4 A(ring)), indicating that CO+(X˜)⋅CO is bound by more than 1.29 eV. The PIPECO measurements also provide evidence that CO+(A˜,B˜)⋅CO are bound with dissociation energies 〉0.3 eV. At P0≤200 Torr and a nozzle temperature (T) of 120 K, nozzle expansion conditions which minimize the formation of (CO)n (n≥3), the intensities for the CO+(A˜,B˜)⋅CO PIPECO bands are found to be negligibly small compared to that for the CO+(X˜)⋅CO PIPECO band. This observation supports the conclusion that the excited CO+(A˜,B˜)⋅CO ions are dissociative, with dissociation lifetimes〈42 μs. This conclusion is contrary to that of the preliminary study which is based on the PIPECO spectrum for (CO)+2 measured at P0=350 Torr and T=120 K. Assuming that the radiative lifetimes of CO+(A˜ or B˜) and CO+(A˜ or B˜)⋅CO are identical, we estimate that the dissociation lifetimes for CO+(A˜)⋅CO and CO+(B˜)⋅CO are (approximately-less-than)4 μs and (approximately-less-than)50 ns, respectively.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 91 (2002), S. 5325-5333 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The adjustable photoluminescence (PL) and field electron emission (FEE) properties of boron carbonitride (B–C–N) nanotubes grown under well-controlled conditions are studied systematically. Large-scale highly aligned B–C–N nanotubes are synthesized directly on Ni substrates by the bias-assisted hot filament chemical vapor deposition method. Single-walled B–C–N nanotubes and nanometric B–C–N heterojunctions are obtained by the pulsed-arc-discharge technique and pause-reactivation two-stage process, respectively. It is found that the microstructures, orientations, and chemical compositions of the nanotubes can be controlled by varying growth parameters. The mechanism of the controllable growth is also investigated. Intense and stable PL from the nanotubes is observed in both blue-violet (photon energies 3.14–2.55 eV) and yellow-green bands (photon energies 2.13–2.34 eV) and the emission bands are adjusted by varying the compositions of the nanotubes. FEE properties are also studied and optimized by varying the B or N atomic concentrations in the nanotubes. All these results verify the controllability of the electronic band structure of the B–C–N nanotubes. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: An end station for soft x-ray fluorescence spectroscopy has been constructed, which includes an experiment chamber, rotatable 90° under ultrahigh vacuum conditions around the incoming synchrotron radiation beam, which is provided with a high-resolution soft x-ray spectrometer. A manipulator allowing three axes of rotation, three directions of translation, as well as LN2 cooling and resistive heating is mounted to the chamber and serves as the sample holder. Samples can be transferred under vacuum between the experiment chamber and two other chambers, one for sample preparation and another for introducing new samples and for sample storage. The end station has been used at two different synchrotron radiation laboratories (beamline BW3) at HASYLAB in Hamburg and at ALS (beamline 7.0) in Berkeley. Polarization-dependent and angular resolved, selectively excited x-ray emission studies have been made on ordered as well as nonordered systems, e.g., high-Tc superconducting systems, diamond, fullerenes, and molecular ices. The experimental system will be presented along with some recent scientific results. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The SpectroMicroscopy Facility at the Advanced Light Source is based on a high brightness, high-resolution beamline, and includes a collection of projects designed to exploit the unique characteristics of the soft x-ray beam. The beamline itself is comprised of a 5-m long, 5-cm-period undulator, a spherical-grating monochromator with water-cooled gratings. Adaptive optics refocus the monochromatic beam to two "microfocus'' experimental stations with spot sizes less than 50 μm diameter and a third "nanofocus'' station uses a zone-plate lens to further demagnify the microfocus spot. Experimental stations include an "ultraESCA'' spectrometer for small-area spectroscopy and photoelectron diffraction, a scanning transmission x-ray microscope, and photoelectron microscopes. Commissioning experiments of microscopic actinide photoemission, surface-core-level photoelectron diffraction, and high-resolution soft x-ray fluorescence demonstrate dramatic improvements in sensitivity due to the high brightness and small focus of the beamline. