ALBERT

Description: Controversy surrounding the mechanisms and controls on argon diffusion in K-feldspar has led us to undertake direct diffusion measurements on a crystal with simple microtextures, over a range of temperatures. Measurements of argon diffusion profiles in a gem-quality iron-rich orthoclase heated in a cold seal apparatus, have been undertaken in situ using an ultra-violet laser ablation microprobe (UVLAMP) technique. The results agree very closely with the previously determined bulk values for Benson Mines orthoclase (activation energy ( E)=43.8±1 kcal mol -1) and vacuum furnace cycle-heating studies of K-feldspars ( E=46±6 kcal mol -1). However, instead of defining a single activation energy ( E) and diffusion coefficient ( Do), the data yield two sets of parameters: a low-temperature (550-720°C) array with an E of 47.2±2.5 kcal mol -1 (198.2±10.5 kJ mol -1) and a Do of 0.0374 +0.1123-0.0281 cm 2 s -1, and a high-temperature (725-1019°C) array with an E of 63.8±3.4 kcal mol -1 (268.0±14.3 kJ mol -1) and a Do of 55.0 +225.5-44.2 cm 2 s -1. The new results closely reproduce two sets of apparent activation energies previously measured in cycle-heating studies of Madagascar K-feldspar (40±3 and 57±3 kcal mol -1). Previous interpretations of the two arrays have included multiple domains with variable activation energies and fast track diffusion. However, the UV depth profile analyses indicate simple diffusion to the grain surface and importantly, diffusion radii calculated by combining the UVLAMP and cycle-heating data, are the same as the physical grain sizes used in the experiments, around 1 mm. Vacuum furnace stepped heating experiments on slowly cooled K-feldspars have been interpreted as showing diffusion radii of around 6 μm and indicate complex populations of sub-grains. This study indicates that Madagascar K-feldspar and thus probably all gem-quality K-feldspars act as single diffusion domains and that short-circuit (or pipe) diffusion was not an important loss mechanism. An apparent diffusion compensation relationship in the stepped heating data for Madagascar K-feldspar implies that similar relationships seen in other K-feldspars are a result of a range of diffusion mechanisms.

Description: Detailed geological mapping in the Drosh-Shishi area in southern Chitral (NW Pakistan) was combined with high-precision U-Pb dating on zircons to constrain the timing of magmatism and associated deformation/metamorphic events related to the Kohistan-Karakoram convergence and collision. Our new ages indicate that the Mesozoic to Tertiary magmatic history of this region is influenced by long-lived melt generation above an active subduction zone. Dated intrusive rocks range in age from 130 to 39 million years, indicating that subduction-related magmatism continued after the Kohistan-Karakoram and the India-Asia collisions. Initial hafnium isotope ratios were measured on the dated zircons to constrain the type of melt source of the dated plutons. The data reveal the different nature of partly coeval magmatism in these units, i.e. continental arc magmatism in the Karakoram (ca. 130-104 Ma) and arc magmatism magmatism on the Kohistan side (112-39 Ma). Intrusions within the suture zone can be clearly traced to be Karakoram-derived on the basis of initial Hf isotopic compositions. Granite dykes crosscutting the Kohistan units have sampled an underlying, old continental basement of Gondwana affinity. The geochronological evidence presented in this paper is consistent with Cretaceous subduction beneath the Karakoram Terrane. The related calc-alkaline magmatism seems to have stopped at about 100 Ma. Granite dykes on the Kohistan side show that the magmatic and tectonic history of the Karakoram-Kohistan Suture Zone continued to the Eocene. This long tectono-metamorphic and magmatic activity in the arc plates was likely due to complex and few million year long interplays between subduction and thrusting events in the forearc, within-arc and back-arc regions between two active subduction zones.