ALBERT

Description: Seventeen basalts from Ocean Drilling Program (ODP) Leg 183 to the Kerguelen Plateau (KP) were analyzed for the platinum-group elements (PGEs: Ir, Ru, Rh, Pt, and Pd), and 15 were analyzed for trace elements. Relative concentrations of the PGEs ranged from ~0.1 (Ir, Ru) to ~5 (Pt) times primitive mantle. These relatively high PGE abundances and fractionated patterns are not accounted for by the presence of sulfide minerals; there are only trace sulfides present in thin-section. Sulfur saturation models applied to the KP basalts suggest that the parental magmas may have never reached sulfide saturation, despite large degrees of partial melting (~30%) and fractional crystallization (~45%). First order approximations of the fractionation required to produce the KP basalts from an ~30% partial melt of a spinel peridotite were determined using the PELE program. The model was adapted to better fit the physical and chemical observations from the KP basalts, and requires an initial crystal fractionation stage of at least 30% olivine plus Cr-spinel (49:1), followed by magma replenishment and fractional crystallization (RFC) that included clinopyroxene, plagioclase, and titanomagnetite (15:9:1). The low Pd values ([Pd/Pt]_pm 〈 1.7) for these samples are not predicted by currently available Kd values. These Pd values are lowest in samples with relatively higher degrees of alteration as indicated by petrographic observations. Positive anomalies are a function of the behavior of the PGEs; they can be reproduced by Cr-spinel, and titanomagnetite crystallization, followed by titanomagnetite resorption during the final stages of crystallization. Our modeling shows that it is difficult to reproduce the PGE abundances by either depleted upper or even primitive mantle sources. Crustal contamination, while indicated at certain sites by the isotopic compositions of the basalts, appears to have had a minimal affect on the PGEs. The PGE abundances measured in the Kerguelen Plateau basalts are best modeled by melting a primitive mantle source to which was added up to 1% of outer core material, followed by fractional crystallization of the melt produced. This reproduces both the abundances and patterns of the PGEs in the Kerguelen Plateau basalts. An alternative model for outer core PGE abundances requires only 0.3% of outer core material to be mixed into the primitive mantle source. While our results are clearly model dependent, they indicate that an outer core component may be present in the Kerguelen plume source.

Description: Author Posting. © Oceanography Society, 2019. This article is posted here by permission of Oceanography Society for personal use, not for redistribution. The definitive version was published in Neal, C.R., M.F. Coffin, and W.W. Sager. Contributions of scientific ocean drilling to understanding the emplacement of submarine large igneous provinces and their effects on the environment. Oceanography 32(1), (2019):176–192, doi:10.5670/oceanog.2019.142.

Description: The Ontong Java Plateau (OJP), Shatsky Rise (SR), and Kerguelen Plateau/Broken Ridge (KP/BR) represent three large igneous provinces (LIPs) located in oceanic settings. The basement lavas have been investigated through scientific ocean drilling and, in the case of the OJP, fieldwork on the emergent obducted portions of the plateau in the Solomon Islands. Such studies show that these three LIPs have very different characteristics. For example, the KP/BR still has an active hotspot, whereas the OJP and the SR do not. The OJP is remarkable in its compositional monotony across the plateau (the Kwaimbaita geochemical type), with minor compositional variation found at the margins (the Kroenke, Singgalo, and Wairahito types). Shatsky Rise shows more compositional variation and, like the OJP, has a dominant lava type (termed the “normal” type) in the early stages (Tamu Massif), but subsequent eruptions at the Ori and Shirshov massifs comprise isotopically and trace element enriched lavas, likely reflecting a change in mantle source over time. The KP/BR has highly variable basement lava compositions, ranging from lavas slightly enriched above that of normal mid-ocean ridge basalt in the northern portion (close to the South East Indian Ridge) to more enriched varieties to the south and on Broken Ridge, with a continental crust signature present in lavas from the southern and central KP/BR. The OJP and the KP/BR appear to have formed through punctuated magmatic events, whereas the SR was formed by one relatively long, drawn out event. The formation of oceanic LIPs has in many (but not all) cases been synchronous with oceanic anoxic events. This paper focuses on three oceanic plateaus to emphasize the debate surrounding the environmental impact such LIPs may have had, and also highlights the contributions of scientific ocean drilling to our knowledge of oceanic LIP formation and evolution. This new knowledge allows planning for future oceanic LIP drilling.

Description: Many thanks to the crew and operators of the scientific ocean drilling vessel JOIDES Resolution without whom the understanding of oceanic flood basalts would be severely limited. We also thank the US National Science Foundation for continued support of scientific ocean drilling. We are indebted to Jörg Geldmacher, Paul Wallace, Carlotta Escutia, and Anthony Koppers for reviews of this paper that were insightful and extremely helpful in making it much better than the initial submission.