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of metamorphic geology 20 (2002), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: High-pressure basic granulites are widely distributed as enclaves and sheet-like blocks in the Huaian TTG gneiss terrane in the Sanggan area of the Central Zone of the North China craton. Four stages of the metamorphic history have been recognised in mineral assemblages based on inclusion, exsolution and reaction textures integrated with garnet zonation patterns as revealed by compositional maps and compositional profiles. The P–T conditions for each metamorphic stage were obtained using thermodynamically and experimentally calibrated geothermobarometers. The low-Ca core of growth-zoned garnet, along with inclusion minerals, defines a prograde assemblage (M1) of garnet + clinopyroxene + plagioclase + quartz, yielding 700 °C and 10 kbar. The peak of metamorphism at about 750–870 °C and 11–14.5 kbar (M2) is defined by high-Ca domains in garnet interiors and inclusion minerals of clinopyroxene, plagioclase and quartz. Kelyphites or coronas of orthopyroxene + plagioclase ± magnetite around garnet porphyroblasts indicate garnet breakdown reactions (M3) at conditions around 770–830 °C and 8.5–10.5 kbar. Garnet exsolution lamellae in clinopyroxene and kelyphites of amphibole + plagioclase around garnet formed during the cooling process at about 500–650 °C and 5.5–8 kbar (M4). These results help define a sequential P–T path containing prograde, near-isothermal decompression (ITD) and near-isobaric cooling (IBC) stages.The clockwise hybrid ITD and IBC P–T paths of the HP granulites in the Sanggan area imply a model of thickening followed by extension in a collisional environment. Furthermore, the relatively high-pressures (6–14.5 kbar) of the four metamorphic stages and the geometry of the P–T paths suggest that the HP granulites, together with their host Huaian TTG gneisses, represent the lower plate in a crust thickened during collision. The corresponding upper-plate might be the tectonically overlying Khondalite series, which was subjected to medium- to low-pressure (MP/LP: 7–4 kbar) granulite facies metamorphism with a clockwise P–T path including an ITD segment. Both the HP and the MP/LP granulite facies events occurred contemporaneously at c. 1.90–1.85 Ga in a collisional environment created by the assembly process of the North China craton.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 4596-4607 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Bi2Sr2Ca0.64Cu1.64Ox (nominally Bi2212) powders were fabricated into powder-in-tube Ag- and Ag(7 at. % Cu)-sheathed tapes by cold and hot rolling to investigate the effects of sheath composition and rolling conditions on their microstructural development and superconducting properties. Bi2212 tapes with Ag(Cu) sheaths exhibited improved grain alignment and interfacial uniformity, as well as enhanced formation of the Bi-free phase (≈Sr7.5Ca6.5Cu14Ox), relative to the Ag-sheathed specimens. The hot-rolled Ag(Cu)-sheathed tapes displayed superior critical current densities (Jc), where magnetization Jcm=1.5×106 (H(parallel)c) and 4.6×105 A/cm2 (H⊥c) at T=5 K, H=1 T. Correspondingly, these specimens had transport critical current densities (Jct) of 6.7×104 A/cm2 (H(parallel)c) and 5.4×104 A/cm2 (H⊥c) at T=4.2 K, H=0 T and 2.2×104 A/cm2 (H(parallel)c) and 3.0×104 A/cm2 (H⊥c) at T=4.2 K, H=14 T. The chemical stability of the Ag(Cu) sheath regions during the partial melting process was also studied. Rapid oxidation of copper produced Cu2O precipitates in the sheath at 885 °C, and subsequently a Cu2O-free zone developed near the core/sheath interface. A theoretical analysis of Cu2O precipitate formation and decomposition during thermal processing is presented. © 1995 American Institute of Physics.
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