ISSN:
0887-624X
Keywords:
polymer support
;
dichlorotriazine
;
cooperative effect
;
pseudo crown ether
;
phase transfer catalyst
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Poly(2,4-dichloro-6-vinyl-1,3,5-triazine-co-styrene)s were prepared by the reaction of poly(2,4-diamino-6-vinyl-1,3,5-triazine-co-styrene)s with hydrochloric acid, and followed by treatment with thionyl chloride and N,N-dimethylformamide. The chlorine atoms in the resulted polymers were replaced readily by several nucleophiles such as amide, alkoxide, and mercaptide to afford the corresponding polymers in moderate yields. Among these, polymers containing oligo (oxyethylene) groups at both 2 and 4 positions of 1,3,5-triazine ring worked effectively as phase transfer catalysts for the reaction of n-octyl bromide with alkali metal thiocyanates in toluene-water systems. However, polystyrenes containing only one oligo (oxyethylene) group in monomer unit scarcely exhibited the activity under these conditions although the degree of loading of the functional group was almost the same. The activity depended on the number of oxyethylene units, and the selectivity to alkali metal ions was also observed. © 1992 John Wiley & Sons, Inc.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pola.1992.080300804
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