Description: A total of 16 Ontong Java Plateau (OJP) basalt samples from Ocean Drilling Program Legs 192 and 130 were analysed for major, trace and platinum-group elements (PGEs; Ir, Ru, Rh, Pt and Pd). Major- and trace-element compositions determined by our study confirm Leg 192 shipboard analyses that indicated a new group of more primitive or Kroenke-type' basalts, with higher MgO, Ni and Cr, and lower incompatible-element, abundances than the more common Kwaimbaita-type basalts. The PGE abundances quantified here extend the range of the continuum of compositions found in previously analysed OJP basalts and are similar to those present in some komatiites. The PGEs, therefore, cannot be used to differentiate definitively between OJP basalts groups. The two samples analysed from Leg 130 (one from Site 803 and one from Site 807) are akin to the Kwaimbaita-type basalts. Low-temperature alteration has not affected Pd abundances in the Leg 192 basalts as it has in the Solomon Island and the Leg 130 samples. Elemental abundances and ratios along with petrography reveal that the OJP basalts have not experienced sulphide saturation. Positive correlations of Ir and Ru with Cr and Ni attest to the lithophile behaviour of the PGEs and lend more credence to studies suggesting compatibility of these elements in oxide and silicate phases, such as Cr-spinel and olivine. Estimates of sulphur abundance in the mantle, degree of partial melting and pressure of melt initiation were used in conjunction with the model of Mavrogenes & O'Neill to calculate a minimum initial excess temperature of +185-+235{degrees}C (1465-1515{degrees}C at 3.5-4.0 GPa) above ambient mantle for the OJP source. This is in broad agreement with a fossil geotherm preserved in megacrysts and peridotite xenoliths found in pipe-like intrusives of alnoite that outcrop on the island of Malaita, Solomon Islands. Using the PGEs as a guide, the OJP basalts were modelled using a three-source component melt mix: a 10% garnet peridotite melt of primitive mantle composition, which then passed through the garnet-spinel transition and melted a further 20%, a 30% partial melt of fertile upper mantle and 0-1% of outer core material. The core component was included only in the plume source, and the ratio of plume source to upper mantle source was 19: 1. It is evident from this study that the PGE contents of at least some of the OJP basalts are too high to be generated by primitive mantle sources alone. A PGE-enriched component is required and we suggest that this is outer core material. While a sulphide-rich mantle component could also increase the PGE abundances (assuming that the sulphide is exhausted during partial melting), the sulphur-undersaturated nature of these basalts argues against this. Variations in the amount of outer core in the source (from 0 to 1 wt%) and degree of fractional crystallization can account for the entire range in PGE abundances of OJP basalts.

Description: Tholeiitic basalts have been recovered from drill sites in different locations on the Ontong Java Plateau (OJP) and are remarkably homogeneous across this large igneous province. The most abundant basalt type is represented by the Kwaimbaita Formation on Malaita in the Solomon Islands, where it is capped by the isotopically distinct and slightly more incompatible-element-enriched basalt of the Singgalo Formation. Ocean Drilling Program (ODP) Leg 192 drilled five sites on the OJP, four of which penetrated basement lava successions. All basalt recovered during Leg 192 is chemically and isotopically indistinguishable from Kwaimbaita-type lavas. Site 1184 of ODP Leg 192 is situated on the eastern salient of the OJP, and is unique because the recovered volcaniclastic succession contains the first conclusive evidence for emergence of part of the OJP above sea level. Within this succession are clasts of basaltic material. We report the major element-, trace-element and isotopic compositions of 14 moderately to highly altered basalt clasts. On the basis of incompatible-element concentrations, specifically high field strength elements (HFSE) and rare earth elements (REE), four groups of clasts are defined. Group 1 clasts are similar to basalt from the Kwaimbaita Formation. Group 2 clasts show variable composition, but the heavy rare earth element (HREE) concentrations are similar to those of basalts from the Kwaimbaita Formation. Group 3 clasts have compositions similar to the high-MgO Kroenke-type basalt recovered during ODP Leg 192. Group 4 clasts are more evolved than the Kwaimbaita or Singgalo lavas, and contain deep negative Eu and Sr anomalies on primitive-mantle (PM)-normalized diagrams, as well as high concentrations of Nb, Ta and Th. Group 4 clasts also show a large fractionation of Nb from La and have (Nb/La)PM ratios of approximately 2. Sr-, Nd- and Pb-isotope ratios were measured on five clasts covering all four groups. Although the Sr- and Pb-isotope ratios exhibit some variability, which we attribute to alteration, the Nd-isotope ratios are within the field defined for Kwaimbaita-type lavas. We conclude that most of the compositional variability displayed by these clasts is a result of alteration and that Ta appears to be the most immobile incompatible trace element. All of the clasts were derived from the mantle source that produced the Kwaimbaita-type and Kroenke-type basalts. Our data emphasize the widespread nature of Kwaimbaita-type basalt and show that the source region was active under both the eastern salient and the high plateau of the OJP.

Description: The compositions of glass clasts in volcaniclastic rocks recovered from drilling at Site 1184 on the eastern salient of the Ontong Java Plateau (OJP) are investigated using microbeam analytical methods for major, minor and trace elements. These data are compared with whole-rock elemental and isotopic data for bulk tuff samples, and with data from basalts on the high plateau of the OJP. Three subunits of Hole 1184A contain blocky glass clasts, thought to represent the juvenile magmatic component of the phreatomagmatic eruptions that generated the volcaniclastic rocks. The glass clasts have unaltered centres, and are all basaltic low-K tholeiites, with flat chondrite-normalized rare earth element (REE) patterns. Their elemental compositions are very similar to the Kwaimbaita-type and Kroenke-type basalts sampled on the high plateau. Each subunit has a distinct glass composition and there is no intermixing of glass compositions between subunits, indicating that each subunit is the result of one eruptive phase, and that the volcaniclastic sequence has not experienced reworking. The relative heterogeneity preserved at Site 1184 contrasts with the uniformity of compositions recovered from individual sites on the high plateau, and suggests that the eastern salient of the OJP had a different type of magma plumbing system. Our data support the hypothesis that the voluminous subaerially erupted volcaniclastic rocks at Site 1184 belong to the same magmatic event as the construction of the main Ontong Java Plateau. Thus, the OJP would have been responsible for volatile fluxes into the atmosphere in addition to chemical fluxes into the oceans, and these factors may have influenced the contemporaneous oceanic anoxic event.